In general, the acceleration vector for planar motion in polar coordinates is given by $$\mathbf a=(\ddot r-r\dot\theta^2)\hat r+(r\ddot\theta+2\dot r\dot\theta)\hat\theta$$
Although you don't say it, I assume you are asking aboutFor circular motion wherewe have $\dot r=\ddot r=0$, so that the centripetal acceleration becomes $$a_r=r\dot\theta^2$$ and the tangential acceleration becomes$^*$ $$a_\theta=r\ddot\theta$$
Therefore, one could argue that these values are related through the $r$ variable such that $$\frac{a_r}{\dot\theta^2}=\frac{a_\theta}{\ddot\theta}$$
Of course, if there is no tangential acceleration for our circular motion we get an undefined value mathematically, butI should say that this makesrelation is more "descriptive" than "constraining" in the sense physically. You can have anythat it doesn't necessarily mean that the centripetal acceleration for uniform circular motiondetermines the tangential acceleration or vice versa.
Note It really only says that these two ratios have to be equal, as $a_c$ depends on $\dot\theta^2$ in the angular acceleration is justsame way $a_\theta$ depends on $\ddot\theta$, so if. I know this probably isn't as insightful as you want to bring that in too then that is a pretty simple thing to dowere hoping for, but it's what we have.
InTherefore, in terms of how useful this relation is for doing physics problems, I'm not so sure. Both accelerations are easy to determine if you already know $\dot\theta$ and $\ddot\theta$, but I digress.
Note that the angular acceleration is just $\ddot\theta$, so if you want to bring that in too then that is a pretty simple thing to do.
Also note that if there is no tangential acceleration for our circular motion we get an undefined value mathematically, but this makes sense physically. You can have any centripetal acceleration for uniform circular motion.
You might be more familiar with notation $a_c=r\omega^2=v^2/r$ and $a_\theta=r\alpha$. I could have started here, but I wanted to give a more general approach starting from "the beginning" with general planar motion in polar coordinates. This is usually my starting point for investigating questions like these.