As you say, you should use Gauss's law. You pick a Gaussian surface that is a sphere concentric with the insulated sphere, with radius less than or equal to $R$. Then you get:
$$ 4\pi r^2 E = \frac{Q_{enc}(r)}{\epsilon_0} $$
with $Q_{enc}(r)$ the charge enclosed by the surface of radius $r$.
If you pick $r = R$ you get $Q_{enc}(R) = 4\pi R^2E\epsilon_0$.
I'm not entirely comfortable that this is consistent with a physical distribution of charge. Because $E$ is constant everywhere, it must be that $Q_{enc}(r) \propto r^2$. I can't immediately find a charge distribution which achieves this without requiring infinite But then charge density is infinite at the origin. I'm not saying it's wrong, but something to be cautious aboutcentre.