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Jul 21, 2013 at 22:41 vote accept Francisco Presencia
Jan 25, 2013 at 14:51 comment added Mark Mitchison I think the main similarity between the depletion and hydrophobic interactions is that they are entropic forces, arising because the system can minimise its free energy by maximising configurational entropy. But most macroscopic forces are also entropic, for example the forced exerted by an ideal gas on the walls of the container is an entropic force.
Jan 25, 2013 at 13:59 comment added Francisco Presencia I thought about lipid bilayers because that's what I was studying in the first place, but then thought that it would be more similar without the hydrophilic heads. Which is again really similar to the Depletion force and Casimir effect for what I could understand in the link, right? (non-native so a couple of things in the link were not clear for me)
Jan 25, 2013 at 8:04 comment added John Rennie @MarkMitchison: I have absolutely no idea if you could calculate the Casimir force just from entropy: sorry!
Jan 25, 2013 at 7:46 comment added Mark Mitchison Great answer, +1. I've always found the link between the Casimir effect and the depletion interaction fascinating. Do you know if it is possible to derive the Casimir force from entropic considerations alone?
Jan 25, 2013 at 7:18 history answered John Rennie CC BY-SA 3.0