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Thomas Fritsch
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For an ideal gas constant volume heat addition process, change of entropy equation is:

∆S= cv ln⁡(T2/T1)+ R ln⁡(v2/v1)= ∫dq/T+S(gen)$$\Delta S= c_v \ln\frac{T_2}{T_1}+ R \ln\frac{v_2}{v_1}= \int \frac{dq}{T}+S_{gen}$$

The term [R ln⁡(v2/v1) ]$R \ln\frac{v_2}{v_1}$ equals zero, since it’s a constant volume process.

For ideal gas ∫dq/T =cv ln⁡(T2/T1) $\int \frac{dq}{T} =c_v \ln\frac{T_2}{T_1}$ .

Then:

∆S= cv ln⁡(T2/T1)= cv ln⁡(T2/T1)+S(gen)$$\Delta S= c_v \ln\frac{T_2}{T_1}= c_v \ln\frac{T_2}{T_1}+S_{gen}$$

Therefore, the S(gen)$S_{gen}$ term equals zero and the process is reversible.

The question is: why does the S(gen)$S_{gen}$ term equal zero and the process is reversible when this is a heat addition through a finite temperature difference?

To give a numerical example, imagine that an ideal gas is put in a rigid tank of uniform temperature where its initial temperature is 400$400$ K, and a hot reservoir at 500$500$ K. then heat is transferred from the hot reservoir to the rigid tank until the temperature of the rigid tank is 430$430$ K.

referring to the expressions above T1 =400$T_1 =400$ K and T2 =430$T_2 =430$ K.

For an ideal gas constant volume heat addition process, change of entropy equation is:

∆S= cv ln⁡(T2/T1)+ R ln⁡(v2/v1)= ∫dq/T+S(gen)

The term [R ln⁡(v2/v1) ] equals zero, since it’s a constant volume process.

For ideal gas ∫dq/T =cv ln⁡(T2/T1) .

Then:

∆S= cv ln⁡(T2/T1)= cv ln⁡(T2/T1)+S(gen)

Therefore, the S(gen) term equals zero and the process is reversible.

The question is: why does the S(gen) term equal zero and the process is reversible when this is a heat addition through a finite temperature difference?

To give a numerical example, imagine that an ideal gas is put in a rigid tank of uniform temperature where its initial temperature is 400 K, and a hot reservoir at 500 K. then heat is transferred from the hot reservoir to the rigid tank until the temperature of the rigid tank is 430 K.

referring to the expressions above T1 =400 K and T2 =430 K.

For an ideal gas constant volume heat addition process, change of entropy equation is:

$$\Delta S= c_v \ln\frac{T_2}{T_1}+ R \ln\frac{v_2}{v_1}= \int \frac{dq}{T}+S_{gen}$$

The term $R \ln\frac{v_2}{v_1}$ equals zero, since it’s a constant volume process.

For ideal gas $\int \frac{dq}{T} =c_v \ln\frac{T_2}{T_1}$ .

Then:

$$\Delta S= c_v \ln\frac{T_2}{T_1}= c_v \ln\frac{T_2}{T_1}+S_{gen}$$

Therefore, the $S_{gen}$ term equals zero and the process is reversible.

The question is: why does the $S_{gen}$ term equal zero and the process is reversible when this is a heat addition through a finite temperature difference?

To give a numerical example, imagine that an ideal gas is put in a rigid tank of uniform temperature where its initial temperature is $400$ K, and a hot reservoir at $500$ K. then heat is transferred from the hot reservoir to the rigid tank until the temperature of the rigid tank is $430$ K.

referring to the expressions above $T_1 =400$ K and $T_2 =430$ K.

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For an ideal gas constant volume heat addition process, change of entropy equation is:

∆S= cv ln⁡(T2/T1)+ R ln⁡(v2/v1)= ∫dq/T+S(gen)

The term [R ln⁡(v2/v1) ] equals zero, since it’s a constant volume process.

For ideal gas ∫dq/T =cv ln⁡(T2/T1) .

Then:

∆S= cv ln⁡(T2/T1)= cv ln⁡(T2/T1)+S(gen)

Therefore, the S(gen) term equals zero and the process is reversible.

The question is: why does the S(gen) term equal zero and the process is reversible when this is a heat addition through a finite temperature difference?

To give a numerical example, imagine that an ideal gas is put in a rigid tank of uniform temperature where its initial temperature is 400 K, and a hot reservoir at 500 K. then heat is transferred from the hot reservoir to the rigid tank until the temperature of the rigid tank is 430 K.

referring to the expressions above T1 =400 K and T2 =430 K.

For an ideal gas constant volume heat addition process, change of entropy equation is:

∆S= cv ln⁡(T2/T1)+ R ln⁡(v2/v1)= ∫dq/T+S(gen)

The term [R ln⁡(v2/v1) ] equals zero, since it’s a constant volume process.

For ideal gas ∫dq/T =cv ln⁡(T2/T1) .

Then:

∆S= cv ln⁡(T2/T1)= cv ln⁡(T2/T1)+S(gen)

Therefore, the S(gen) term equals zero and the process is reversible.

The question is: why does the S(gen) term equal zero and the process is reversible when this is a heat addition through a finite temperature difference?

For an ideal gas constant volume heat addition process, change of entropy equation is:

∆S= cv ln⁡(T2/T1)+ R ln⁡(v2/v1)= ∫dq/T+S(gen)

The term [R ln⁡(v2/v1) ] equals zero, since it’s a constant volume process.

For ideal gas ∫dq/T =cv ln⁡(T2/T1) .

Then:

∆S= cv ln⁡(T2/T1)= cv ln⁡(T2/T1)+S(gen)

Therefore, the S(gen) term equals zero and the process is reversible.

The question is: why does the S(gen) term equal zero and the process is reversible when this is a heat addition through a finite temperature difference?

To give a numerical example, imagine that an ideal gas is put in a rigid tank of uniform temperature where its initial temperature is 400 K, and a hot reservoir at 500 K. then heat is transferred from the hot reservoir to the rigid tank until the temperature of the rigid tank is 430 K.

referring to the expressions above T1 =400 K and T2 =430 K.

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entropy Entropy generation of constant volume heat addition process

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