It does not work like that. The wave function of 6 electrons is the product, not the sum, of orbitals (wave functions of a single electrons). However, since electrons are fermions the overall wave function must be antisymmetric. Thus, the simplest wave functionsfunction that you can write for the 6 electron-benzene approximation (in the spirit of the H"uckel method) is the Slater determinant: $$\psi({\bf{r}_1,\ldots,\bf{r}_6}) = \left| \begin{array}{cccccc} \phi_1(r_1) \alpha(1) & \phi_1(r_1)\beta(1) & \phi_2(r_1)\alpha(1) & \phi_2(r_1) \beta(1) & \phi_3(r_1)\alpha(1) & \phi_3(r_1)\beta(1) \\ \vdots & \vdots & \vdots & \vdots & \vdots & \vdots \\ \phi_1(r_6)\alpha(6) & \phi_1(r_6)\beta(6) & \phi_2(r_6)\alpha(6) & \phi_2(r_6)\beta(6) & \phi_3(r_6)\alpha(6) & \phi_3(r_6)\beta(6) \end{array} \right|$$ where $\phi_k$ are the H"uckel single electron wavefunctions (the orbitalsMO-LCAO in H"uckel's approach), $\bf{r}_i$ is the position and spin variable of electron $i$, and $\alpha(i)$ and $\beta(i)$ refer to the spin function (up and down, respectively). The Slater determinant has 6 rows: you change the electron index in each row.
Following the simple H"uckel theory the energy of the system is $E = 2(E_1 + E_2 + E_3)$ where $E_k$ is the energy of the orbital. (Of course this is a rough approximation that doesn't take into account interelectron repulsion or the double counting of these repulsions if they are included in some averageda self-consistent way in $E_k$.)
Therefore the time-dependent wave function is $\Psi({\bf{r}_1,\ldots,\bf{r}_6},t) = \psi({\bf{r}_1,\ldots,\bf{r}_6}) e^{-iEt/\hbar}$