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Jan 15, 2017 at 14:14 comment added AHB @SRS the answer is no because of definition of equilibrium.
Jan 15, 2017 at 14:13 comment added SRS I didn't say, I move out of equilibrium. I'm asking about the possibility of maintaining the same equilibrium while doing work.
Jan 15, 2017 at 14:10 comment added AHB @SRS Yes. In EQ, they hold. But not out of it. And that sign convention is more than a convention, most of the books assume the positive work to be done on the system. But here an increment in volume indicated negative work on the system.
Jan 15, 2017 at 14:08 comment added SRS the sign is a convention. The equations I wrote does hold in equilibrium. It doesn't hold when you're out of equilibrium. If one understands, what can/cannot happen in mechanical equilibrium, one can generalize the conclusion for generalized works for chemical and thermal equilibrium.
Jan 15, 2017 at 14:04 history answered AHB CC BY-SA 3.0