Alcohol will boil off first
The boiling point is 78.37 °C
There will be some water but the ratio of alcohol in the vapor phase will be higher than the liquid. Water and alcohol are azeotropes so things flop at about 70% alcohol.
The size is not that much of a factor - hexane is volatile.
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Table salt (NA CL) is not much more volatile than a rock
melting point 801 °C (1,474 °F)
boiling point 1,413 °C (2,575 °F)
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The lowest vapor pressure I could find is at 759.88 °K = 486.73 °C
1.88322997019E-006 kPa
Vapor Pressure of Sodium chloride
The vapor pressure of water is 101.32 kPa at 100 °C
Water is 53,801,182 times more volatile at 100 °C than salt at 486.73 °C
Salt is dissolved in water but that does not make the salt more volatile.
Basically no salt evaporates. With very rapid boiling you might get some entrainment. The vapor phase is going to have essentially not salts or minerals as they are solids are at 100 °C.
Take a quart of water and add a cup of salt. Put it on the stove and let all the water boil off. You will have a cup of salt.