Skip to main content
12 events
when toggle format what by license comment
Aug 4, 2016 at 13:51 vote accept Eric Walker
Nov 12, 2015 at 23:02 history edited rob CC BY-SA 3.0
added 443 characters in body
Oct 24, 2015 at 13:19 comment added rob … which is why I used the actual wavefunctions evaluated at $r=0$
Oct 23, 2015 at 21:24 comment added Eric Walker What struck me about the figure was that the nuclear volume and the barrier are a speck at the origin, and that for s-waves at all n there is a local maximum at the origin that overwhelms the nucleus and the barrier.
Oct 23, 2015 at 21:12 comment added rob It doesn't. Because of the shell theorem what matters is the electron density near the nucleus; the large-$n$ electrons spend more of their time far from the nucleus.
Oct 23, 2015 at 5:05 comment added Eric Walker Does Figure 3-8 of this discussion alter your assumptions about the radial distribution of the s-orbits for $n>1$? chemistry.mcmaster.ca/esam/Chapter_3/section_2.html
Oct 23, 2015 at 1:38 comment added rob @EricWalker An excellent point which I was editing in as you commented; it changes the answer quite a bit.
Oct 23, 2015 at 1:34 history edited rob CC BY-SA 3.0
added 1033 characters in body
Oct 23, 2015 at 1:24 comment added Eric Walker Why did you drop the discussion of the barrier width, which seems more pertinent to the question?
Oct 23, 2015 at 1:10 history rollback rob
Rollback to Revision 1
Oct 23, 2015 at 1:05 history edited rob CC BY-SA 3.0
added 1519 characters in body
Oct 22, 2015 at 23:40 history answered rob CC BY-SA 3.0