Skip to main content
replaced images of book with actual text plus minor formatting & title swap
Source Link
Kyle Kanos
  • 28.8k
  • 41
  • 69
  • 135

Non equlibrium thermodynamics: How exactly does Applying Euler Homogenous Function Theorem allows one to go from total differentials df to f itself?$df$ or $f$

enter image description here

I am currently reading this bookDemirel's Nonequilibrium Thermodynamics in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying toauthor's do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the firstfollowing step to it

EDIT: Zoom in of the problem enter image description here

IsThe pressure $P$ and temperature $T$ define the result fromvalues at each point of the text obtained fromsystem and are therefore called direct integrationintensive properties, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

That issome of which can be expressed as derivatives of extensive properties, is thissuch as temperature \begin{align} X=\sum_i X_in_i &&&& [1] \end{align}

$$T=\left(\frac{\partial U}{\partial S}\right)_{V,N}$$ where $U$ is actually not this

\begin{align} dX=\sum_i X_idn_i &&&& [2] \end{align}

integrated

But just because of Euler Homogeneous Function Theorem, ifthe energy and $[2]$$S$ is true, thenthe entropy. If $[1]$ must also be true$X$ denotes any extensive property (not necessarily a thermodynamic propert) of a phase, we may derive intensive properties denoted by the$X_i$ and called as partial properties $X_i=\left(\partial X/\partial n_i\right)_{T,p,n_i}$ ($i\neq j$). For any partial property we have $dX=\sum_i\left(\partial X/\partial n_i\right)dn_i=\sum_iX_idn_i$ at constant $T$ and $P$. The Euler theorem? shows that $X=\sum_iX_in_i$

Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

That is, is this relation $$ X=\sum_i X_in_i \tag{1} $$ the integration of this relation $$ dX=\sum_i X_idn_i? \tag{2} $$ But just because of Euler Homogeneous Function Theorem, if (2) is true, then (1) must also be true by the theorem?

Non equlibrium thermodynamics: How exactly does Euler Homogenous Function Theorem allows one to go from total differentials df to f itself?

enter image description here

I am currently reading this book in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying to do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the first step to it

EDIT: Zoom in of the problem enter image description here

Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

That is, is this \begin{align} X=\sum_i X_in_i &&&& [1] \end{align}

is actually not this

\begin{align} dX=\sum_i X_idn_i &&&& [2] \end{align}

integrated

But just because of Euler Homogeneous Function Theorem, if $[2]$ is true, then $[1]$ must also be true by the theorem?

Applying Euler Homogenous Function Theorem to $df$ or $f$

I am currently reading Demirel's Nonequilibrium Thermodynamics in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the author's do the following step:

The pressure $P$ and temperature $T$ define the values at each point of the system and are therefore called intensive properties, some of which can be expressed as derivatives of extensive properties, such as temperature $$T=\left(\frac{\partial U}{\partial S}\right)_{V,N}$$ where $U$ is the energy and $S$ is the entropy. If $X$ denotes any extensive property (not necessarily a thermodynamic propert) of a phase, we may derive intensive properties denoted by $X_i$ and called as partial properties $X_i=\left(\partial X/\partial n_i\right)_{T,p,n_i}$ ($i\neq j$). For any partial property we have $dX=\sum_i\left(\partial X/\partial n_i\right)dn_i=\sum_iX_idn_i$ at constant $T$ and $P$. The Euler theorem shows that $X=\sum_iX_in_i$

Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

That is, is this relation $$ X=\sum_i X_in_i \tag{1} $$ the integration of this relation $$ dX=\sum_i X_idn_i? \tag{2} $$ But just because of Euler Homogeneous Function Theorem, if (2) is true, then (1) must also be true by the theorem?

added 291 characters in body
Source Link
Secret
  • 935
  • 2
  • 9
  • 19

enter image description here

I am currently reading this book in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying to do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the first step to it

EDIT: Zoom in of the problem enter image description here

Tl;dr: Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

That is, is this \begin{align} X=\sum_i X_in_i &&&& [1] \end{align}

is actually not this

\begin{align} dX=\sum_i X_idn_i &&&& [2] \end{align}

integrated

But just because of Euler Homogeneous Function Theorem, if $[2]$ is true, then $[1]$ must also be true by the theorem?

enter image description here

I am currently reading this book in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying to do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the first step to it

EDIT: Zoom in of the problem enter image description here

Tl;dr: Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

enter image description here

I am currently reading this book in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying to do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the first step to it

EDIT: Zoom in of the problem enter image description here

Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

That is, is this \begin{align} X=\sum_i X_in_i &&&& [1] \end{align}

is actually not this

\begin{align} dX=\sum_i X_idn_i &&&& [2] \end{align}

integrated

But just because of Euler Homogeneous Function Theorem, if $[2]$ is true, then $[1]$ must also be true by the theorem?

added 179 characters in body
Source Link
Secret
  • 935
  • 2
  • 9
  • 19

enter image description here

I am currently reading this book in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying to do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the first step to it

EDIT: Zoom in of the problem enter image description here

Tl;dr: Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

enter image description here

I am currently reading this book in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying to do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the first step to it

EDIT: Zoom in of the problem enter image description here

enter image description here

I am currently reading this book in order to learn more about entropy and nonequlibrium thermodynamics

However I and stumped on how the authors do this step here as shown in the left side of the image

Background: I am trying to do some research on modelling relationship between entropy and chemical potentials for isomerisation reactions, which requires computing partial derivatives where the variables are chemical potentials of particles in a system. Thus I have to make sure I have used the maths correctly (especially integrating multivariate expressions expressed as differentials), thus this question is the first step to it

EDIT: Zoom in of the problem enter image description here

Tl;dr: Is the result from the text obtained from direct integration, or it just looks like it is integrated because of the consequence of Euler Homogeneous Function Theorem?

added 113 characters in body
Source Link
Secret
  • 935
  • 2
  • 9
  • 19
Loading
Source Link
Secret
  • 935
  • 2
  • 9
  • 19
Loading