Take a room and an ice cube as an example. Let's say that the room is the isolated system. The ice will melt and the total entropy inside the room will increase. This may seem like a special case, but it's not. All what I'm really saying is that the room as whole is not at equilibrium meaning that the system is exchanging heat, etc. inside itself increasing entropy. That means that the subsystems of the whole system are increasing their entropy by exchanging heat with each other and since entropy is extensive the system as whole is increasing entropy. The cube and the room will exchange, at any infinitesimal moment, heat $Q$, so the cube will gain entropy $\frac{Q}{T_1}$, where $T_1$ is the temperature of the cube because it gained heat $Q$, and the room will looselose entropy $\frac{Q}{T_2}$, where $T_2$ is the temperature of the room because it lost heat $Q$. Since $\frac{1}{T_1}>\frac{1}{T_2}$ the total change in entropy will be positive. This exchange will continue until the temperatures are equal meaning that we have reached equilibrium. If the system is at equilibrium it already has maximum entropy.