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16

The next approximation beyond the ideal gas is given by the Van der Waals fluid equation. It is a phenomenological law which takes into account the finite size of the molecules and their interactions with themselves. When you plot several Van der Vaals isotherms for a given substance, you observe that some of them show a phase transition from gas to liquid ...


11

Getting from gas to liquid is a matter of interparticle interaction winning over thermal agitation. There are several reasons why interparticle interactions are very weak in the case of helium atoms. On one hand, it is a noble gas and thus cannot form covalent bonds. On the other hand, it is very light hence highly non-polarizable: its Van der Waals ...


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For the first question, it is the low boiling temperature, 4.21K for Helium-4 and 3.19K for Helium-3, that makes helium difficult to be liquefied. Hydrogen's boiling temperature at 1 atm is 20.27K, or about 4-5 times higher. For pre-cooling, one can take a look of entropy $$\delta S = \frac {dQ}{T}$$ We can see that, because T is very small, a slight ...



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