New answers tagged spin-chains
The canonical example for MPS (in fact, the first MPS ever) is the AKLT model (http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.59.799, https://projecteuclid.org/euclid.cmp/1104161001). The 2nd reference also discusses the 2D (=PEPS) version of the state. Another example of an exact MPS/PEPS model are (nearest-neighbor) RVB states (https://arxiv.org/...
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