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It depends on what you mean by vacuum. If you mean a field configuration that has $F=0$, then the gauge potential is locally pure gauge (cf. this answer by Qmechanic), so there can only be global obstructions to the gauge equivalence class of the $A$ corresponding to $F=0$ being $A=0$ everywhere. On $\mathbb{R}^{1,3}$, there is no such obstruction. If ...

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