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The answer lies in probability theory. Roughly, the probability of an event or macro state $A$ to happen is the number of instances $\Omega(A)$ in which it is fulfilled divided by the total number of possible instances or micro states $\Omega$ i.e. $p(A) = \frac{\Omega(A)}{\Omega}$. So the reason why you want to maximize $\Omega(A)$ is because you seek ...

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