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2
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2answers
42 views

X-ray diffraction analytical principle - diffraction or reflection?

I am an MSc in analytical chemistry, currently working with x-ray diffraction. The technique is called "x-day diffraction", but are not the x-rays reflected? Max von Laue discovered that x-rays were ...
0
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2answers
109 views

Compute distance between planes in a crystal

I want to compute the distance between two (111) planes in a cubic crystalline structure, in order to do some computations involving Bragg reflection. I have a sketch of which the (111) planes are, ...
2
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1answer
35 views

How many atoms does one need to get reliable crystal information with X ray or electron diffraction?

I know that, in theoretical derivations of X ray diffraction (XRD) or electron diffraction (ED), we always assume an infinite lattice, and, as you make the crystal smaller, edge effects start to ...
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1answer
22 views

Why can the twin plane be uncoincide with the composition plane in reflection twin?

In the book Elements of X-Ray Diffraction, p67, I found the following sentence: In the case of a reflection twin, the composition plane may or may not coincide with the twin plane. But I think ...
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1answer
20 views

Is it more difficult to create higher energy photons, given there is excess available energy?

Im not talking about pair production, I mean a single photon created from an energy transition between two electron shells. I'm studying K(alpha) and K(beta) fluorescence transitions in metals, and ...
1
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0answers
13 views

X-ray diffraction analyisis: The angle of elastic x-ray scattering

What is the scattering angle distribution for x-rays (in the 8keV range) scattered elastically? I work with XRD analysis, which is fundamentally basede on these elastic scatterings of x-rays. I read ...
1
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0answers
66 views

The reciprocal lattice of HCP lattice

There is a very similar question here Reciprocal Lattice of a non-bravais lattice, but I don't fully understand the answer, and the question is now obsolete so I feel that I should ask it again. How ...
1
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0answers
24 views

How do I use MAUD for phase quantification of XRD data with AMCSD standards?

I'm a biologist with some raw powder XRD data of biominerals, need to quantify different phases, can't access commercial software or databases at the moment. Does anyone have experience with using ...
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0answers
26 views

Reciprocal space maps units

I have seen reciprocal space maps in different units. In some figures, it is represented in delta(l) delta(h) reciprocal space maps units. In some figures it is shown in Q(parallel) and Q(normal) ...
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0answers
55 views

Why does inelastic X-ray scattering probe the longitudinal dielectric function as opposed to the transverse dielectric function?

Light is a transverse wave. Therefore, light in the optical range (i.e. visible light) couples to transverse collective excitations of a material when measuring the optical conductivity for instance. ...
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0answers
96 views

Pseudocubic unit cells: how to construct one?

I keep coming across the term pseudocubic unit cell while reading about orthorhombic perovskite structures. No clear explanation ...
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0answers
32 views

The correspondence between real space and reciprocal space

From what I've learned, a point $P=(h\ k\ l)^T$ in the real space can be expressed as a linear combination of the primitive vectors $$A\left(\array{n_1\\n_2\\n_3}\right)=P$$ Where $A=(a_1a_2a_3)$ is ...
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0answers
21 views

Crystallography and symmetry operations

I am trying to figure out the basis for deuterate solid state water. To do so I took the position of the basis atoms from http://rruff.geo.arizona.edu/AMS/amcsd.php and then I applied the symmetry ...
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0answers
12 views

Why Nitrides have internal polarization?

Why GaN has internal polarization? I know that in wurtzite crystal structure, the atomistic bonds are not equivalent and as a result there appears a net dipole and consequently a polarization. But ...
0
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0answers
17 views

Impurities involved in nucleation centres

When magmas begin to crystallise, a first step is the formation of a crystal nucleus around an impurity (nucleation centre), whereby a few of the right atoms get together to form a speck of a crystal. ...
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0answers
68 views

Bragg's law - intensity “sensitivity” to lattice spacing or scattering angle

I don't understand this sentence (emphasis added): A consideration of Bragg's law (nλ = 2dsinθ), i.e. the relationship between scattering angle (θ) and the interplanar spacing (d) shows that if ...
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0answers
2k views

How to calculate lattice parameter of wurtzite struture

I am trying to calculate lattice parameter of ZnO (wurtzite). I have found out the formula for calculating lattice parameter of this system from a research article. $\frac{1}{^{d^{2}}}=\frac{H ^{2}+ ...