A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Probability and double slit

if a beam of identical particles at random distances from each other (or exactly 1/2 lambda between each other) travelling with the same v towards a double sllit do not interfere with each others wave ...
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165 views

Single quantum particle in beam splitter, with different systems located in each channel

Suppose a quantum mechanical particle enters a beam-splitter, which sends its wave packets into two mutually orthogonal channels, $C_a$ and $C_b$. Suppose that $C_a$ also contains System A, with ...
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23 views

Deriving Wave Function for Scattering States with Delta-Function Potential

I am following the Griffiths Book on Quantum Mechanics, and am following the derivation for the wave function for Delta-Function Potentials. $$V(x) = -\alpha \delta(x)$$ In the scattering states, ...
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208 views

How can I solve this quantum mechanical “paradox”?

Let a (free) particle move in $[0,a]$ with cyclic boundary condition $\psi(0)=\psi(a)$. The solution of the Schrödinger-equation can be put in the form of a plane wave. In this state the standard ...
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407 views

How to determine the transmission coefficient of a gaussian wave packet scattering on an finite square well?

I am doing a scattering simulation of a Gaussian wave packet on a finite square well. I have solved numerically the Schroedinger equation and I know the values of the wave function after the ...
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Is there a “natural” way to interpolate between a set of bound state wave functions?

Consider for example the Coulomb potential, $-Z/r$, for which there exist a set of bound states with energy $\epsilon_n := {-Z^2 \over 2 n^2}$ (in Hartree). If I want the "wavefunctions" for some ...
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538 views

Degeneracy in one dimension

I'm reading this wikipedia article and I'm trying to understand the proof under "Degeneracy in One Dimension". Here's what it says: Considering a one-dimensional quantum system in a potential ...
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240 views

Why does the wave description say that probability oscillates, while the phase interpretation says constant amplitude?

The wave description of a particle illustrates an oscillating probability of the particle being found in any point in space. When a particle travels, it carries along with it a phase that oscillates ...
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45 views

How can energy be negative in a finite square well?

Say if the potential $V(x) < 0$ in the well but the sides or the scattered states its zero potential, anyways How is that the energy in the well is less than zero? Is it because the potential ...
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241 views

Normalized wave functions in position and momentum space

Using the following expression for the Dirac delta function: $$\delta(k-k')=\frac{1}{2\pi}\int_{-\infty}^{\infty}e^{i(k-k')x}\mathrm{d}x$$ show that if $\Psi(x,t)$ is normalized at time $t=0$, ...
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61 views

What's the microscopic and macroscopic effect of wavefunction dispersion?

In Quantum Mechanics (Merzbacher 2nd ed.), problem 2.1 asks us to derive the time evolution of a one-dimensional Gaussian wavefunction (formula given for $t=0$), assuming the velocity is in the $+x$ ...
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Notation of complex valued atomic orbitals

Atomic orbitals are usually labeled $1s$, $2p_x$, $2p_x$, $2p_z$ and so on. These wave functions are defined to be real valued. The original wave functions are complex valued. The $2p_x$ orbital is ...
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49 views

Expectation value of the Hamiltonian [closed]

How to calculate expectation value of the Hamiltonian for hydrogen atom? $$\langle H \rangle_{\alpha l} \equiv \frac{\langle \psi_{\alpha l m}|H(r)| \psi_{\alpha l m}\rangle} {\langle \psi_{\alpha l ...
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32 views

How to rewrite a wave function in terms of spheical harmonics

I'm given a wave function for a particle, in three variables (spherical coordinates): $ψ=ψ(r, θ, φ) = re^{-r/a}sin(θ)sin(φ)$. I'm tasked with rewriting $ψ$ in terms of spherical harmonics which are ...
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206 views

Finite potential well, parity of solutions

I'm working through some problems for a QM exam and I've realised I don't really understand the concept of parity of solutions. I'm looking at a simple finite potential well problem: $$V(x)=0, \quad ...
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51 views

Energy of hydrogen atom - Schrodinger equation [closed]

The wavefunction of the electron in the hydrogen atom is $ k* exp(-r/a)$ (k is the normalization constant), but it does not take n into account, whereas the solution of Schrödinger's equation ...
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86 views

Clarification about two forms of the wave function

The wave function in the position representation is $\langle\ x\rvert\psi\rangle$ = $ \psi (x) $ , where $ \psi (x) $ are the continuous coefficients that multiply the orthonormal basis vectors, i.e, ...
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3k views

Periodic boundary condition on a Wave Function of a Particle in a Box

Until now, solving the Schrodinger Equation for a particle in a box was relatively easy because the boundaries conditions imposed zero value on the wave function at the boundaries. But now I must find ...
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Difference for boundary condition, particle in a box

When solving the simple problem of a free particle in a box of volume $V = L^3$, we can impose either periodic boundary conditions $\psi(0) = \psi(L)$ and $\psi '(0)= \psi'(L)$ either strict boundary ...
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226 views

Hartle and Hawking's universal wavefunction

My apologies in advance if this question is poorly worded or doesn't make any sense, however I have just finished reading into this theory and it seems as though Hawkings No Boundary Universe is ...
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1answer
42 views

How to calculate the frequency of oscillation of superposition states [closed]

Been working on this question for a while and I'm not sure how to go about it. Could someone point me in the right direction, particularly for the frequency question. The question is as follows: A ...
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Coupled quantum harmonic oscillator

Given the following Hamiltonian for two identical linear oscillators with spring constant $k$ and interaction potential $\alpha x_1x_2$; I was asked to find the expectation value $\langle ...
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Density of classical states in quantum theory

Let's first treat electrons as classical objects. I can evaluate the classical energy of each state in a configurational space (3N real numbers and, say, spins) using just Coulomb's law. Then I ...
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768 views

How to compute the expectation value $\langle x^2 \rangle$ in quantum mechanics?

$$\langle x^2 \rangle = \int_{-\infty}^\infty x^2 |\psi(x)|^2 \text d x$$ What is the meaning of $|\psi(x)|^2$? Does that just mean one has to multiply the wave function with itself?
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Why wavefunction is sometimes multiplied by the radius to get probability density?

When solving 1d particle in a box, the probability density is said to be proportional to $|\psi|$, but when solving 3d orbitals, the probability density is said to be proportional to $|\psi|^2 r^2$. ...
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Semi-infinite / Asymmetric potential well

I'm asked to come up with an ansatz and solve for the coefficients of a asymmetric infinite potential well, where: $$ V = \begin{cases} \infty \text{ for } x< 0 \\ V_0 \text{ for } 0 \leq x \leq L ...
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43 views

Two fermions with total spin 1 antisymmetric wave function? [closed]

How can I prove, that two fermions with a total spin of 1 must have an antisymmetric wave function?
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44 views

Can we measure the energy of one of several identical particles?

Suppose we have a many-particle system described via a many-particle wavefunction that involves single-particle states $\lvert\lambda_{a}\rangle$, $\lvert\lambda_{b}\rangle$, ...
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404 views

Quantum Mechanics in Electric Field

I am working on a problem which looks like this. Consider a charged particle with charge $q$ trapped in a box of length $L$ with finite constant potential $ V_0 $ on both ends. A constant (static) ...
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169 views

How can quantum wavefunctions be smooth/continuous when particles are created/destroyed/changed?

My (admittedly limited) understanding of the Schrodinger equation tells me that the vector differential operators are only meaningful over a differentiable phase space. For example, if the dimensions ...
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24k views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
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38 views

Wave packets in Dirac equation

Gaussian wave packets remain Gaussians after evolution in case of the Schrodinger equation. It is a very useful property of these wave packets. I don't think the same is true for a Gaussian wave ...
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Floquet quasienergy spectrum, continuous or discrete?

I haven't got a feeling about Floquet quasienergy, although it is talked by many people these days. Floquet theorem: Consider a Hamiltonian which is time periodic $H(t)=H(t+\tau)$. The ...
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Derivation of group velocity using Fourier transform

The aim is to determine the group velocity of a wave packet with the general form $$\Psi\left(x,t\right)=\frac{1}{\sqrt{2\pi}}\int_{-\infty}^{\infty} \phi\left(x\right)e^{i\left(kx-\omega ...
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24 views

Why can a free particle not exists in a stationary state? [duplicate]

In normalising the complete wavefunction of a free partcile; $V(x)=0$ we arrive at $\int_{-\infty}^{\infty}\Psi_{k} ^\dagger\Psi_{k}dx=|A|^{2}\int_{-\infty}^{\infty}dx=|A|^{2}\left(\infty\right)$ ...
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How can we fix the constant of the energy eigenstates of a quantum free particle such that they satisfy the orthonormality condition?

For a quantum free particle, the momentum and energy eigenstates are compatible. The constants of the momentum eigenstates are fixed by their orthonormality. Similarly, how can we fix the constant for ...
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For a quantum free particle, would it be possible to relate the wavefunction $a_E(E)$ in energy basis and $a_p(p)$ in momentum basis?

The energy for a free particle has continuous energy eigenvalues $E$. Let $u(E,x)$ be its energy eigenstates in position basis. Its wavefunction $\psi(x,t)$ can be expressed as \begin{align} ...
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Minimum uncertainity

I'm confused in finding the condition for minimum uncertainty, The author in the book I refer goes on saying that $|g\rangle=c|f\rangle$ is the condition for minimum uncertainity for some constant ...
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53 views

Tricky particle in an infinite potential well question

For a particle in an infinite square-well potential in an energy eigenstate, the probability distribution relating to outcomes of position measurements vanishes outside the square well and takes a ...
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50 views

In quantum descriptions of atoms why are observables (which we derive from the wave function) attributed to electrons?

For example the orbital angular momentum, for the hydrogen atom. Is this the total angular momentum of the atom(electron and proton) or just the electron? I am asking because, I am learning about how ...
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Why does the electron wave function collapse in a double slit experiment?

Did the electron wave function collapse in the double slit experiment due to being observed, OR is it that the electron wave function collapsed because the instrument used to measure it physically ...
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25 views

Find the eigen state of angular momentum for a trial wave function [closed]

If I have a simple trial wave function like this, $$\psi(r_x,r_y,r_z)=\exp(-v_1(r_x^2+r_y^2)-v_2r_z^2)$$ Can you tell me the detials for how to get the eigen state for $J=0$ for this wave function ...
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71 views

Physical interpretation of the constant coefficient appearing in solution to the Schrodinger equation

The product solution to the Schrodinger's equation is $$\Psi_{n} \left ( x,t \right )=\psi\left ( x \right )\phi\left ( t \right )$$ By superposition, the solution becomes $$\Psi \left ( x,t ...
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2answers
160 views

Why does the wavefunction have to be continuous in the presence of a Dirac delta potential?

Considering the time-independent Schrödinger equation, I can see for a finite potential, why the wavefunction has to be continuous, I can also see why the first derivative of the wavefunction is ...
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41 views

Propagation of momentum space wave function in linear potential [closed]

Under linear potential which denoted as $$V(x)=-Fx$$ Momentum space eigenket at time $t=0$ and some time $t$ has a relationship of $$\phi(p,t) = \mathrm{exp}\left[\frac{(p-Ft)^3-p^3}{6m\hbar ...
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Quantum Backaction Question

Question about quantum back action in hypothetical scenario: We know that, at $t_0$, a certain kind of particle, with spin initially prepared to be “spin right” in the x basis, goes through a ...
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Infinite square well physical interpretation

In quantum mechanics, the description of the infinite square well is given with the potential energy defined as $$V(x) = \begin{cases} 0 & \text{if } 0 \leq x \leq a,\\ \infty & ...
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1answer
81 views

Finite two-dimensional potential square well [closed]

I'm trying to solve the Schrodinger equation $$ -\frac{\hbar^2}{2m}\nabla^2 \psi+V(x,y)\psi(x,y)=E\psi(x,y) \tag{1}$$ for the finite two dimensional potential square well, that is, where ...
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Probability of measuring an observable $P$ in state $f$, computation [duplicate]

I have state vector $$f(x)=e^{-|x|+ix}$$ and observable $$P=-i\frac {d} {dx} $$ probability that measurement of $P$ in state $f$ will be in $[-1,1]$ I am stuck on this step. I dont know how to take ...