A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
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How to understand wavefunction in quantum mechanics in math

I am reading some introduction on quantum mechanics. I don't understand all but I get the point that the wavefunction tells some probability aspects. In one book, they show one example of the ...
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No well-defined frequency for a wave packet?

There are similar questions to mine on this site, but not quite what I am asking (I think). The de Broglie relations for energy and momentum $$ \lambda = \frac{h}{p}, \\ \nu = E/h .$$ equate a ...
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Overlap integral and probability

I have a question regarding how to extract probability from an overlap integral. Specifically, I am calculating the probability of a particle in a bound state in a delta potential $V=-\alpha ...
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819 views

Expectation value of total energy for the quantum harmonic oscillator [closed]

A particles unnormalized wavefunction is given as $$\psi(x)=2\psi_1+\psi_2+2\psi_3.$$ How can I find $\langle E\rangle $ without calculating $\langle T\rangle$ or $\langle V\rangle $ ...
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Workaround to fermion sign problem?

My (rather incomplete) understanding of the NP-hard fermion/numerical sign problem is that it occurs when attempting to converge on a wavefunction for many-body fermion systems (for example, a small ...
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Gaussian wave packet

At our QM intro our professor said that we derive uncertainty principle using the integral of plane waves $\psi = \psi_0(k) e^{i(kx - \omega t)}$ over wave numbers $k$. We do it at $t=0$ hence $\psi = ...
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Wavefunction's inner product

When two wavefunctions are orthogonal we can write that $$\langle\Psi_n|\Psi_m\rangle=\delta_{mn}$$ This means that $$\langle\Psi_1|\Psi_2\rangle=\langle\Psi_2|\Psi_1\rangle=0$$ But if the two ...
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Wave function decomposition

Problem: Given the wave function $\Psi_0=A\sin^2(\theta)$ along with the Hamiltonian operator of a physical system: $H=\frac{L^2}{2I}+g B L_z$, find the eigenvalues and eigenfunctions of $\hat{H}$ ...
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Why do wave packets spread out over time?

Why do wave functions spread out over time? Where in the math does quantum mechanics state this? As far as I've seen, the waves are not required to spread, and what does this mean if they do?
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Normalizing Wave Functions

We normalize the wave function to $1$, but couldn't we also normalize it to $-i$ as $(-i)^2=1$? Does this not work? Is it equivalent?
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Normalizing a Wave Function

How would I normalize the wave function: $ \psi (x)$ = $Ce^{i\rho_0x/\hbar}e^{-|x|/2\Delta x}$? I squared it, which got rid of the imaginary part-Then I considered breaking up the absolute value-but ...
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Transition integral from 1-D cartesian into 3-D polar coordinate system

Lets say we have an electron which can be in two states. Its wavefunction for two states is then $\Psi=A\Psi_n + B\Psi_m$, where $\Psi$ is time dependent wave function. I know that the transition ...
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Quantum states as rays as opposed to vectors

I recently read that a quantum state is actually defined by a ray and not a vector. That is it is possible to multiply a state $\psi$ by any complex number $c\in \mathbb{C}$ and you won't be changing ...
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Explicit solutions to 2-d Dirac Equation

The 2-d Dirac equation without any constants is represented usually as $$i*dt (\phi) = D (\phi)$$ where $D = m\sigma_2-i\sigma_1dx-i\sigma_3dy$. Where can I find explicit closed form solutions to ...
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What methods exist for us to measure the position and momentum of atoms that make up molecules?

In this paper, Localization of an atom by homodyne measurement. A. M. Herkommer et al. Quantum Semiclass. Opt. 8 no. 1, p. 189 (1996) (paywalled). the authors are able to localize atoms using ...
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Where does the wave function of the universe live? Please describe its home

Where does the wave function of the universe live? Please describe its home. I think this is the Hilbert space of the universe. (Greater or lesser, depending on which church you belong to.) Or maybe ...
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How to prove dp/dt = -dV/dx? Quantum mechanics [closed]

I got this problem from a book called Introduction to quantum mechanics, griffin 2nd edition. and I did not get why the solution says first term integrates to zero, integration by parts twice?! ...
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A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
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Implicit Postulate of Quantum Mechanics

Consider the following quantum system: a particle in a one dimensional box (= infinite potential well). The energy eigenstates wave functions all vanish outside the box. But the position eigenstates ...
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Sinusoidal Wave Displacement Function

I am learning about waves (intro course) and as I was studying Wave Functions, I got a little confused. The book claims that the wave function of a sinusoidal wave moving in the $+x$ direction is ...
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975 views

Expectation value of momentum

I'm having a problem with an expectation value that doesn't seem to add up for me. What I know is, that $\psi(\vec{r})$ is a wavefunction for a particle in three dimensions. The Hamiltonian is given ...
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Variational Derivation of Schrodinger Equation

In reading Weinstock's Calculus of Variations, on pages 261 - 262 he explains how Schrodinger apparently first derived the Schrodinger equation from variational principles. Unfortunately I don't ...
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Wavefunction as a combination of two stationary states - how to find those states?

Lets say we have a particle in a infinite square well which has a wavefunction like this ($A$ is some constant and $d$ is the width of the well): \begin{align} A\left[ \sin \left(\frac{2 \pi ...
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Confusion about wavefunction separability

A wavefunction is inherently a multi-particle function. If you have a container that is perfectly isolated from the external universe (not possible, but just imagine it) and filled with $n$ ...
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Historical background of wave function collapse

I wonder what were the main experiments that led people to develop the concept of wave function collapse? (I think I am correct in including the Born Rule within the general umbrella of the collapse ...
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Could quantum mechanics work without the Born rule?

Slightly inspired by this question about the historical origins of the Born rule, I wondered whether quantum mechanics could still work without the Born rule. I realize it's one of the most ...
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221 views

Orbital of Hydrogen molecule

does anybody here know an analytical approximation of the bonding hydrogen orbital MOLECULE? I am looking for a good approximation to this orbital, that might be in some textbooks to get an ...
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199 views

Why don't cancelling wavefunctions for two different particles give zero total wavefunction?

Let $\left|a\right>=e^{i(kx-\omega t)}$, $\left|b\right>=-e^{i(kx-\omega t)}$ be two neutral particles in the 1D free space without any interaction. Then ...
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The Energy Eigenvalue of a Wavefunction

I've been reading an introduction to quantum mechanics online, and while constructing the Schrodinger equation for a free particle, the equation $i\hbar \frac{d \Psi}{dt}=\hbar\omega\Psi$ is obtained. ...
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271 views

States and observables in quantum mechanics

I'm beginning learn quantum mechanics. As I understand, state is a map $\phi$ from $L^2(\mathbb R)$ such that $|\phi|^2$ describes probability density of a particle's position. By integrating ...
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538 views

Basic question on bra-ket notation

Which of the following corresponds to a $ \psi(x)$, a wavefunction written in the position basis: $ x| \psi\rangle $ or $ \langle x| \psi\rangle $? If it is the second expression (which my textbook ...
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Time Reversal Operator

I know that time reversal operator is an antiunitary operator. How does it work on wavefunctions? I believe in this way: $$T \psi (k,+)=e^{i\pi S_y/\hbar} K \psi (k,+) = \psi^*(-k,-),$$ but I am not ...
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Solving a time independent Schrödinger equation with a given potential

I'm trying to rework this old homework problem, and I am having problems arriving at the same solution on the answer sheet: Let $$V(x)=\begin{cases}\infty &\text{ if } x < 0\\ ...
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560 views

Solution of 1-D Schrodinger equation for the potential $V(x) = -\frac{1}{|x|}$

May be this question might have already been asked but i couldn't find it, so let me know if its already there. Consider a potential, $V(x) = -\frac{1}{|x|}$ and if we apply this to a one dimensional ...
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Writing wave functions with spin of a system of particles

Suppose I have 2 fermions in a potential $V(x)$. Both particles are moving in one dimension: the $x$ axis. Then, neglecting the interaction between the particles, the spatial wave function of the ...
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What does the wavefunction of atom look like at low temperature?

I am reading an introduction material on Bose-Einstein condensation (BEC) at low temperature and it stated that when the temperature approaches zero kelvin, almost all atoms are degenerated into the ...
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Wavefunction operators and the observable [closed]

So I got this from the exam I had yesterday. I couldn't really answer it other and it played on my mind through the night Show that if a wave function $\psi$ , is an eigenfunction of an operator [Q], ...
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A quantum particle which is almost at rest but whose position is random!

Assume a particle is given by a quantum state which is constructed in such a way that it is equally probable to find it anywhere in an fixed interval $(0,L)$ but has arbitrarily low velocity. The ...
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244 views

Is normalization consistent with Schrodinger's Equation?

Schrodinger's Equation does not set a limit on the size of wave functions but to normalize a wave function a limit must be set. How is this consistent physically and mathematically with Schrodinger's ...
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Schrödinger equation in position representation

$$ \DeclareMathOperator{\dif}{d \!} \newcommand{\ramuno}{\mathrm{i}} \newcommand{\exponent}{\mathrm{e}} \newcommand{\ket}[1]{|{#1}\rangle} \newcommand{\bra}[1]{\langle{#1}|} ...
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Meaning of inner product $\langle \vec{r} | \psi(t)\rangle $

I have come across the equation which comes out of the nothing in Zettili's book Quantum mechanics concepts and applications p. 167: $$\psi(\vec{r},t) ~=~ \langle \vec{r} \,|\, \psi(t) \rangle.$$ ...
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Decomposition of this wave function in eigenfunctions

I have this wave function of a system on a central potential: $V(r)$: $$\Phi(x,y,z)=C(x+y+z)e^{-\alpha r^2}.$$ And I'm asked a few things about probabilities. I don't have problems with that, because ...
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Problem from Sakurai about a delta-function potential [closed]

Can you help me with this problem from Sakurai: A particle of mass m in one dimension is bound to a fixed center by an attractive delta-function potential: $$V(x) ~= ~-a\delta(x) , \qquad ...
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Why do people say the phase oscillates in time and the amplitude stays the same but the intensity of a traveling beam does oscillate with time?

I'm confused why people say the phase oscillates in time and the amplitude stays the same (the reason for having complex numbers). But on the other hand, the intensity of a traveling beam does ...
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Text interpretation in Griffith's intro to QM

It says in Griffith's chapter 2.1, that: $$\tag{2.14} \Psi(x,t)~=~\sum_{n=1}^{\infty}c_n\,\psi_n(x) e^{(-iE_n t/\hbar)}$$ It so happens that every solution to the (time-dependent) Schrodinger ...
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Expectation value of position in infinite square well

I'm looking for some help to a question. I'm working in the infinite square well, and I have the wavefunction: $$\psi(x,t=0)=A\left( i\sqrt{2}\phi_{1}+\sqrt{3}\phi_{2} \right).$$ For every time t, ...
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First-order pertubation theory

I'm having some trouble figuring this out, so I was hoping someone could help. I need to show that the first-order pertubation of the ground state energy is not changed by the pertubation $H'$, given ...
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Infinite Potential Well Energy for Piece-wise Constant Wave Function

I'm trying to compute the expectation value of energy for a certain state in an infinite potential well but I'm getting contradictory answers. The well has potential \begin{align} V(x) = \left\{ ...
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Harmonic oscillator - wavefunctions

I understand now how I can derive the lowest energy state $W_0 = \tfrac{1}{2}\hbar \omega$ of the quantum harmonic oscillator (HO) using the ladder operators. What is the easiest way to now derive ...