A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Meaning of $C$ in wavefunction equation ($\Psi_{MO} = C_1\phi_A(1s) + C_2\phi_B(1s)$, where $C_1=\pm C_2$)

I've just cracked open a biophysics textbook and it's all fine up until the introduction of the letter C in a wavefunction equation, and declaring C1= ±C2 I've had lectures on eigenfunctions etc. ...
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Physical interpretation of normalization of wave fuctions

Does normalization of wave function mean that we are getting our state vector to unit length? If that's the case what does it mean physically? Also is the underlying vector space finite dimensional? ...
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1answer
332 views

Quantum Mechanics - Rectangular Potential Barrier - Normalisation

I have a quick question regarding the normalisation of the wave function of a particle incident on a potential barrier specifically regarding the normalisation of the wave functions. The problem is ...
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1answer
106 views

Obtain the eigenfunction of Jz for the wave function of an electron in a hydrogen atom? [closed]

The wave function of an electron in a hydrogen atom is given by Is this wave function an eigenfunction of Jz , the z-component of the electron’s total angular momentum? If yes, find the ...
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979 views

Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ ...
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Physical position eigenfunction normalisation

We know that the Dirac function $$\delta(a)=\lim_{a \rightarrow 0} \delta_{a}(x)$$ can be written as an infinitesimally narrow Gaussian: $$ \delta_{a}(x) := \frac{1}{\sqrt{2\pi a^2}}e^{-x^2/2a^2}$$ ...
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116 views

Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
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Calculating the expectation value of a Hamiltonian

I want to calculate the expectation value of a Hamiltonian. I have a wave function that is $$\psi = \frac{1}{\sqrt{5}}(1\phi_1 + 2\phi_2).$$ I want to know if I set this up properly. The ...
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137 views

Why don't we need to normalize wavefunction to find probability distribution?

Consider an unormalized wavefunction of a rotor at $t = 0$, a combination of $n=0$ and $n=2$ states: $$\psi(\phi) = 3 - 2 \cos (2\phi).$$ Find the probability distribution in angle. The ...
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225 views

Can a wave possess spin?

Since a matter wave is associated with a particle in quantum mechanics, does the wave spins? I mean, can we visualize the spinning of wave or is it possible that the wave spins?
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126 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
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444 views

Normalizing the sum of wavefunctions and calculating probabilty - understanding concepts

A state of a particle bounded by infinite potential walls at x=0 and x=L is described by a wave function $\psi = a\phi_1 + b\phi_2 $ where $\phi_i$ are the stationary states. So let's say we want to ...
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3answers
705 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
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1answer
624 views

Transmission and reflection

What is the transmission amplitude of a wavefunction $\phi(x)=e^{ikx}(\tanh x -ik)$? I would have thought that it is $\tanh x -ik$ since this is the factor associated with the forward travelling ...
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328 views

Why is $|\Psi|^2$ the probability density?

I am starting with Quantum Mechanics, learning online. I can't seem to find the reason for $|\Psi|^2$ being the probability density of finding an electron. They've just taken it for granted ...
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148 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
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2answers
2k views

Calculating the most probable radius for an electron of a hydrogen atom in the ground state

This link describes a method for determining the most probable radius of an electron for a Hydrogen atom in the ground state. It states that : The radial probability density for the hydrogen ...
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70 views

How will a particle with energy less than $V_{\rm min}$ behave?

Consider e.g. the finite square well: $V = -V_o$ between $x=-a$ and $x=a$, $V=0$ elsewhere Now for scattering states, $E$ must be $> 0$. For normalizable bound states, $E$ must be $< 0$ and ...
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52 views

Potential Step - Choosing Wavefunctions

http://uqu.edu.sa/files2/tiny_mce/plugins/filemanager/files/4190016/Quantum_Mechanics_1/ch4-virtual-book.pdf On page 2 of the above pdf they describe how they select their wavefunctions. Finding the ...
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1answer
238 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
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2answers
115 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
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174 views

Solving the 1D Schrodinger Equation for a Free Particle - Two Different Methods?

So starting from the time dependent schrodinger equation I perform separation of variables and obtain a time and spatial part. The spatial part is in effect the time independent schrodinger equation. ...
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59 views

Calculating the Probability Current of a Travelling Wave

Calculate the probability current density vector $\vec{j}$ for the wave function : $$\psi = Ae^{-i(wt-kx)}.$$ From my very poor and beginner's understanding of probability density current it is : ...
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Apply the Heisenberg Equation to the Hamiltonian [closed]

$\frac{d}{dt}$$\hat{H}$ = $\frac{i}{\hbar}$$[\hat{H},\hat{H}]$ +$\frac{\partial{\hat{H}}}{\partial{t}}$ That's as far as I've got. I do not know much about the Heisenberg equation or even what it ...
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217 views

Expectation Values and Derivation of Heisenberg Equation?

Consider a system of particles with wave function $\psi$(x) (x can be understood to stand for all degrees of freedom of the system; so, if we have a system of two particles then x should represent ...
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178 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
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62 views

Wave function - Working towards Orthonormal solution

As you can see below, the two pages attached describe how to obtain the final solution of orthonormality. I do not completely follow the discussion but I will talk you through what I DO understand ...
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147 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
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KdV equation and classical linear wave equation

Like we know, the standard form of KdV equation is $$u_{t}-6uu_{x}+u_{xxx}=0,\tag{1}$$ where this equation describes a solitary wave propagation and $u=u(x,t)$. On the other hand, we know the ...
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247 views

What happens to the wave function after applying the D'Alembert operator?

Is the result of applying the D'Alembert operator on a wave function always zero? Or are there exceptions?
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Is there a direct physical interpretation for the complex wavefunction?

The Schrodinger equation in non-relativistic quantum mechanics yields the time-evolution of the so-called wavefunction corresponding to the system concerned under the action of the associated ...
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69 views

Free particle Schrödinger Equation

Some sources give the free-particle solution to Schrödinger equation as $$\psi(x,t) =Ae^{i(kx-\omega t)} + Be^{-i(kx+\omega t)}$$ while some sources give it as $$\psi(x,t) =Ae^{i(kx-\omega t)}$$ ...
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289 views

Why do we must initially assume that the wavefunction is complex?

The sound waves are real, and they can interfere, so corresponding apparat may be used in quantum mechanics. We also may use the time dependence in a form of orthogonal matrix multiplying the initial ...
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What is probability current in quantum mechanics?

What is probability current in quantum mechanics? Why define such a thing? I mean the meaning of probability current. I know the formula for it but I just don't get the idea of a flow of probability ...
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65 views

Reflection of an evanescent matter wave within a finite barrier?

To my understanding if I have a finite barrier with potential $V(x)>E$, then to the left of the barrier, the wavefunction can be represented as two exponentials: $$\psi= e^{(ik_{left} x)} + ...
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730 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
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1answer
4k views

What does $\Psi^*$ mean in Schrodinger's formulation of Quantum Mechanics?

I am not a physics student. In one of my courses, some fundamental concepts of Quantum mechanics were needed, so I was going through them when I stumbled upon this. It says $$\text{probability} = ...
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492 views

Why complex functions for explaining wave particle duality?

I have this very bad habit of going to the scratch, discarding all the developments of a theory and worldly knowledge, and ask some fundamental (mostly stupid and naive, as some may say) questions as ...
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107 views

Momentum Operator in Quantum Mechanics

1) What is the difference between these two momentum operators: $\frac{\hbar}{i}\frac{\partial}{\partial x}$ and $-i\hbar\frac{\partial}{\partial x}$? How are these two operators the same? My ...
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1answer
282 views

Expectation value of energy from the position state of hydrogen atom [closed]

I was given with the position state of hydrogen atom: $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ I am getting confused about getting the expectation value of ...
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355 views

The formal solution of the Schrodinger equation

Let's have Schrodinger equation (or some equation in Schrodinger form) $$ \tag 1 i \partial_{0} \Psi ~=~ \hat{H} \Psi . $$ One likes to write that it has formal solution $$ \tag 2 \Psi (t) ~=~ ...
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257 views

Harmonic Oscillator potential, proof that Gaussians remain Gaussians?

I read in several papers that for a Harmonic Oscillator Hamiltonian in the time dependent Schrödinger equation a Gaussian wave packet remains Gaussian. Unfortunately I could not find any proof for ...
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1answer
607 views

Correspondence between wave function and state vector

I am confused with connection between state $| \psi \rangle$ of a quantum system and corresponding wave function $\psi(x)$ (at a given time). I have been told that for every state $| \psi \rangle$ we ...
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27 views

Learning about group velocity, phase velocity and particle velocity [duplicate]

I am studying quantum physics and I would like to know a bit more in detail about group velocity, particle velocity and phase velocity. Can you guys suggest some books/online resources where I can ...
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Confusion about state of a quantum system

I am confused with the concept of state of a quantum system. First postulate of QM ussualy says that the wave function of the system contains all information about the state of the system. But reading ...
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92 views

Regarding derivation of Probability Current

The question for the full derivation of Probability Conservation -> Probability Current was already asked here: Probability current. I apologize for not retyping it out, but it's already beautifully ...
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530 views

Two ways of calculating the expectation value of momentum

The expectation value of momentum is given by: $$ \langle p\rangle = \int_{-\infty}^{\infty}\psi^{*}(x)\left(-i\hbar\frac{\partial}{\partial x}\right)\psi(x)dx $$ How can I show that the above ...
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80 views

Group velocity of localized wavepacket

This is a Homework problem so please feel free to not answer and just give pointers. A localized wavepacket is given as: $$\Phi(r,t=0 ) = \frac { e^{-\large\frac {r^2}{2s^2}} e^{\large\frac{i\pi ...
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Probability current

Conservation of probability: Suppose a wavefunction has ${\partial \mathbb P \over \partial t} = -t f(x,t)$ and ${\partial j \over \partial x} = i f(x,t)$. How does it follow that ${\partial \mathbb P ...