A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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97 views

Momentum representation of a function with discontinuous derivative [closed]

Consider the following wave packet $$\psi = Ce^{2\pi i p_0x/h}e^{-|x|/(2\Delta x)}$$ where $h$ is the Planck's constant and $C$ is the normalization constant. The derivative of this function is ...
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1answer
274 views

Probability current vs. direction of wave function

I did an exercise for my Quantum-Mechanics Lecture: Let $\hbar$=2m=1. A particle in 1 dimension has $j(x)=2\ Im(\overline{\psi} (x) \ \psi'(x))$ and it's to show that there are superpositions $\psi ...
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2answers
469 views

Understanding the Wave Function and Excited States

A wave function is an infinite dimensional vector space, how can it "live" in $\mathbb{R}^3$? Given the equation that is built like: $$\Psi (x,t) = \sum ^{\infty} _{n=1} c_n \psi _n (x) e^{-i E_n t / ...
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1answer
736 views

Orthonormality of Radial Wave Function

Is the radial component $R_{n\ell}$ of the hydrogen wavefunction orthonormal? Doing out one of the integrals, I find that $$\int_0^{\infty} R_{10}R_{21}~r^2dr ~\neq~0$$ However, the link below says ...
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512 views

Wave function collapse

When we try to measure the position of a system, wavefunction collapses to form a spike. After a while, the wavefunction spreads again, and you take another measurement, the results will be different" ...
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718 views

Writing a Wavefunction as a Linear Combination of Eigenstates

We have the following wavefunction for the hydrogen atom: $$\psi(r,\theta,\phi)=\frac{1}{\sqrt{4\pi}}\frac{1}{(2a)^{3/2}}\frac{r}{a}e^{-r/2a}\sin(\theta)\sin(\phi)$$ where $a$ is the Bohr radius. ...
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1answer
227 views

Majorana wavefunction

I'm trying to compute the wavefunction for a Majorana state in an nanowire/superconductor hybrid system, like arXiv: Majorana Fermions and a Topological Phase Transition in ...
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1answer
312 views

Confusion about the probability cloud

What is the meaning of the electron probability cloud? I understood it to mean that the electron has a probability to be found in a certain postion before measurement, but now after reading ...
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5answers
886 views

Infinite Wells and Delta Functions

In considering a delta potential barrier in an infinite well, I can just enforce continuity at the potential barrier-it doesn't have to go to zero. Why then does it need to go to zero at the walls of ...
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1answer
553 views

Why is the wave function complex? [duplicate]

Why should an equation (TDSE) in which first time derivative is related to second space derivative have a solution that contains $i$?The wave function is supposed to be complex, but I am unable to ...
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4answers
397 views

Reconstruction of “wavefunction” phases from $|\psi(x)|$ and $|\tilde \psi(p)|$

Consider a "wavefunction" $\psi(x)$, which has a Fourier transform $\tilde \psi(p)$ Suppose that we know, for each $x$, $|\psi(x)|^2$, and that we know, for each $p$, $|\tilde \psi(p)|^2$. Have we ...
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1answer
194 views

In Schrödinger equation, can we get $\Psi$ if we know $\varphi(n)$?

Let $A$ be a mechanical quantity and we know its eigenfunction $\varphi(n)$. Can we get its wave function $\Psi$, if we measure $A$ for many (maybe infinite) times at the same time?
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1answer
378 views

Tunnelling through a Dirac potential barrier

I am reading a QM book by Griffiths, which says it is possible for wave particle to tunnel through a barrier formulated by a Dirac function. This function is known to peak at infinity and also ...
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2answers
153 views

Does Schrödinger equation have dual-property with Heat equation?

I have experimental data that Schödinger equation maintains high frequencies, while heat equation low. Does Schrödinger equation have some duality property with heat equation?
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2answers
226 views

How to understand wavefunction in quantum mechanics in math

I am reading some introduction on quantum mechanics. I don't understand all but I get the point that the wavefunction tells some probability aspects. In one book, they show one example of the ...
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1answer
2k views

How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
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1answer
283 views

Quantum harmonic Oscillator analytic method

I'm using a book from Griffiths, I got really stuck about how he arrived at the approximate solution, is it just by trying( trial solution method?), I really appreciate any help on this. ...
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1answer
307 views

Given wave function at $t=0$, what is the process of deriving time dependent wave equation? [closed]

Suppose $$\Psi (x, t=0)=Ae^{i\alpha _1}\psi _1(x)+Be^{i\alpha _2}\psi_2(x)+Ce^{i\alpha _3}\psi_3(x).$$ If $\psi _n$ are the energy eigenfunctions how would I derive $\Psi (x,t)$? I am having trouble ...
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1answer
1k views

Overlap integral and probability

I have a question regarding how to extract probability from an overlap integral. Specifically, I am calculating the probability of a particle in a bound state in a delta potential $V=-\alpha ...
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1answer
817 views

Expectation value of total energy for the quantum harmonic oscillator [closed]

A particles unnormalized wavefunction is given as $$\psi(x)=2\psi_1+\psi_2+2\psi_3.$$ How can I find $\langle E\rangle $ without calculating $\langle T\rangle$ or $\langle V\rangle $ ...
2
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2answers
165 views

Workaround to fermion sign problem?

My (rather incomplete) understanding of the NP-hard fermion/numerical sign problem is that it occurs when attempting to converge on a wavefunction for many-body fermion systems (for example, a small ...
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1answer
144 views

Meaning of $C$ in wavefunction equation ($\Psi_{MO} = C_1\phi_A(1s) + C_2\phi_B(1s)$, where $C_1=\pm C_2$)

I've just cracked open a biophysics textbook and it's all fine up until the introduction of the letter C in a wavefunction equation, and declaring C1= ±C2 I've had lectures on eigenfunctions etc. ...
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3answers
146 views

Non-normalizable QM bound state in 4 spatial dimensions?

Edit 26/Sept/13: Fixed Typo in potential I'm solving the following (seemingly simple) quantum-mechanical problem in four spatial dimensions. In natural units ($\hbar^2/2m=1$), the Schrödinger ...
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1answer
129 views

Wavefunction's inner product

When two wavefunctions are orthogonal we can write that $$\langle\Psi_n|\Psi_m\rangle=\delta_{mn}$$ This means that $$\langle\Psi_1|\Psi_2\rangle=\langle\Psi_2|\Psi_1\rangle=0$$ But if the two ...
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386 views

Wave function decomposition

Problem: Given the wave function $\Psi_0=A\sin^2(\theta)$ along with the Hamiltonian operator of a physical system: $H=\frac{L^2}{2I}+g B L_z$, find the eigenvalues and eigenfunctions of $\hat{H}$ ...
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3answers
771 views

When Eigenfunctions/Wavefunctions are real?

When the Hamiltonian is Hermitian(i,e. beyond the effective mass approximation), generally under which conditions the eigenfunctions/wavefunctions are real? What happens in 1D case like the finite ...
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6answers
1k views

Why do wave packets spread out over time?

Why do wave functions spread out over time? Where in the math does quantum mechanics state this? As far as I've seen, the waves are not required to spread, and what does this mean if they do?
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1answer
214 views

Normalizing a Wave Function

How would I normalize the wave function: $ \psi (x)$ = $Ce^{i\rho_0x/\hbar}e^{-|x|/2\Delta x}$? I squared it, which got rid of the imaginary part-Then I considered breaking up the absolute value-but ...
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1k views

Normalizing Wave Functions

We normalize the wave function to $1$, but couldn't we also normalize it to $-i$ as $(-i)^2=1$? Does this not work? Is it equivalent?
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272 views

Quantum states as rays as opposed to vectors

I recently read that a quantum state is actually defined by a ray and not a vector. That is it is possible to multiply a state $\psi$ by any complex number $c\in \mathbb{C}$ and you won't be changing ...
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1answer
136 views

Explicit solutions to 2-d Dirac Equation

The 2-d Dirac equation without any constants is represented usually as $$i*dt (\phi) = D (\phi)$$ where $D = m\sigma_2-i\sigma_1dx-i\sigma_3dy$. Where can I find explicit closed form solutions to ...
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1answer
1k views

How to prove dp/dt = -dV/dx? Quantum mechanics [closed]

I got this problem from a book called Introduction to quantum mechanics, griffin 2nd edition. and I did not get why the solution says first term integrates to zero, integration by parts twice?! ...
2
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3answers
247 views

Implicit Postulate of Quantum Mechanics

Consider the following quantum system: a particle in a one dimensional box (= infinite potential well). The energy eigenstates wave functions all vanish outside the box. But the position eigenstates ...
2
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1answer
1k views

A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
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2answers
151 views

Transition integral from 1-D cartesian into 3-D polar coordinate system

Lets say we have an electron which can be in two states. Its wavefunction for two states is then $\Psi=A\Psi_n + B\Psi_m$, where $\Psi$ is time dependent wave function. I know that the transition ...
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312 views

Confusion about wavefunction separability

A wavefunction is inherently a multi-particle function. If you have a container that is perfectly isolated from the external universe (not possible, but just imagine it) and filled with $n$ ...
3
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2answers
917 views

Wavefunction as a combination of two stationary states - how to find those states?

Lets say we have a particle in a infinite square well which has a wavefunction like this ($A$ is some constant and $d$ is the width of the well): \begin{align} A\left[ \sin \left(\frac{2 \pi ...
2
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1answer
221 views

Orbital of Hydrogen molecule

does anybody here know an analytical approximation of the bonding hydrogen orbital MOLECULE? I am looking for a good approximation to this orbital, that might be in some textbooks to get an ...
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2answers
2k views

The Energy Eigenvalue of a Wavefunction

I've been reading an introduction to quantum mechanics online, and while constructing the Schrodinger equation for a free particle, the equation $i\hbar \frac{d \Psi}{dt}=\hbar\omega\Psi$ is obtained. ...
2
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3answers
271 views

States and observables in quantum mechanics

I'm beginning learn quantum mechanics. As I understand, state is a map $\phi$ from $L^2(\mathbb R)$ such that $|\phi|^2$ describes probability density of a particle's position. By integrating ...
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2answers
538 views

Basic question on bra-ket notation

Which of the following corresponds to a $ \psi(x)$, a wavefunction written in the position basis: $ x| \psi\rangle $ or $ \langle x| \psi\rangle $? If it is the second expression (which my textbook ...
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1answer
238 views

What happens to the wave function after applying the D'Alembert operator?

Is the result of applying the D'Alembert operator on a wave function always zero? Or are there exceptions?
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1answer
1k views

Time Reversal Operator

I know that time reversal operator is an antiunitary operator. How does it work on wavefunctions? I believe in this way: $$T \psi (k,+)=e^{i\pi S_y/\hbar} K \psi (k,+) = \psi^*(-k,-),$$ but I am not ...
9
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1answer
2k views

Variational Derivation of Schrodinger Equation

In reading Weinstock's Calculus of Variations, on pages 261 - 262 he explains how Schrodinger apparently first derived the Schrodinger equation from variational principles. Unfortunately I don't ...
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1answer
560 views

Solution of 1-D Schrodinger equation for the potential $V(x) = -\frac{1}{|x|}$

May be this question might have already been asked but i couldn't find it, so let me know if its already there. Consider a potential, $V(x) = -\frac{1}{|x|}$ and if we apply this to a one dimensional ...
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1answer
823 views

Solving a time independent Schrödinger equation with a given potential

I'm trying to rework this old homework problem, and I am having problems arriving at the same solution on the answer sheet: Let $$V(x)=\begin{cases}\infty &\text{ if } x < 0\\ ...
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1answer
191 views

Wavefunction operators and the observable [closed]

So I got this from the exam I had yesterday. I couldn't really answer it other and it played on my mind through the night Show that if a wave function $\psi$ , is an eigenfunction of an operator [Q], ...
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3answers
2k views

Writing wave functions with spin of a system of particles

Suppose I have 2 fermions in a potential $V(x)$. Both particles are moving in one dimension: the $x$ axis. Then, neglecting the interaction between the particles, the spatial wave function of the ...
4
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2answers
266 views

A quantum particle which is almost at rest but whose position is random!

Assume a particle is given by a quantum state which is constructed in such a way that it is equally probable to find it anywhere in an fixed interval $(0,L)$ but has arbitrarily low velocity. The ...
5
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2answers
468 views

Schrödinger equation in position representation

$$ \DeclareMathOperator{\dif}{d \!} \newcommand{\ramuno}{\mathrm{i}} \newcommand{\exponent}{\mathrm{e}} \newcommand{\ket}[1]{|{#1}\rangle} \newcommand{\bra}[1]{\langle{#1}|} ...