A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
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974 views

Why does a plane wave have definite momentum?

Apologies if this is a little vague. It might not have a good answer. Given the interpretation of $|\psi(x)|^2$ as a probability distribution it's unsurprising that a wave function that is ...
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334 views

Why the hydrogen radial wave function is real?

Why the hydrogen radial wave function is real? Is it a coincidence?
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In the expansion of the scattered wave function, why do these two functions have the same index?

See Griffiths Quantum Mechanics, eq. 11.21. Evidently, $$\psi(r,\theta,\phi)=Ae^{ikz}+A\sum\limits_{l,m}^{\infty}C_{l,m}h_{l}(kr)Y_{l}^{m}(\theta,\phi).$$ But I don't see why the $l$th Hankel function ...
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What's the physical significance of the inner product of two wave functions in quantum region?

I am a reading a book for beginners of the quantum mechanics. In one section, the author shows the inner product of two wave functions $\langle\alpha\vert\beta\rangle$. I am wondering what's the ...
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295 views

Does quantum mechanics predict instantaneous action at a distance even without entanglement?

The suggestion that quantum mechanics implies that instantaneous action at a distance occurs is normally based on the contention that this follows from the entanglement of particles that share a ...
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559 views

If wave packets spread, why don't objects disappear?

If you have an electron moving in empty space, it will be represented by a wave packet. But packets can spread over time, that is, their width increases, with it's uncertainty in position increasing. ...
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594 views

How do I solve these integrals of wave function and operator?

First integral $$\int \Psi^*({\bf r},t)\hat {\bf p} \Psi({\bf r},t)\, d^3r,$$ where the $\Psi({\bf r},t)=e^{i({\bf k}\cdot{\bf r}-\omega t)}\,\,\,$ and $\hat {\bf p}=-i\hbar \nabla$. Second one ...
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Superposition of wavefunctions

Suppose you have 2 normalized wavefunctions $\psi_1=Ne^{iax}e^{if(x)}e^{i\omega t}$ and $\psi_2=Ne^{-iax}e^{if(x)}e^{i\omega t}$ defined on $x\in [-x_0,x_0]$ and vanishes for $|x|>x_0$. What then ...
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607 views

Simple rotation of an atomic orbital wavefunction

We know that an atomic orbital wavefunction may be written in terms of polar coordinates, $$\psi (r, \theta, \phi) = R(r) A(\theta, \phi)$$ where $R(r)$ is the radial component and $A(\theta, \phi)$ ...
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Is de Broglie matter wave a mass or a particle hypothesis?

I'm having difficulty understanding de Broglie matter wave hypothesis. It is a mass or a particle hypothesis? According to de Broglie a particle with mass $m$ moving at a constant speed has an ...
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Why do wave functions need to be normalized? Why aren't the normalized to begin with? [duplicate]

Before I started studying quantum mechanics, I thought I knew what normalization was. Just pulling off Google, here's a definition that matches what I've understood normalization to mean: ...
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What is the energy of a Gaussian wave packet?

Suppose we have a potential barrier situation, that is $V(x)$ is zero everywhere except on the interval $[-a,a]$, where it is equal to some $V_0 > 0$. Introduce some Gaussian shaped wave packet to ...
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54 views

Does an excited state wave function depend on state preparation?

Consider a quantum system with a ground state and many excited states (e.g. an atom). If the system is in an excited state, to what extent does its wave function depend on the method of state ...
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186 views

The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...
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86 views

Does the wave function of a particle completely describe the state of the particle?

In classical mechanics, if you know the position and momentum of a particle at time $t$ and the Hamiltonian, you can predict the particle's position and momentum at any time. In quantum mechanics, if ...
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Calculating the most probable radius for an electron of a hydrogen atom in the ground state

This link describes a method for determining the most probable radius of an electron for a Hydrogen atom in the ground state. It states that : The radial probability density for the hydrogen ...
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Entropy before and after collapse of the wavefunction/ and interpretation?

Seems like it might be pretty rudimentary but I want to see if my thinking is on the right track as well as what the result means. The question is, is the entropy of the collapse of a wavefunction or ...
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151 views

Three dimensional wave packets in momentum space

I am given the 3D wave packet: $$\psi(x,y,z)=N\,\exp\left(\frac{-(x^2+y^2+2z^2)}{2a^2}\right).$$ I was asked to find N (easy enough). Then I was asked the probability that we measure $z$ greater than ...
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76 views

Transition from coordinate space to momentum space for SHO

I am given that the ground state of the SHO in position space is given as $$\langle q|\psi_0\rangle=\frac{1}{a^{\frac12}\pi^{\frac14}}e^{-q/4a^2}$$ Where a is a constant with units of length. I am ...
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662 views

Solving quantum radial equation for infinite potential spherical annulus for $l=0$

There is a mass $m$ in a potential such that $$ V(r) = \left\{ \begin{array}{lr} 0, & a \leq r \leq b\\ \infty, & \text{everywhere else} \end{array} \right. $$ ...
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Bloch wave function orthonormality?

there is this text book that is giving me a hard time for a while now: It shows that Bloch wave functions can be written as $$\Psi_{n\vec{k}}\left(\vec{r}\right) = \frac{1}{\sqrt{V}}e^{i\vec k \vec ...
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127 views

Product of position eigenvectors at different times

I've been thinking about this, and it might sound like a stupid question, but I can't seem to find an answer anywhere, here goes: Whenever we calculate expecation-values between two position ...
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Overlap integral and probability

I have a question regarding how to extract probability from an overlap integral. Specifically, I am calculating the probability of a particle in a bound state in a delta potential $V=-\alpha ...
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A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
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Writing wave functions with spin of a system of particles

Suppose I have 2 fermions in a potential $V(x)$. Both particles are moving in one dimension: the $x$ axis. Then, neglecting the interaction between the particles, the spatial wave function of the ...
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Decomposition of this wave function in eigenfunctions

I have this wave function of a system on a central potential: $V(r)$: $$\Phi(x,y,z)=C(x+y+z)e^{-\alpha r^2}.$$ And I'm asked a few things about probabilities. I don't have problems with that, because ...
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268 views

Harmonic oscillator - wavefunctions

I understand now how I can derive the lowest energy state $W_0 = \tfrac{1}{2}\hbar \omega$ of the quantum harmonic oscillator (HO) using the ladder operators. What is the easiest way to now derive ...
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438 views

In Dirac notation, what do the subscripts represent? (Solution for particle in a box in mind)

So the set of solutions for the particle in a box is given by $$\psi_n(x) = \sqrt{\frac{2}{L}}\sin(\frac{n\pi x}{L}).$$ In Dirac notation $<\psi_i|\psi_j>=\delta_{ij}$ assuming $|\psi_i>$ ...
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Solving the time independent Schrodinger equation: Does a complex solution make sense?

In my notes, I have the Time Independent Schrodinger equation for a free particle $$\frac{\partial^2 \psi}{\partial x^2}+\frac{p^2}{\hbar^2}\psi=0\tag1$$ The solution to this is given, in my notes, ...
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Non-Degeneracy of Eigenvalues of Number Operator for Simple Harmonic Oscillator [duplicate]

Possible Duplicate: Proof that the One-Dimensional Simple Harmonic Oscillator is Non-Degenerate? I'm trying to convince myself that the eigenvalues $n$ of the number operator ...
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Bound States in a Double Delta Function Potential [closed]

Let $V(x) = −u \delta(x) - v \delta(x − a)$ where $u, v > 0$ correspond to a potential with two $\delta$ wells. Let $v > u$. If $a$ is very large, there is certainly a bound state: the particle ...
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Does wavefunction reach its largest peak near(not in) the classical forbidden region?

As we can see in the picture in this website: http://ctz116.ust.hk/xyli2/images/animation/quchem73.html It's strange that the bound state wavefunction always reach its largest peak near the boundary ...
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296 views

Considering the wave function is not 'real', what is interfering?

I find the idea of the wave function being 'just' a collection of numbers (probabilities) quite alluring, and elegant in explaining away the whole 'collapse' business (see Luboš' answer to this ...
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Why Pauli exclusion instead of electrons canceling out?

To quote Wikipedia, The Pauli exclusion principle is the quantum mechanical principle that no two identical fermions (particles with half-integer spin) may occupy the same quantum state ...
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Angular momentum operator and expectation values

I was reading some notes and it says that $\langle L_z^2\rangle=\langle L^2\rangle$ IFF the system is radially symmetric. I can see that in order that the LHS of the statement implies that $\langle ...
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How to calculate time evolution of a wave function in an 1D infinite square well potential?

A particle in an infinite square well has an initial wavefunction $$\psi (x,0) ~=~ Ax(a-x) \qquad \mathrm{for}\qquad 0\leq x\leq a.$$ Now the question is to calculate $\psi (x,t)$. I have ...
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Are Everettian branchings global or local?

Everett's theory of quantum mechanics is about the wavefunction of the whole universe holistically. If a branching occurs very far away at the Andromeda galaxy, do I also branch? Are branchings global ...
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Can someone clarify what should and should not be an operator in my verification of the 1D solution to the SE for a free particle?

I just worked out the 1D free particle solution to the Schrödinger equation. My wave function was \begin{equation} \psi(x,t) = Ae^{i(px-Et)/\hbar} \end{equation} So I plugged this into both sides ...
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Wave functions as $x$ goes to infinity

This problem emerged when I was going through some QM exercises: I've been asked to find the commutator $[A,B]$ where $A,B$ are defined as $$A\psi(x)=x\frac{\partial }{\partial x}\psi(x),$$ ...
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Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
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Wavefunction of isomers

In quantum chemistry, the wavefunction for a molecule can be viewed as the output of a function $\xi(m, n_1,..., n_k)$ with $m, n_i \in \mathbb{Z}^+$ that returns a $|\psi\rangle$ that satisfies a ...
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100 views

Koopmann von Neumann (KvN) Theory

I was just wondering does anyone have any informative sources apart from the obvious wikipedia articles regarding Koopmann von Neumann (KvN) theory? Or if its possible could someone explain the basic ...
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Eigenfunctions corresponding to degenerate spectra

It is well knwon that an eigenstate can be obtained by superposing wavepackets. In other words, if $\Psi({\bf x},t)$ is the solution of the time dependent Schroedinger equation for an initial ...
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On use of Hamiltonians for Helium

The Hamiltonian of helium can be expressed as the sum of two hydrogen Hamiltonians and that of the Coulomb interaction of two electrons. $$\hat H = \hat H_1 + \hat H_2 + \hat H_{1,2}.$$ The wave ...
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Kronig-Penney model

I am studying the Kronig-Penney model as treated in the book by Kittel: Introduction to Solid State Physics. In this model one considers a period potential which is zero in the region $[0,a]$ ...
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Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
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How do I describe two entangled electrons in the same state except for a different spin

I am trying to formulate the wave function that describes two entangled electons having the same position but opposite spin. According to the Pauli exclusion principle this should be possible. And ...
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Electron distribution around atom when moving

I do not have much experience on this but if an atom has some electrons around nucleus and the atom itself it is moving at some speed does that affect the distribution of electrons around? I am ...
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Box normalisation and Particle in a box - Quantum Mechanics

I have been long itched by this issue of subtle difference between box-normalised free particle and infinite-dimensional potential well. Choosing a one dimensional case, the Hamiltonian in two cases ...