A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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The Energy Eigenvalue of a Wavefunction

I've been reading an introduction to quantum mechanics online, and while constructing the Schrodinger equation for a free particle, the equation $i\hbar \frac{d \Psi}{dt}=\hbar\omega\Psi$ is obtained. ...
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509 views

Solution of 1-D Schrodinger equation for the potential $V(x) = -\frac{1}{|x|}$

May be this question might have already been asked but i couldn't find it, so let me know if its already there. Consider a potential, $V(x) = -\frac{1}{|x|}$ and if we apply this to a one dimensional ...
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78 views

Determining the Wave Function From Initial Conditions

This is Problem 2.6 (b) in Griffiths, Intro to QM: A particle in an infinite square well has its initial wave function an even mixture of the first two stationary states: $\Psi(x,0) = ...
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243 views

General wavefunction and Schrödinger Equation

I'm starting with quantum mechanics and the book I follow (Griffiths) first introduces the wavefunction as the probability density of the position of a 0-spin single particle. Later on I've realized ...
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206 views

How to understand wavefunction in quantum mechanics in math

I am reading some introduction on quantum mechanics. I don't understand all but I get the point that the wavefunction tells some probability aspects. In one book, they show one example of the ...
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343 views

Mathematical explanation of quantum teleportation

I am now studying quantum teleportation. I get what the process is like but I'm wondering why it happens this way. You've got two entangled particles A and B whose wavefunctions are entangled. You ...
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109 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
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134 views

Expectation Values and Derivation of Heisenberg Equation?

Consider a system of particles with wave function $\psi$(x) (x can be understood to stand for all degrees of freedom of the system; so, if we have a system of two particles then x should represent ...
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Meaning of $C$ in wavefunction equation ($\Psi_{MO} = C_1\phi_A(1s) + C_2\phi_B(1s)$, where $C_1=\pm C_2$)

I've just cracked open a biophysics textbook and it's all fine up until the introduction of the letter C in a wavefunction equation, and declaring C1= ±C2 I've had lectures on eigenfunctions etc. ...
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Plane wave expansion in cylindrical coordinates

I am trying to solve scattering problem in 2D and got to expand the wave function in cylindrical system which comes out to be Hankel function. Can you tell me how to expand the plane wave $\exp(i ...
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Reason for the Gaussian wave packet spreading

I have recently read how the Gaussian wave packet spreads while propagating. see: http://en.wikipedia.org/wiki/Wave_packet#Gaussian_wavepackets_in_quantum_mechanics Though I understand the ...
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356 views

matter wave and wave function

Is there any mathematical relationship between matter wave (or de Broglie wave) and wave function? Also, does each type of particle (e.g. photon, electron, positron etc.) have its own unique wave ...
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Symmetric eigenfunctions?

So a symmetric eigenfunction / wavefunction is defined as: $$P_{ij} ψ_a (r_1,r_2,…,r_i,…,r_j,…,r_N )=ψ_a(r_1,r_2,…,r_i,…,r_j,…,r_N )$$ But for it to be symmetric does this have to be true for all $ij$ ...
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178 views

Energy and time evolution of a particle in a potential well

Hoping this is not a silly and stupid question let me ask for help in this problem. I have a particle in an infinite square well (the box is from 0 to a), in the state described by the function ...
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74 views

Can the wavefunction of a system be reconstructed from density matrices of subsystems?

Suppose we have several interacting particles in pure state $\left|\psi\right>$. For each of particles we can extract density matrices via $$\rho_i(x_i,x_i^\prime)=\int ...
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204 views

Confusion about the probability cloud

What is the meaning of the electron probability cloud? I understood it to mean that the electron has a probability to be found in a certain postion before measurement, but now after reading ...
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103 views

Wavefunction's inner product

When two wavefunctions are orthogonal we can write that $$\langle\Psi_n|\Psi_m\rangle=\delta_{mn}$$ This means that $$\langle\Psi_1|\Psi_2\rangle=\langle\Psi_2|\Psi_1\rangle=0$$ But if the two ...
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317 views

Wave function decomposition

Problem: Given the wave function $\Psi_0=A\sin^2(\theta)$ along with the Hamiltonian operator of a physical system: $H=\frac{L^2}{2I}+g B L_z$, find the eigenvalues and eigenfunctions of $\hat{H}$ ...
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What does the wavevector $\textbf{k}$ mean?

In Ashcroft, Mermin Solid State Physics, Eq. 17.43 is $$ \epsilon(\textbf{k}) = \frac{\hbar^2 k^2}{2m} - e\phi(\textbf{r}) $$ where $\textbf{k}$ is the wavevector and all other symbols have their ...
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Can we measure “wavefunction” of quantum particles?

We know that there is uncertainty principle, so question: can we ever measure wavefunction of particles? I do not think this is possible, but I am not sure. I guess that everything is probabilistic. ...
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160 views

normalizing a wavefunction

I have a homework problem that I can't get started on, below is the first bit. I feel like I should just be able to integrate to find $C$ but I get a divergent integral. Can someone give me a hint as ...
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229 views

What does it mean for something to be a ket?

Ok so I will provide the following example, which I am choosing at random from Sabio et al(2010): $$\psi(r,\phi)~=~\left[ \begin{array}{c} A_1r\sin(\theta-\phi)\\ ...
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Pulsed Spherical Wave

Can somebody help show me how a pulsed spherical wave has a wavefunction of the form U(r,t) = (1/r)a(t-r/c), where a(t) is an arbitrary function, r is the radius of the spherical wave, t is time, and ...
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478 views

Solving Schrödinger's equation for a specific potential

I am trying to solve this differential equation: $$-\chi''(\epsilon)+\Big[\epsilon^2+\frac{2F}{hw}\sqrt{\frac{h}{hw}}\epsilon \Big]\chi(\epsilon)=\mu\chi(\epsilon) \tag1$$ This was found ...
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Schematic expression of the Schrodinger equation

it would be great if someone could help me understand the following quote regarding wavefunctions :) "$$\psi(x)=\sum_n C_nu_n(x)+\int dE C(E)u_E(x)$$ The expression is schematic because we have ...
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Adding versus multiplying identical photons' wavefunctions?

I am currently confused with understanding many identical photons' wavefunctions. I think that photon wavefunctions are supposed to be multiplied together to describe the total state of all bosons. ...
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177 views

Correspondence between wave function and state vector

I am confused with connection between state $| \psi \rangle$ of a quantum system and corresponding wave function $\psi(x)$ (at a given time). I have been told that for every state $| \psi \rangle$ we ...
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186 views

Gaussian Probability Distribution?

The uncertainty principle states that, $$\sigma _{{x}}\sigma _{{p}}\geq {\frac {\hbar }{2}}.$$ It is mentioned from many sources that the probability distribution of the particle position and ...
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Spin eigenvalues and eigenvectors problem. Is this the correct way to solve it?

An electron is described by the Hamiltonian $ H=\frac{e}{mc}\bar{S}\cdot\bar{B} $ where $\bar{S} =(S_x,S_y,S_z)$ is the spin operator and $\bar{B}$ the magnetic field. For $t>0$ ...
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261 views

A difference between Plane Wave and Collimated?

Collimation is clearly in reference to ray($\vec{k}_{xy}$ vector) orientation unlike waterfront continuity( $\phi_{xy}$ phase shift) described by plane-wave. Not to say that one is not directly ...
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213 views

Area under the graph of squared wave function

I was given a graph of square of the wave function of a hydrogen atom, against the distance of the electron from the nucleus (denoted by r). What I know is that the square of the wave function gives ...
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How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
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638 views

Finite, square, potential well

Lets say we have a finite square well symetric around $y$ axis (picture below). I know how and why general solutions to the second order ODE (stationary Schrödinger equation) are as follows for ...
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134 views

Where is a particle bound in a delta potential?

I can picture a bound state in a harmonic oscillator, or in an infinite square well, but where is a particle bound in a delta potential?
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Wavefunction restrictions of odd potentials

So I was just reading back through Griffiths' "Introduction to Quantum Mechanics" and solving some of the problems for practice. There is a nice one (problem 2.1c for those playing at home) where you ...
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320 views

Cylindrical wave

I know that a wave dependent of the radius (cylindrical symmetry), has a good a approximations as $$u(r,t)=\frac{a}{\sqrt{r}}[f(x-vt)+f(x+vt)]$$ when $r$ is big. I would like to know how to deduce ...
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What does the wavefunction of atom look like at low temperature?

I am reading an introduction material on Bose-Einstein condensation (BEC) at low temperature and it stated that when the temperature approaches zero kelvin, almost all atoms are degenerated into the ...
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Gaussian wave packet

At our QM intro our professor said that we derive uncertainty principle using the integral of plane waves $\psi = \psi_0(k) e^{i(kx - \omega t)}$ over wave numbers $k$. We do it at $t=0$ hence $\psi = ...
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195 views

Once I have the eigenvalues and the eigenvectors, how do I find the eigenfunctions?

I am using Mathematica to construct a matrix for the Hamiltonian of some system. I have built this matrix already, and I have found the eigenvalues and the eigenvectors, I am uncertain if what I did ...
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Solving the time independent Schrodinger equation: Does a complex solution make sense?

In my notes, I have the Time Independent Schrodinger equation for a free particle $$\frac{\partial^2 \psi}{\partial x^2}+\frac{p^2}{\hbar^2}\psi=0\tag1$$ The solution to this is given, in my notes, ...
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What does the quantum state of a system tell us about itself?

In quantum mechanics, quantum state refers to the state of a quantum system. A quantum state is given as a vector in a vector space, called the state vector. The state vector theoretically ...
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238 views

Quantum Mechanics - The Normalization of $\psi_{3,1,1}$

Show that the hydrogen atomic wavefunction $\psi_{3,1,1}$ is normalized, and that it is orthogonal to $\psi_{3,1,−1}$. I'm not sure if I'm supposed to consider the radial part. I can show that ...
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578 views

One dimensional Schrödinger equation equation with initial condition, finding the probability of the particle's future position

A particle of mass $m$ moves freely in the interval $[0,a]$ on the $x$ axis. Initially the wave function is: $$f(x)=\frac{1}{\sqrt{3}}\operatorname{sin}\Big( \frac{\pi x}{a} ...
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186 views

fermions and quantum gates

Say that I have 2 qubits - 2 spin half fermions. my initial condition is $|00\rangle$ in the spin-wave function and some anti-symmetrical spacial wave function. I'm wondering about what happens when ...
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35 views

Are all identical fermions in orthogonal states as opposed to different general states?

A professor told me that most physicists assume that all identical fermions are in completely orthogonal states. If that is true, then does that mean that that the total wave function is highly ...
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Sign of the wave function in orbital representation?

I have some fog in my head and a rather simple question for you: When the sign of the wave function is representated on orbitals, what is this sign? I mean is it the sign of the real part of the ...
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Stationary state of time-independent Schroedinger equation is always real valued function?

I am reflecting on the solution of the time-independent Schroedinger equation. My reasoning is that the stationary state of the time-independent Schroedinger equation must be a real valued function ...
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Understanding wave functions

I'm currently writing an essay on the measurement problem, and I'm not quite certain that I've fully understood the purpose of the wave function, in that does the following sentence make sense with ...
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Why don't we need to normalize wavefunction to find probability distribution?

Consider an unormalized wavefunction of a rotor at $t = 0$, a combination of $n=0$ and $n=2$ states: $$\psi(\phi) = 3 - 2 \cos (2\phi).$$ Find the probability distribution in angle. The ...
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Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...