A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Physical meaning of linear combination of possible states in infinite well

The solution of infinite well, positioned from $x=0$ $x=l$, is $$ \Psi_n(x,t)= \sqrt{\frac{2}{l}}\sin\left(\frac{n\pi}{l}x\right)e^{iE_nt} $$ But the most general solution of this problem is : $$ ...
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131 views

Is it accurate to say “a wavefunction is a function of particle positions or momenta”?

Something has been bothering me for a while. I encounter this kind of statement everywhere: While a single particle is described by a wave function $\Psi({\vec r};t)$, a system of two particles, ...
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104 views

Minimum information necessary to represent a pure quantum state

I was thinking about how quantum states are represented for various types of systems, and how the amount of classical information (bits) required to represent a state depends on its basis. Let's take ...
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85 views

Why is the full eigenfunction a product of eigenfunctions and not a sum?

For example suppose there is a two electron system. Why is the full eigenfunction a product of the spatial eigenfunction and spin-wave-function for the two electron system?
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813 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
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244 views

Expectation Values and Derivation of Heisenberg Equation?

Consider a system of particles with wave function $\psi$(x) (x can be understood to stand for all degrees of freedom of the system; so, if we have a system of two particles then x should represent ...
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171 views

Does Schrödinger equation have dual-property with Heat equation?

I have experimental data that Schödinger equation maintains high frequencies, while heat equation low. Does Schrödinger equation have some duality property with heat equation?
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269 views

Orbital of Hydrogen molecule

does anybody here know an analytical approximation of the bonding hydrogen orbital MOLECULE? I am looking for a good approximation to this orbital, that might be in some textbooks to get an ...
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1k views

Solving a time independent Schrödinger equation with a given potential

I'm trying to rework this old homework problem, and I am having problems arriving at the same solution on the answer sheet: Let $$V(x)=\begin{cases}\infty &\text{ if } x < 0\\ ...
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830 views

Interpretation of de Broglie wave

Until what point can the de Broglie wave be thought as a real wave? I mean, is it made of something? What amplitude does it have? Is it a sine wave? How can it be related to the wavefunction of the ...
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1answer
294 views

What does the notation $|x_1,x_2\rangle$ mean?

I would like clarification on an equation in the paper "Free matter wave packet teleportation via cold-molecule dynamics", L. Fisch and G. Kurizki, Europhysics Letters 75 (2006), pp. 847-853, DOI: ...
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217 views

Why don't cancelling wavefunctions for two different particles give zero total wavefunction?

Let $\left|a\right>=e^{i(kx-\omega t)}$, $\left|b\right>=-e^{i(kx-\omega t)}$ be two neutral particles in the 1D free space without any interaction. Then ...
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106 views

What is the difference between real orbital & complex orbital?

While reading Atomic orbitals, I came before these two terms. The 'real orbital' is given here: Real orbitals An atom that is embedded in a crystalline solid feels multiple preferred axes, ...
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330 views

Quantum harmonic oscillator solved by analytic method using Schrödinger equation and wave function

I'm having trouble understanding the recursion formula. Using $\xi \equiv \sqrt{m\omega/\hbar}x$ and $K = 2E/\hbar\omega$, the time-independent Schrödinger equation becomes $$\frac{d^2\psi}{d\xi ^2} ...
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434 views

Differences between wave function and set of orthonormal wave functions?

I'm reading a QM book. It first says for wave function: "The state of a physical system (or particle) is completely specified by an entity associated with it called a wave function, Ψ , that in ...
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142 views

I am learning Quantum Mechanics and I have some questions about some basic concept [closed]

What does a "STATE" exactly mean in quantum mechanics? What is the equivalence of "STATE" in classical mechanics? If we have a wave function $\Psi$ , its absolute square $|\Psi|^2$ is the ...
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156 views

Logic of the 'imaginary wave function collapse' argument in Double Slit experiment

My question is in regards to the stance that the 'wave function collapse' is not an actual physical occurrence. That is, you are not, by observation, changing the particles position from a wave to a ...
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1answer
75 views

Free particle Schrödinger Equation

Some sources give the free-particle solution to Schrödinger equation as $$\psi(x,t) =Ae^{i(kx-\omega t)} + Be^{-i(kx+\omega t)}$$ while some sources give it as $$\psi(x,t) =Ae^{i(kx-\omega t)}$$ ...
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631 views

Two ways of calculating the expectation value of momentum

The expectation value of momentum is given by: $$ \langle p\rangle = \int_{-\infty}^{\infty}\psi^{*}(x)\left(-i\hbar\frac{\partial}{\partial x}\right)\psi(x)dx $$ How can I show that the above ...
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204 views

Spin state of electron after measurement

I have a system of two spin 1/2 particles in a superposition of spin states in the z-direction given by: $\psi = \frac{1}{2} |+ +\rangle + \frac{1}{2} |+ -\rangle + \frac{1}{\sqrt{2}} |- -\rangle$ ...
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1answer
269 views

Energy and time evolution of a particle in a potential well

Hoping this is not a silly and stupid question let me ask for help in this problem. I have a particle in an infinite square well (the box is from 0 to a), in the state described by the function ...
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1answer
624 views

Wave function collapse

When we try to measure the position of a system, wavefunction collapses to form a spike. After a while, the wavefunction spreads again, and you take another measurement, the results will be different" ...
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How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
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1answer
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Why does a plane wave have definite momentum?

Apologies if this is a little vague. It might not have a good answer. Given the interpretation of $|\psi(x)|^2$ as a probability distribution it's unsurprising that a wave function that is ...
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358 views

Why the hydrogen radial wave function is real?

Why the hydrogen radial wave function is real? Is it a coincidence?
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90 views

In the expansion of the scattered wave function, why do these two functions have the same index?

See Griffiths Quantum Mechanics, eq. 11.21. Evidently, $$\psi(r,\theta,\phi)=Ae^{ikz}+A\sum\limits_{l,m}^{\infty}C_{l,m}h_{l}(kr)Y_{l}^{m}(\theta,\phi).$$ But I don't see why the $l$th Hankel function ...
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What's the physical significance of the inner product of two wave functions in quantum region?

I am a reading a book for beginners of the quantum mechanics. In one section, the author shows the inner product of two wave functions $\langle\alpha\vert\beta\rangle$. I am wondering what's the ...
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576 views

If wave packets spread, why don't objects disappear?

If you have an electron moving in empty space, it will be represented by a wave packet. But packets can spread over time, that is, their width increases, with it's uncertainty in position increasing. ...
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624 views

How do I solve these integrals of wave function and operator?

First integral $$\int \Psi^*({\bf r},t)\hat {\bf p} \Psi({\bf r},t)\, d^3r,$$ where the $\Psi({\bf r},t)=e^{i({\bf k}\cdot{\bf r}-\omega t)}\,\,\,$ and $\hat {\bf p}=-i\hbar \nabla$. Second one ...
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868 views

Superposition of wavefunctions

Suppose you have 2 normalized wavefunctions $\psi_1=Ne^{iax}e^{if(x)}e^{i\omega t}$ and $\psi_2=Ne^{-iax}e^{if(x)}e^{i\omega t}$ defined on $x\in [-x_0,x_0]$ and vanishes for $|x|>x_0$. What then ...
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1answer
649 views

Simple rotation of an atomic orbital wavefunction

We know that an atomic orbital wavefunction may be written in terms of polar coordinates, $$\psi (r, \theta, \phi) = R(r) A(\theta, \phi)$$ where $R(r)$ is the radial component and $A(\theta, \phi)$ ...
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Do quantum wave functions curve spacetime before they are measured

Do wave functions cause spacetime curvature before they are measured, or would curvature only happen upon measurement? I guess the question becomes, do quantum wavefunctions carry energy while they ...
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systems of particles that are not symmetric or anti-symmetric; Helium 4

Suppose I have an electron and a proton, and that the electron is in the spin-up state, and that the proton is in the spin-down state. The particles are distinguishable, so I should just be able to ...
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1answer
137 views

Is de Broglie matter wave a mass or a particle hypothesis?

I'm having difficulty understanding de Broglie matter wave hypothesis. It is a mass or a particle hypothesis? According to de Broglie a particle with mass $m$ moving at a constant speed has an ...
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230 views

Why do wave functions need to be normalized? Why aren't the normalized to begin with? [duplicate]

Before I started studying quantum mechanics, I thought I knew what normalization was. Just pulling off Google, here's a definition that matches what I've understood normalization to mean: ...
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Question on wave function of hydrogen

http://physicsworld.com/cws/article/news/2013/may/23/quantum-microscope-peers-into-the-hydrogen-atom http://io9.com/the-first-image-ever-of-a-hydrogen-atoms-orbital-struc-509684901 they are claimed to ...
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1answer
163 views

What is the energy of a Gaussian wave packet?

Suppose we have a potential barrier situation, that is $V(x)$ is zero everywhere except on the interval $[-a,a]$, where it is equal to some $V_0 > 0$. Introduce some Gaussian shaped wave packet to ...
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Does an excited state wave function depend on state preparation?

Consider a quantum system with a ground state and many excited states (e.g. an atom). If the system is in an excited state, to what extent does its wave function depend on the method of state ...
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221 views

The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...
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1answer
92 views

Does the wave function of a particle completely describe the state of the particle?

In classical mechanics, if you know the position and momentum of a particle at time $t$ and the Hamiltonian, you can predict the particle's position and momentum at any time. In quantum mechanics, if ...
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Calculating the most probable radius for an electron of a hydrogen atom in the ground state

This link describes a method for determining the most probable radius of an electron for a Hydrogen atom in the ground state. It states that : The radial probability density for the hydrogen ...
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Entropy before and after collapse of the wavefunction/ and interpretation?

Seems like it might be pretty rudimentary but I want to see if my thinking is on the right track as well as what the result means. The question is, is the entropy of the collapse of a wavefunction or ...
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1answer
164 views

Three dimensional wave packets in momentum space

I am given the 3D wave packet: $$\psi(x,y,z)=N\,\exp\left(\frac{-(x^2+y^2+2z^2)}{2a^2}\right).$$ I was asked to find N (easy enough). Then I was asked the probability that we measure $z$ greater than ...
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1answer
80 views

Transition from coordinate space to momentum space for SHO

I am given that the ground state of the SHO in position space is given as $$\langle q|\psi_0\rangle=\frac{1}{a^{\frac12}\pi^{\frac14}}e^{-q/4a^2}$$ Where a is a constant with units of length. I am ...
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Solving quantum radial equation for infinite potential spherical annulus for $l=0$

There is a mass $m$ in a potential such that $$ V(r) = \left\{ \begin{array}{lr} 0, & a \leq r \leq b\\ \infty, & \text{everywhere else} \end{array} \right. $$ ...
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556 views

Bloch wave function orthonormality?

there is this text book that is giving me a hard time for a while now: It shows that Bloch wave functions can be written as $$\Psi_{n\vec{k}}\left(\vec{r}\right) = \frac{1}{\sqrt{V}}e^{i\vec k \vec ...
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136 views

Product of position eigenvectors at different times

I've been thinking about this, and it might sound like a stupid question, but I can't seem to find an answer anywhere, here goes: Whenever we calculate expecation-values between two position ...
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1answer
2k views

Overlap integral and probability

I have a question regarding how to extract probability from an overlap integral. Specifically, I am calculating the probability of a particle in a bound state in a delta potential $V=-\alpha ...
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1answer
3k views

A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
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Writing wave functions with spin of a system of particles

Suppose I have 2 fermions in a potential $V(x)$. Both particles are moving in one dimension: the $x$ axis. Then, neglecting the interaction between the particles, the spatial wave function of the ...