A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Area under the graph of squared wave function

I was given a graph of square of the wave function of a hydrogen atom, against the distance of the electron from the nucleus (denoted by r). What I know is that the square of the wave function gives ...
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1k views

How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
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284 views

Wave function decomposition

Problem: Given the wave function $\Psi_0=A\sin^2(\theta)$ along with the Hamiltonian operator of a physical system: $H=\frac{L^2}{2I}+g B L_z$, find the eigenvalues and eigenfunctions of $\hat{H}$ ...
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596 views

Finite, square, potential well

Lets say we have a finite square well symetric around $y$ axis (picture below). I know how and why general solutions to the second order ODE (stationary Schrödinger equation) are as follows for ...
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1answer
130 views

Where is a particle bound in a delta potential?

I can picture a bound state in a harmonic oscillator, or in an infinite square well, but where is a particle bound in a delta potential?
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304 views

Wavefunction restrictions of odd potentials

So I was just reading back through Griffiths' "Introduction to Quantum Mechanics" and solving some of the problems for practice. There is a nice one (problem 2.1c for those playing at home) where you ...
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292 views

Cylindrical wave

I know that a wave dependent of the radius (cylindrical symmetry), has a good a approximations as $$u(r,t)=\frac{a}{\sqrt{r}}[f(x-vt)+f(x+vt)]$$ when $r$ is big. I would like to know how to deduce ...
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336 views

What does the wavefunction of atom look like at low temperature?

I am reading an introduction material on Bose-Einstein condensation (BEC) at low temperature and it stated that when the temperature approaches zero kelvin, almost all atoms are degenerated into the ...
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1answer
186 views

Once I have the eigenvalues and the eigenvectors, how do I find the eigenfunctions?

I am using Mathematica to construct a matrix for the Hamiltonian of some system. I have built this matrix already, and I have found the eigenvalues and the eigenvectors, I am uncertain if what I did ...
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825 views

What does the quantum state of a system tell us about itself?

In quantum mechanics, quantum state refers to the state of a quantum system. A quantum state is given as a vector in a vector space, called the state vector. The state vector theoretically ...
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233 views

Quantum Mechanics - The Normalization of $\psi_{3,1,1}$

Show that the hydrogen atomic wavefunction $\psi_{3,1,1}$ is normalized, and that it is orthogonal to $\psi_{3,1,−1}$. I'm not sure if I'm supposed to consider the radial part. I can show that ...
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544 views

One dimensional Schrödinger equation equation with initial condition, finding the probability of the particle's future position

A particle of mass $m$ moves freely in the interval $[0,a]$ on the $x$ axis. Initially the wave function is: $$f(x)=\frac{1}{\sqrt{3}}\operatorname{sin}\Big( \frac{\pi x}{a} ...
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66 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
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35 views

Potential Step - Choosing Wavefunctions

http://uqu.edu.sa/files2/tiny_mce/plugins/filemanager/files/4190016/Quantum_Mechanics_1/ch4-virtual-book.pdf On page 2 of the above pdf they describe how they select their wavefunctions. Finding the ...
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66 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
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35 views

Reflection of an evanescent matter wave within a finite barrier?

To my understanding if I have a finite barrier with potential $V(x)>E$, then to the left of the barrier, the wavefunction can be represented as two exponentials: $$\psi= e^{(ik_{left} x)} + ...
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126 views

Bloch wave function orthonormality?

there is this text book that is giving me a hard time for a while now: It shows that Bloch wave functions can be written as $$\Psi_{n\vec{k}}\left(\vec{r}\right) = \frac{1}{\sqrt{V}}e^{i\vec k \vec ...
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725 views

Ground State Wavefunction of Two Particles in a Harmonic Oscillator Potential

Question: Two identical, non-interacting spin-$1/2$ particles are in a 1D Harmonic Oscillator Potential. Their Hamiltonian is given by ...
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130 views

Modulus Square of the Gaussian Wave Packet for uncertainty in $p$

Upon evaluating the integral (2.67) and obtaining the complex valued equation given in box 2.4, the author performs the modulus square to obtain the Gaussian distribution (2.68). How does one go about ...
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330 views

Writing a Wavefunction as a Linear Combination of Eigenstates

We have the following wavefunction for the hydrogen atom: $$\psi(r,\theta,\phi)=\frac{1}{\sqrt{4\pi}}\frac{1}{(2a)^{3/2}}\frac{r}{a}e^{-r/2a}\sin(\theta)\sin(\phi)$$ where $a$ is the Bohr radius. ...
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263 views

Tunnelling through a Dirac potential barrier

I am reading a QM book by Griffiths, which says it is possible for wave particle to tunnel through a barrier formulated by a Dirac function. This function is known to peak at infinity and also ...
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1answer
586 views

How to prove dp/dt = -dV/dx? Quantum mechanics [closed]

I got this problem from a book called Introduction to quantum mechanics, griffin 2nd edition. and I did not get why the solution says first term integrates to zero, integration by parts twice?! ...
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130 views

Transition integral from 1-D cartesian into 3-D polar coordinate system

Lets say we have an electron which can be in two states. Its wavefunction for two states is then $\Psi=A\Psi_n + B\Psi_m$, where $\Psi$ is time dependent wave function. I know that the transition ...
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245 views

Infinite Potential Well Energy for Piece-wise Constant Wave Function

I'm trying to compute the expectation value of energy for a certain state in an infinite potential well but I'm getting contradictory answers. The well has potential \begin{align} V(x) = \left\{ ...
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948 views

Time evolution of Gaussian wave packet

I'm slightly confused as to answer this question, someone please help: Consider a free particle in one dimension, described by the initial wave function $$\psi(x,0) = ...
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145 views

Why does the wave description say that probability oscillates, while the phase interpretation says constant amplitude?

The wave description of a particle illustrates an oscillating probability of the particle being found in any point in space. When a particle travels, it carries along with it a phase that oscillates ...
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73 views

Why is the Horizontal Force Constant in Deriving the One Dimensional Wave Equation

My textbook in deriving the wave equation for a one dimensional elastic string stated that the horizontal direction force is constant.I understand that the horizontal components of the tensions on ...
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120 views

Phase shift in electromagnetic potential

In Aharonov-Bohm effect, how to derive that the wave function of a electric charge $q$ acquires a phase shift $\phi=\frac{q}{\hbar}\int \mathbf{A} \cdot d\mathbf{x}$ after travelling in the non-zero ...
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88 views

Question about the linearity of wave functions

For piece-wise constant potential, the potential energy is constant so the time dependent wave function can take the form $\psi(x,t)=C_1e^{i(kx- \omega t)}+C_2e^{i(-kx-\omega t)}$ where ...
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159 views

How is wavefunction probability redistributed after partial wavefunction collapse?

Suppose I set up the double-slit experiment using photons as my particle. Behind the left slit I place a beam splitter that points some of the light off in the direction of a camera (represented as ...
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749 views

Wave function of Hydrogen Atom [closed]

Wavefunction of a Hydrogen atom is expressed in eigenfunctions as: $$\psi(\boldsymbol r,t=0)=1/\sqrt{14}(2\psi_{100}(\boldsymbol r)-3\psi_{200}(\boldsymbol r)+\psi_{322}(\boldsymbol r) ).$$ Is ...
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767 views

Schrödinger function: Separable wave function with even potential function of x

I have done the Problem 2.1 in Griffiths' quantum mechanics, and it seems not making sense to me. What if the wave function isn't symmetric at all? Then obviously the proof doesn't work. The ...
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57 views

How to compare differences in waves?

I have a series of waves that I would like to compare to one another. The measurements are two-dimensional with time on the x-axis and an intensity measurement on the y-axis. I'd like some way of ...
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2k views

what is phase angle of wave function $\phi \,$?

this is wave function: $$\Psi{(\vec r, t)}=\Psi_0 e^{i(\vec k \cdot \vec r-\omega t)}$$ $$\Psi{(\vec r, t)}=A e^{i(\phi + \vec k \cdot \vec r-\omega t)}$$. what is phase angle $\phi$ of wave ...
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479 views

How Represent Waves via Complex Numbers?

i try to finished my thesis, (Just have a problem with the wave mechanics) this is wave function: $$\Psi(\vec x, t)=A\exp{i(\phi+\vec k.\vec x-\omega t)}$$ In mathematics, the symbol $i$ is ...
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517 views

How Light or Water Intensity is equal to square modulus of wave function of Light or Water Waves $I=|\psi|^2 \,$?

I've seen the Wave Function as a psi $\Psi$ $\psi$. And always heard that the wave function is the Complex Number as Imaginary and real number. But I've never seen it I've never seen components of ...
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216 views

Expressing a particle's matter wave in terms of its momentum

I'm following Zettili's QM book and on p. 39 the following manipulation is done, Given a localized wave function (called a wave packet), it can be expressed as $$\psi(x,t) = \frac{1}{\sqrt{ 2 \pi}} ...
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331 views

Sudden change in the Hamiltonian

Could someone explain what this sentence mean? "If the Hamiltonian changes suddenly by a finite amount, the wavefunction must change continuously in order that the time-dependent Schrodinger equation ...
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1answer
424 views

Determining wave function for term symbol 1D

I am trying to follow a book (Introduction to Ligand Field Theory by Ballhausen in 1962 on pg 15), but it isn't clear how they make a particular leap. Background I want to find the wave function for ...
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58 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
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81 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
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36 views

Electron distribution around atom when moving

I do not have much experience on this but if an atom has some electrons around nucleus and the atom itself it is moving at some speed does that affect the distribution of electrons around? I am ...
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33 views

KdV equation and classical linear wave equation

Like we know, the standard form of KdV equation is $$u_{t}-6uu_{x}+u_{xxx}=0,\tag{1}$$ where this equation describes a solitary wave propagation and $u=u(x,t)$. On the other hand, we know the ...
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33 views

Entropy before and after collapse of the wavefunction/ and interpretation?

Seems like it might be pretty rudimentary but I want to see if my thinking is on the right track as well as what the result means. The question is, is the entropy of the collapse of a wavefunction or ...
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22 views

Conduction and propagation

What is the difference between conduction of electric wave in conductor and propagation of electromagnetic wave in dielectric? Why propagation term is used for dielectric and conduction for ...
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28 views

How does a complex wavefunction “hold” energy?

Feynmann Lectures Vol 3 Ch 8 Sec 6 describes how an ammonia molecule can have two definite energy states. If the amplitudes of the base states are $ C_1(t) ...
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88 views

Energy difference between symmetric and antisymmetric wavefunctions

Is there any energy difference between a particle in a symmetric wavefunction and an identical particle in an identical potential but in a state with an anti-symmetric wavefunction? Or is it ...
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113 views

How does wave function collapse when I measure position?

Text books say that when you measure a particle's position, its wave function collapses to one eigenstate, which is a delta function at that location. I'm confused here. A measurement always have ...
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72 views

Particle in a higher-dimensional box with an attractive delta potential

Suppose you have a particle in the box $[0,L]^d$, with an attractive Dirac delta potential $-\delta_{\vec w}(x)$ at $\vec w$. How do you solve the Schroedinger equation for this system? In the case ...
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58 views

Does light or observation collapse wave functions? [duplicate]

I hear that observation is what causes the wave function collapse, but that doesn't make sense considering that an eye or camera is just a physical system with no particularly special properties. In ...