A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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2answers
552 views

Schroedinger equation for hydrogen atom

I have got a problem understanding the meaning of the Laplace operator in the Schrödinger equation for the hydrogen atom. $$\Big(-\frac{\hbar^2}{2m_e} \Delta_{r_e} - \frac{\hbar^2}{2M_P} \Delta_{r_p} ...
12
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3answers
465 views

Bound states of the $V(x)=\pm \delta'^{(n)}(x)$ potential?

The $\delta(x)$ Dirac delta is not the only "point-supported" potential that we can integrate; in principle all their derivatives $\delta', \delta'', ...$ exist also, do they? If yes, can we look for ...
0
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4answers
357 views

Physical intuition behind negative values for wave function?

So a positive and a positive wave function create a bonding orbital where the probability of finding an electron is summed while a positive and a negative create an anti-bonding orbital with a lower ...
1
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1answer
133 views

Is the photon's wave function the same as an electromagnetic wave(light)? [duplicate]

The first that i have been taught in Quantum Mechanics is the photoelectric phenomenon. Without analyzing it, it concludes that when we shine light at the circuit(roughly speaking), the work required ...
4
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2answers
101 views

Do quantum wave functions curve spacetime before they are measured

Do wave functions cause spacetime curvature before they are measured, or would curvature only happen upon measurement? I guess the question becomes, do quantum wavefunctions carry energy while they ...
0
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1answer
172 views

Probability and double slit

if a beam of identical particles at random distances from each other (or exactly 1/2 lambda between each other) travelling with the same v towards a double sllit do not interfere with each others wave ...
0
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2answers
294 views

Why is $ \psi = A \cos(kx) $ not an acceptable wave function for a particle in a box?

Why is $ \psi = A \cos(kx) $ not an acceptable wave function for a particle in a box with rigid walls at $x=0$ and $x=L$ where $$ k = \frac {(2mE)^{1/2}} {\hbar} \, ?$$ I had plugged the wave ...
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1answer
210 views

Width of a 1 dimensional box with same ground state energy as hydrogen atom [closed]

I am trying to find the width $L$ of a one-dimensional box for which the ground state energy of an electron in the box equals the absolute value of the ground state of a hydrogen atom. No ...
0
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2answers
86 views

How can a solution of the time-independent Schrödinger equation evolve in space?

I understand that if the Hamiltonian does not depend on the time, the Schrödinger Equation becomes separable, so you get $$ H \psi(x) = E \psi(x) $$ and $$ \Psi(x,t) = ...
1
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1answer
50 views

Potential energy function for high energy continuum?

For the hydrogen atom the quantised energy levels are: $$E_n = \frac{- 13.6 eV}{n^2}\quad\text{with}\quad n = 1,2,3...$$ One peculiar property of this quantisation is that for large $n$ the energy ...
5
votes
3answers
367 views

Confusion about 1-forms as introduced in “Gravitation” (Kip S. Thorne,…)

In the book Gravitation in chapter 2, paragraph 5, they introduce the concept of 1-forms by thinking about the momentum 4-vector differently. They first introduce the de Broglie 1-form as follows (I ...
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2answers
196 views

How to predict bound states in a 1 D triangular well?

Assume we have a (single) particle in a potential well of the following shape: For $x \leq 0$, $V = \infty$ (Region I) For $x \geq L$, $V = 0$ (Region III) For the interval $x > 0$ to $x < ...
0
votes
1answer
142 views

Schrodinger's equation with negative sign

In time dependent Schrodinger's equation as given in Schrodinger's lecture (Four Lectures on Wave mechanics, Blackie & Son, 1949, pg22) he arrives at $$\nabla^2\psi-\frac{4 \pi m ...
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2answers
340 views

What do “ℜe” and “A*” mean?

What do "$\mathfrak{Re}$" and "A*" mean in the following equation (taken from James Binney and David Skinner's QM lecture notes, equation 1.12), \begin{align} p(S\text{ or ...
2
votes
1answer
52 views

Why do the two amplitudes need to match together through the region between the boxes?

This is an excerpt from Feynman's lectures 3; Suppose we think of the situation in Fig. 7–3, which has two boxes held at the constant potentials $ϕ_1$ and $ϕ_2$ and a region in between where ...
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2answers
117 views

Why can the probability function for a particle in an infinite square well be larger than 1?

For a particle in a one dimensional infinite potential well of width $L$ the probability function is: $$P_n(x)=\left(\frac{2}{L}\right)\sin^2\left(\frac{n\pi x}{L}\right)$$ for $0\leq x\leq L$. The ...
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3answers
1k views

Electron as a standing wave and its stability

1. When it was an era of classical mechanics we used to believe in the Bohr's atomic model. It interpreted electrons as particles (although I couldn't understand how come Bohr who interpreted ...
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3answers
200 views

Wave Function concept

What do we mean when we say wave function of electron? Does it mean wave nature of electrons? I am really confused.Without clearing this confusion i cannot proceed to molecular orbital theory.I am ...
0
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1answer
237 views

Semi-infinite / Asymmetric potential well

I'm asked to come up with an ansatz and solve for the coefficients of a asymmetric infinite potential well, where: $$ V = \begin{cases} \infty \text{ for } x< 0 \\ V_0 \text{ for } 0 \leq x \leq L ...
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2answers
87 views

Where does the factor of $x$ come from in this formula for expectation value?

Given the normalised ground-state wave-function: $$\Psi(x, t)=\begin{cases} \sqrt\frac{2}{d}\cos(\frac{\pi x}{d})e^\frac{-i\hbar\pi^2t}{2md^2} & \ \lvert x\rvert<\frac{d}{2}, \\ 0 & ...
4
votes
4answers
191 views

Isn't the 'slit' in a double-slit experiment also a wave?

I'm new to QM so excuse my naivety. I was watching an online MIT QM course that described the double-slit experiment (with electrons) when it occurred to me that I have a question. In the video, the ...
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0answers
24 views

Cancelling waves and preservation of energy

In quantum physics, a particle is "defined" by a wavefunction. If you would take 2 particles with the same wavefunction, and negate one of them. They would cancel each other other out. Take for ...
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0answers
28 views

Solutions to time-independent Schrödinger's equation with symmetrical (even) potential [duplicate]

A problem from Griffith's Introduction to Quantum Mechanics asks to prove the following: Given a symmetric potential $V(x)$ $(=V(-x))$, the solutions to the time-independent Schrödinger's equation ...
1
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1answer
657 views

What does a light wave look like (3d model)

What does a light wave look like? The only models I can seem to find online are 2D waves, they just look like sin() graphs. I have seen the models of the two components of "light waves" (electric ...
21
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2answers
731 views

What is the Copenhagen interpretation of quantum field theory?

I am most interested in interpretational differences due to the fact that quantum field theory is relativistic while quantum mechanics is not. By "Copenhagen interpretation" I mean a minimal ...
6
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2answers
200 views

What state the wave function collapses into after an inaccurate measurement?

I'm watching MIT online lectures Quantum Physics I (roughly from one hour mark in the video). The lecturer explains wave functions that describe "Stationary States" that consist of a single energy ...
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0answers
60 views

Transfer function of a space varying wave equation

$$\frac{\partial ^2 \psi}{\partial x^2}-\mu \epsilon \frac{\partial ^2 \psi}{\partial t^2}-\mu \sigma \frac{\partial \psi}{\partial t}=0$$ Is the wave electromagnetic wave equation in lossy, source ...
2
votes
1answer
156 views

The definition of the vacuum state of quantum field by path-integral

In the review Entanglement entropy of black holes by Sergey Solodukhin (arXiv:1104.3712, equation 13), I see a definition of vacuum state of quantum field by path integral over half of the total ...
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1answer
39 views

$\sqrt{\frac{\omega ^2}{c^2}-k_z^2}$ in cylindrical harmonics

The radial component of the solution of the wave equation in cylindrical coordinates is $$J_\nu \bigg(\rho\sqrt{\frac{\omega ^2}{c^2}-k_z^2}\,\,\bigg).$$ But I always thought that $\frac \omega c$ ...
3
votes
1answer
196 views

Plane wave expansion of cylindrical functions:Summation of the Hankel functions

I understand that; in cylindrical coordinates, the basic solutions of the Helmholtz equation are of the form Hankel function of integer order times a complex exponential term ...
3
votes
3answers
309 views

Constructing solutions to the time-dependent Schrödinger's equation

The following question is from David Griffiths' Introduction to Quantum Mechanics: Problem 2.13 A particle in the harmonic oscillator potential starts out in the state $$\Psi(x,0) = A[3 ...
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5answers
183 views

Does measurement change the evolution of wave function?

Basically any measurement is on wave function $|\psi\rangle$ is done by operator $X$ such that $X|\psi\rangle$ results observable $x$ with some probability. But what happens to $|\psi\rangle$? Does ...
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2answers
75 views

Does a free electron, one that's not either in an atom or a wire, have an associated wave-function?

Would a free electron, one that's not either in an atom or moving through a wire, but moving through empty space on its own, have an associated wave-function? Or, is an electron described as a ...
1
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1answer
94 views

Solution of the Radial Part of the Schroedinger Equation [closed]

The general Schroedinger Equation is: $$\left[-\frac{\hbar^2}{2m}\triangle +V(r,\vartheta,\varphi)\right]\psi_{nlm}=E\psi_{nlm}$$ When considering free waves, i.e. $V(r,\vartheta,\varphi)=0$ and a ...
0
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1answer
62 views

Property of the wave functions of a free particle

How can I show that the following holds? $$\langle nlm\mid \partial_z^2\mid nlm\rangle=-\int_0^{4\pi}d\Omega\int_0^{\infty}drr^2\left|\partial_z\psi_{nlm}\right|^2$$ The wave functions of a free ...
1
vote
2answers
115 views

How do phase carries structural information about the function? [closed]

Suppose you are on a railway platform and you hear the sound of train coming towards you. Now, Using Fourier transformation we can convert the time domain function (here take sound as a function) ...
0
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1answer
57 views

For an event that can occur in many ways, why is the wavefunction of the event the sum of wavevfunction for each way separately?

The wavefunction of identical particles is given as: $$\psi_{1,2} (x_1,x_2) = \psi_1(x_1)\psi_2(x_2) + \psi_2(x_1)\psi_1(x_2)$$ . Why is it so? Why is it the sum of the two states? What is the ...
2
votes
1answer
240 views

How to visualize a Schrödinger cat state?

I recently read about Schrödinger cat states, which are basically a superposition of two coherent states $|\alpha\rangle$ with opposite phases, that is, $$ |\mathrm{cat}\rangle = |\alpha\rangle \pm ...
1
vote
1answer
77 views

Analytical non-separable solution for schrodinger equation

I am an undergraduate with the background of a first course in Quantum Mechanics. I want to find out if there exist non-unique solutions to Schrodinger equation. So I have to find potentials ...
2
votes
1answer
315 views

What is the difference between real orbital & complex orbital?

While reading Atomic orbitals, I came before these two terms. The 'real orbital' is given here: Real orbitals An atom that is embedded in a crystalline solid feels multiple preferred axes, ...
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votes
1answer
92 views

Where do these two equalities for the expectation value come from precisely? Doesn't $\Psi^* x \Psi = x |\Psi|^2$?

Where do these two equalities for the expectation value come from precisely? : $$\begin{align} \langle x\rangle &= \int_{-\infty} ^\infty \Psi^* x \Psi\,\mathrm{d}x \\ \langle x^2\rangle &= ...
0
votes
1answer
69 views

The Tunnelling Man [closed]

What's the probability that I will tunnel through a solid wall? By "tunnel" I mean, the probability of finding me on the other side of the wall. Assumptions Wall thickness = $d$ Clearly state any ...
1
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1answer
115 views

Finding the wave function of a quantum harmonic oscillator [duplicate]

How can I find the wave function of a quantum harmonic oscillator? If I measure its energy several times, my measurements will change the state of a system. All I know are the possible states, given ...
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vote
2answers
138 views

Why is probability of finding the electron at a certain point when one of the slits is closed $|\Psi|^2 $ & not $|\Psi|^2 dx$?

Let in a given physical condition, the wave-function to a particle be assigned as $|\Psi (x_i,0,0,t)|^2 dx$. Now, at the double-slit experiment , the probability of finding the particle at any $x$ ...
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1answer
61 views

Particle in a box - speed probability distribution

Consider a particle in a box with infinite barriers. By solving the Schrödinger we can find the probability of finding the particle at some points in the box. How can we find the probability of ...
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3answers
113 views

How to measure the wave-function experimentally?

Do experimental physicists really measure the wave function of a system? How do they do it? Do they make many identically-prepared systems and measure the position of the particle(s) over and over ...
0
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2answers
166 views

What is the meaning of integrating over the state space?

If $\lvert\psi\rangle$ denotes the state space corresponding to a qubit, then what is the meaning of the $$\int d\psi$$ where the integral is over whole state space of a qubit? How do I evaluate it? ...
0
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3answers
84 views

Probability density for wavefunction given as infinite superposition of eigenstates

How do we find the probability density as a function of (x,t), if the wavefunction is expressed as an infinite superposition of eigenstates? When the wavefunction is expressed as a superpostion of ...
0
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1answer
277 views

Probability density for momentum in Quantum Mechanics

In a book i found the following equations: $$ \phi(k)=\frac{1}{\sqrt{2\pi}} \int_{-\infty}^\infty \Psi(x,0)e^{-ikx}dx $$ and $$ \Psi(x,t)=\frac{1}{\sqrt{2\pi}} \int_{-\infty}^\infty ...
0
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1answer
91 views

Problem with momentum values in a QM problem

I have the following equation of $Ψ$ around a ring (the particle is bound to move only on the ring): To visualize the state(it dies before L/2 if L=2πR): We can see from the first picture that ...