A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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How does a complex wavefunction “hold” energy?

Feynmann Lectures Vol 3 Ch 8 Sec 6 describes how an ammonia molecule can have two definite energy states. If the amplitudes of the base states are $ C_1(t) ...
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166 views

Energy difference between symmetric and antisymmetric wavefunctions

Is there any energy difference between a particle in a symmetric wavefunction and an identical particle in an identical potential but in a state with an anti-symmetric wavefunction? Or is it ...
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51 views

Setting the normalization volume to 1

In graphene, free electrons can have the following wavefunctions (there are other options, with minus signs in various places, but this will serve as an example): ...
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108 views

Why do we use $\psi$ instead of a straightforward probability?

What is the advantage/purpose of using $\psi$ for wavefunctions and getting the probability with $|\psi|^2$ as opposed to just defining and using the probability function?
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127 views

Box normalisation and Particle in a box - Quantum Mechanics

I have been long itched by this issue of subtle difference between box-normalised free particle and infinite-dimensional potential well. Choosing a one dimensional case, the Hamiltonian in two cases ...
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100 views

Physical position eigenfunction normalisation

We know that the Dirac function $$\delta(a)=\lim_{a \rightarrow 0} \delta_{a}(x)$$ can be written as an infinitesimally narrow Gaussian: $$ \delta_{a}(x) := \frac{1}{\sqrt{2\pi a^2}}e^{-x^2/2a^2}$$ ...
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131 views

Wavefunction Problem wrong in solutions manual? [closed]

Well there is a problem in my book which lists this problem: Calculate the probability that a particle will be found at $0.49L$ and $0.51L$ in a box of length $L$ when it has (a) $n = 1$. Take the ...
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469 views

Infinite and Finite Square Wells

For the infinite square well in the first region, outside the well: $$\frac{-\hbar^2}{2m}\frac{d^2 \psi}{dx^2} + V(x) \psi (x) = E \psi (x),$$ where you set $V = 0$. Rearranging gives $$\frac{d^2 ...
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1answer
112 views

Three dimensional wave packets in momentum space

I am given the 3D wave packet: $$\psi(x,y,z)=N\,\exp\left(\frac{-(x^2+y^2+2z^2)}{2a^2}\right).$$ I was asked to find N (easy enough). Then I was asked the probability that we measure $z$ greater than ...
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90 views

Momentum representation of a state

I am trying to figure out the momentum representation of the state which has the properties $$\langle \psi |\hat q |\psi \rangle=-q_0,$$ $$\langle\psi|\hat p|\psi \rangle=p_0, $$$$\Delta q\Delta ...
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256 views

Gaussian Probability Distribution?

The uncertainty principle states that, $$\sigma _{{x}}\sigma _{{p}}\geq {\frac {\hbar }{2}}.$$ It is mentioned from many sources that the probability distribution of the particle position and ...
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289 views

Imaginary Eigenvalue Of A Hermitian Operator

The eigenfunctions of a Hermitian operator are real. But consider a function $\psi(x)=e^{-\kappa x}$, $x\in\mathbb{R}$, where $\kappa$ is a real constant. Then, $$\hat p \psi(x)=-i\hbar ...
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221 views

How does wave function collapse when I measure position?

Text books say that when you measure a particle's position, its wave function collapses to one eigenstate, which is a delta function at that location. I'm confused here. A measurement always have ...
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1answer
69 views

Transition from coordinate space to momentum space for SHO

I am given that the ground state of the SHO in position space is given as $$\langle q|\psi_0\rangle=\frac{1}{a^{\frac12}\pi^{\frac14}}e^{-q/4a^2}$$ Where a is a constant with units of length. I am ...
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98 views

Particle in a higher-dimensional box with an attractive delta potential

Suppose you have a particle in the box $[0,L]^d$, with an attractive Dirac delta potential $-\delta_{\vec w}(x)$ at $\vec w$. How do you solve the Schroedinger equation for this system? In the case ...
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1answer
85 views

Does light or observation collapse wave functions? [duplicate]

I hear that observation is what causes the wave function collapse, but that doesn't make sense considering that an eye or camera is just a physical system with no particularly special properties. In ...
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147 views

photon polarization, uncertainty in Energy

A beam of red light is sent along the $z$ axis through a polaroid filter that passes only $x$ polarized light. The beam is initially polarized at $30$°, and the total energy is $10$ Joules. Estimate ...
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114 views

Superposition and density matrix. What are these states?

I just wanted to understand the following. Let's stay with the harmonic oscillator in QM, just to have an example at hand. First, there are all the different states for $n=1,2,...$. (Let's call them ...
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2answers
115 views

Infinite well particle subject to additional time dep. potential

I am asked to find the wavefunction of the particle in a well subject to an additional potential $$V(x,t)=\frac{\pi x \hbar}{L}\delta(t).$$ I have already solved that ...
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264 views

Non-separable solution for the Schrödinger equation

Schrödinger solutions are usually if not always of the type: $\psi=\operatorname{T}(t)*\operatorname{X}(x)$ (we use the separation of variables method to arrive at the time independent Schroedinger ...
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64 views

QM 2D Gaussian wave packet translation

I've been reading a lot but cannot find an example of 2D Gaussian wave packet moving in a particular direction. I've done some of the math myself, in a 1D case, and then kind of guessed the ...
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1answer
78 views

A well-defined quantum probability in the beginning of the universe?

In mathematics or statistics, a well defined probability requires a large sample space. However, in the beginning of the universe, when the first quantum collapse happened, the sample space contains ...
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76 views

Question on measuring expectation value of spin with time variation

I have a particle with the following wave function: $$\psi(t) = \frac12 |\uparrow \rangle e^{-i(\omega_1+\omega_2)t/\hbar} +\frac12 |\uparrow \rangle e^{-i(\omega_1-\omega_2)t/\hbar} ...
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120 views

Basic introductory quantum mechanics question [closed]

Given that $\psi = \frac{1}{\sqrt{32 \pi a_{0}^{3}}}(2-\frac{r}{a_0})exp(\frac{-r}{2a_0})$ is a wavefunction of the hydrogen atom, write down the probability density for r and calculate the ratio ...
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1answer
132 views

Spin state of electron after measurement

I have a system of two spin 1/2 particles in a superposition of spin states in the z-direction given by: $\psi = \frac{1}{2} |+ +\rangle + \frac{1}{2} |+ -\rangle + \frac{1}{\sqrt{2}} |- -\rangle$ ...
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123 views

Quantum state with zero standard deviation of position operator

Is any quantum state $|\psi\rangle$ possible such that the standard deviation $\sqrt{\langle\psi|(\Delta\hat{x})^2|\psi\rangle}$ of the position operator $\hat{x}$ is zero? If not, why?
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Solving quantum radial equation for infinite potential spherical annulus for $l=0$

There is a mass $m$ in a potential such that $$ V(r) = \left\{ \begin{array}{lr} 0, & a \leq r \leq b\\ \infty, & \text{everywhere else} \end{array} \right. $$ ...
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166 views

Double slit experiment and entanglement

Just wondering, what would happen in this experiment. In the experiment you would first have two entangled particles. Then you fire one of the particles, lets say "Particle A", at a double slit ...
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Rydberg quasimolecules & stark states?

I found this image : on the internet and I traced it back to this article ,I wanted to use it as part of an architectural visualization for my project(architecture) but for this to happen I need to ...
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1answer
95 views

Angular momentum of hydrogen from $n,l,m$ values

Given a wavefunction for hydrogen $\psi(n,l,m)$ it is possible to calculate its associated energy from $E=-13.6/n^2$. Does a similar equation exist for $L^2$ and $L_z$? That is, if we are given the ...
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172 views

Virial theorem and variational method: an exercise (re-edited)

I have a hydrogen atom, knowing that its Hamiltonian has been modified turning the standard potential $$ V_{0}(r) = -\frac{Z}{r} $$ into $$ V(r) = -\frac{g}{r^{\frac{3}{2}}} $$ with $g$ a positive ...
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Functionals of quantum states in QFT

Almost every book and article I can think of represents states of QFT using the Heisenberg picture of Hilbert space vectors, but Visser in "Lorentzian wormholes" does mention that you can also ...
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154 views

Is $v(p)\exp(ipx)$ really the positron wave function?

In many textbooks the negative energy solution of the Dirac equation is quoted as describing the positron. Actually I don't understand this. For me $v(p)\exp(ipx)$ is the wave function of an electron ...
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155 views

Infinite potential square well solutions

My question is about understanding the different solutions of the potential square well. Imagine a square well defined this way: $$ V(x) = \begin{cases} ∞&\,{\rm if} x<0 \\ 0&\,{\rm ...
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Does the wave function always asymptotically approach zero?

I'm new to quantum physics (and to this site), so please bear with me. I know that quantum mechanics allows particles to appear in regions that are classically forbidden; for example, an electron ...
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158 views

Spin eigenvalues and eigenvectors problem. Is this the correct way to solve it?

An electron is described by the Hamiltonian $ H=\frac{e}{mc}\bar{S}\cdot\bar{B} $ where $\bar{S} =(S_x,S_y,S_z)$ is the spin operator and $\bar{B}$ the magnetic field. For $t>0$ ...
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86 views

At what point is the spin determined in a Stern-Gerlach Apparatus

Consider a particle with spin that travels through a Stern Gerlach box (SGB), which projects the particle’s spin onto one of the eigenstates in the $z$-direction. The SGB defines separate trajectories ...
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138 views

Inexact measurement and wavefunction collapse

As is usually said, measurement of an observable $q$ leads to collapse of wavefunction to an eigenstate of the corresponding operator $\hat q$. That is, now the wavefunction in $q$ representation is ...
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1answer
202 views

Energy and time evolution of a particle in a potential well

Hoping this is not a silly and stupid question let me ask for help in this problem. I have a particle in an infinite square well (the box is from 0 to a), in the state described by the function ...
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1answer
205 views

Interpretation of Dirac equation states

In Pauli theory the components of two-component wavefunction were interpreted as probability amplitudes of finding the particle in particular spin state. This seems easy to understand. But when ...
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348 views

Can we safely assume $\Psi(x,t) = \psi(x)e^{-i\omega t}$ always in QM?

In the particle in a box, harmonic oscillator and in Hydrogen Atom, we can safely assume $$\Psi(x,t) = \psi(x)e^{-i\omega t}.$$ So why not make it a postulate to consider the wave function to be ...
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67 views

Quantum eraser double slit experiment

In the quantum eraser double slit experiment, does the photon (or wavefunction) pass through one slit or both slits when different polarizers are placed over the slits?
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Example of the time-independent Schrödinger equation having a complex solution?

We know $\Psi(x,t)$ is complex, but can $\Psi(x)$ be complex? I have seen particle in a box, well and harmonic oscillator. All have real solutions for time-independent Schrödinger equation. Hence, I ...
7
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1answer
268 views

Virial theorem and variational method: a question

I have an hydrogenic atom, knowing that its ground-state wavefunction has the standard form $$ \psi = A e^{-\beta r} $$ with $A = \frac{\beta^3}{\pi}$, I have to find the best value for $\beta$ ...
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677 views

Particle in a 1-D box and the correspondence principle

Consider the particle in a 1-d box, we know very well the solutions of it. I'd like to see how the correspondence principle will work out in this case, if we consider position probability density ...
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223 views

Wave function for an electron in and around a small charged sphere

I am interested in solutions of the Schroedinger equation. For simplicity I started my studies with the $n=1$ ground state of the hydrogen atom. I was particularly interested in the higher moments of ...
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Why complex functions for explaining wave particle duality?

I have this very bad habit of going to the scratch, discarding all the developments of a theory and worldly knowledge, and ask some fundamental (mostly stupid and naive, as some may say) questions as ...
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Comparison of 1D and 3D wave functions

When discussing the Schroedinger equation in spherical coordinates, it is standard practice in QM handbooks to point out that the radial part of the 3-dimensional wave equation bears a strong analogy ...
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215 views

How axiomatic is the symmetrization requirement (i.e. the Pauli principle)? (in QM)

I've so far always been told, that the symmetrization requirement is an axiom on the level of the Schrödinger equation and the statistical interpretation of the wave function (or it's absolute value). ...
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190 views

Why does $\ell=0$ correspond to spherically symmetric solutions for the spherical harmonics?

In quantum mechanics why do states with $\ell=0$ in the Hydrogen atom correspond to spherically symmetric spherical harmonics?