A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Can a wavefunction be solved to any arbitrary precision, given enough computer time?

I learned that the wavefunction for the hydrogen atom can be solved analytically (we did the derivation in class), but that for more complicated atoms it is "impossible" to solve and that only ...
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Simple Quantum Mechanics question about the Free particle, (part1)

I am reading Introduction to Quantum Mechanics by David Griffiths and I am in Ch2 page 59. He starts out writing the time dependent Schrödinger equation and the solution for $\psi(x,t)$ for the free ...
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A misunderstanding regarding infinite square well

Here is a picture of the energy states of infinite potential well. We can see That the first level have a half wavelength which fittes with a full wave of the second level. $$\frac{ \lambda _{1} ...
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Is this interpretation of $\psi=\frac{1}{\sqrt{\pi a^{3}}}e^{-r/a}$ correct?

Apologies if this is stating the obvious, but I'm a non-physicist trying to understand Griffiths' discussion of the hydrogen atom in chapter 4 of Introduction to Quantum Mechanics. The wave equation ...
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Is the free electron wavefunction stable?

The wavefunction of a free electrons is variously described as a plane wave or a wave packet. I am fairly happy with the wave packet, as it is localised. But if we change to the electron's rest ...
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What does $\Psi^*$ mean in Schrodinger's formulation of Quantum Mechanics?

I am not a physics student. In one of my courses, some fundamental concepts of Quantum mechanics were needed, so I was going through them when I stumbled upon this. It says $$\text{probability} = ...
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Does the wave nature of a particle refer to the wave function?

In quantum mechanics when we talk about the wave nature of particles are we referring in fact to the wave function? Does the wave function describes the probability of finding a particle (ex: ...
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What is the analogy of $|x\rangle$ in quantum field theory?

Let me start from path integral formulation in quantum mechanics and quantum field theory. In QM, we have $$ U(x_b,x_a;T) = \langle x_b | U(T) |x_a \rangle= \int \mathcal{D}q e^{iS} \tag{1} $$ ...
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161 views

How does a unique electron probability distribution correspond to one wavefunction?

I'm reading the Wikipedia article on DFT, and it says that there is a one-to-one correspondence between the ground state particle density $$n_0(\vec{r}) = N \int \text{d}^3 r_2 \int \text{d}^3 r_3 ...
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284 views

Why do we must initially assume that the wavefunction is complex?

The sound waves are real, and they can interfere, so corresponding apparat may be used in quantum mechanics. We also may use the time dependence in a form of orthogonal matrix multiplying the initial ...
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592 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
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128 views

Confused over the presence of 2 expressions for $\Psi(x,t)$

I'm following Griffiths' Introduction to Quantum Mechanics, and I see that he's got 2 different expressions for $\Psi(x,t)$. One of them is ...
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497 views

How to compute the expectation value $\langle x^2 \rangle$ in quantum mechanics?

$$\langle x^2 \rangle = \int_{-\infty}^\infty x^2 |\psi(x)|^2 \text d x$$ What is the meaning of $|\psi(x)|^2$? Does that just mean one has to multiply the wave function with itself?
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196 views

Expected value inequality

Why is $\langle p^2\rangle >0$ where $p=-i\hbar{d\over dx}$, (noting the strict inequality) for all normalized wavefunctions? I would have argued that because we can't have $\psi=$constant, but ...
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Speed of a particle in quantum mechanics: phase velocity vs. group velocity

Given that one usually defines two different velocities for a wave, these being the phase velocity and the group velocity, I was asking their meaning for the associated particle in quantum mechanics. ...
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130 views

What does the notation $\Psi_k/(\Psi_k,\Psi_k)^{1/2} $ mean?

I am currently reading the paper "Gravitation and quantum mechanics for macroscopic objects" by F. Karolyhazy (1966). In his paper, he uses certain notation that I haven't come across before (he also ...
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Time Reversal Operator

I know that time reversal operator is an antiunitary operator. How does it work on wavefunctions? I believe in this way: $$T \psi (k,+)=e^{i\pi S_y/\hbar} K \psi (k,+) = \psi^*(-k,-),$$ but I am not ...
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113 views

How do you determine the “phase” of a hydrogen eigenfunction?

I've been reading the wikipedia article on the atomic orbitals of hydrogen. They have a nice collection of diagrams, such as this one for n,l,m = 3,1,1 This is apparently showing the wavefunction, ...
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77 views

Quantum Wavefunctions Without Space

A handful of physicists have a rather peculiar definition of 'nothing' in terms of cosmology. Their claim is that the Universe, assuming it has 0 total energy, could have arisen from nothing but ...
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161 views

Why is $\omega = \sqrt{K/m}$ valid for a quantum oscillator?

I'm working in the 3rd edition of Modern Physics by Serway, Moses, and Moyer. In 6.6, it talks about a quantum oscillator. I don't fully understand how the definition of frequency works. Now, we ...
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121 views

Why do we use $\psi$ instead of a straightforward probability?

What is the advantage/purpose of using $\psi$ for wavefunctions and getting the probability with $|\psi|^2$ as opposed to just defining and using the probability function?
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At what point is the spin determined in a Stern-Gerlach Apparatus

Consider a particle with spin that travels through a Stern Gerlach box (SGB), which projects the particle’s spin onto one of the eigenstates in the $z$-direction. The SGB defines separate trajectories ...
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Why does $\ell=0$ correspond to spherically symmetric solutions for the spherical harmonics?

In quantum mechanics why do states with $\ell=0$ in the Hydrogen atom correspond to spherically symmetric spherical harmonics?
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Wavefunction as a combination of two stationary states - how to find those states?

Lets say we have a particle in a infinite square well which has a wavefunction like this ($A$ is some constant and $d$ is the width of the well): \begin{align} A\left[ \sin \left(\frac{2 \pi ...
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Vector representation of wavefunction in quantum mechanics?

I am new to quantum mechanics, and I just studied some parts of "wave mechanics" version of quantum mechanics. But I heard that wavefunction can be represented as vector in Hilbert space. In my eye, ...
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Can we impose a boundary condition on the derivative of the wavefunction through the physical assumptions?

Consider the Schrödinger equation for a particle in one dimension, where we have at least one boundary in the system (say the boundary is at $x=0$ and we are solving for $x>0$). Sometimes we want ...
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Projection of wavefunction onto basis function

I am given to believe that one way that one would could represent a wavefunction is by the expansion $$\Psi(x) = \Sigma_n \Psi_n(x) = \Sigma_n f_n\phi_n(x) \tag{1}$$ where $\{\phi_n (x) \}$ is an ...
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How does a Wavefunction collapse?

I have been wondering and researching... How does a wavefunction collapse into one state?More specifically, what conditions cause a wavefunction for a quantum particle to collapse? Does this have to ...
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Infinitely many degeneracy of Landau level: Countable or Uncountable?

Description of Landau levels can be found in many standard textbooks of quantum mechanics and here. Two ubiquitous solutions apply either the symmetric gauge $\vec{A}=(-\frac{1}{2}By,\frac{1}{2}Bx,0)$ ...
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75 views

Probability of measuring momentum [closed]

Suppose we have this wavefunction: $$ \psi = A \left( cos(kx) + cos (2kx) \right) $$ I have to find the possible results of measurement of momentum and their probabilities. Attempt For a momentum ...
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233 views

Harmonic Oscillator potential, proof that Gaussians remain Gaussians?

I read in several papers that for a Harmonic Oscillator Hamiltonian in the time dependent Schrödinger equation a Gaussian wave packet remains Gaussian. Unfortunately I could not find any proof for ...
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Connection between a simple matter wave and Heisenberg's uncertainty relation

When looking at the wave function of a particle, I usually prefer to write $$ \Psi(x,t) = A \exp(i(kx - \omega t)) $$ since it reminds me of classical waves for which I have an intuition ($k$ ...
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Hydrogen wave function in momentum space

We can seperate the wave function of an hydrogen atom in a radial and an angle part: $$ \phi_{n,l,m} (\mathbf{r}) = R_{n,l,m}(r) Y_{l,m}(\vartheta,\varphi) \, , $$ where $Y_{l,m}$ are the spherical ...
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Even and Odd States of a 1D finite potential well

Is it possible for a particle trapped in a 1D finite potential well to evolve from a even state to an odd state and vice-versa? Why?
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wavefunction collapse and uncertainty principle

We all know that wavefunction collapse when it is observed. Uncertainty principle states that $\sigma_x \sigma_p \geq \frac {\hbar}{2}$. When wavefunction collapse, doesn't $\sigma_x$ become $0$?, as ...
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Is $\phi_n =\left\langle \vec r | n \right\rangle $ the photon wave function?

I am a bit confused about this issue and I am still not clear whether is there is a photon wave function or not. Since we use Fock states $| n \rangle$ to represent the state of a quantized ...
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184 views

1D Finite potential well: solutions with $\sinh$ and $\cosh$?

So I am studying the (one dimensional) quantum mechanical finite potential well defined by: $$ V(x) = \cases{0, &|x|>a\cr -V_0, &|x|<a} $$ where $V_0>0$ is a real number. I know ...
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Normalising a wave function in parts?

If we have the wave function $\psi_{100}(r,\theta,\phi)=R_{10}(r)Y_{00}(\theta,\phi)$ when we are normalising it we do the following: $$1=\int| \psi_{100}(r,\theta,\phi)|^2sin(\theta) r^2drd\theta ...
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Formulation and probability of a wave-function [closed]

I have got this problem where I have been given the following wave function: $$\Psi = 0\quad\text{if}~|x| > a\quad\text{and}\quad A(a^2-x^2)\quad \text{if} \quad |x|< a$$ Now the first question ...
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Expectation values-Wavefunction

I'm a bit puzzled about an excercise in which I have to find the expectation values for position and momentum. Normally this should be pretty easy but in this case I just don't get the point. ...
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What methods exist for us to measure the position and momentum of atoms that make up molecules?

In this paper, Localization of an atom by homodyne measurement. A. M. Herkommer et al. Quantum Semiclass. Opt. 8 no. 1, p. 189 (1996) (paywalled). the authors are able to localize atoms using ...
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Interpretation of $e|\psi|^2$ as electron density

In solid state physics the electron density is often equated to $e|\psi|^2$. However, the Sakurai says (Chapter 2.4, Interpretation of the Wave Function, p. 101) that adopting such a view leads "to ...
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Finding $\psi(x,t)$ for a free particle starting from a Gaussian wave profile $\psi(x)$

Consider a free-particle with a Gaussian wavefunction, $$\psi(x)~=~\left(\frac{a}{\pi}\right)^{1/4}e^{-\frac12a x^2},$$ find $\psi(x,t)$. The wavefunction is already normalized, so the next thing to ...
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Transmission and reflection

What is the transmission amplitude of a wavefunction $\phi(x)=e^{ikx}(\tanh x -ik)$? I would have thought that it is $\tanh x -ik$ since this is the factor associated with the forward travelling ...
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Majorana wavefunction

I'm trying to compute the wavefunction for a Majorana state in an nanowire/superconductor hybrid system, like arXiv: Majorana Fermions and a Topological Phase Transition in ...
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Functionals of quantum states in QFT

Almost every book and article I can think of represents states of QFT using the Heisenberg picture of Hilbert space vectors, but Visser in "Lorentzian wormholes" does mention that you can also ...
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How do I figure out the probability of finding a particle between two barriers?

Given a delta function $\alpha\delta(x+a)$ and an infinite energy potential barrier at $[0,\infty)$, calculate the scattered state, calculate the probability of reflection as a function of ...
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Is there any operator behind probability, in quantum mechanics?

In Quantum mechanics, the probability of finding a particle at position $x$ is given by $|\psi(x)|^2$, where $\psi$ is the wave function. Wonder what is the operator which gives this probability? Is ...
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Text interpretation in Griffith's intro to QM

It says in Griffith's chapter 2.1, that: $$\tag{2.14} \Psi(x,t)~=~\sum_{n=1}^{\infty}c_n\,\psi_n(x) e^{(-iE_n t/\hbar)}$$ It so happens that every solution to the (time-dependent) Schrodinger ...
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Sinusoidal Wave Displacement Function

I am learning about waves (intro course) and as I was studying Wave Functions, I got a little confused. The book claims that the wave function of a sinusoidal wave moving in the $+x$ direction is ...