A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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States and observables in quantum mechanics

I'm beginning learn quantum mechanics. As I understand, state is a map $\phi$ from $L^2(\mathbb R)$ such that $|\phi|^2$ describes probability density of a particle's position. By integrating ...
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283 views

wave superposition of electrons and quarks

Is quantum wave superposition of electrons and quarks possible? If not, can different types of elementary particles be mixed in wave superposition?
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924 views

Matter waves and de Broglie wave length

The wavelength of a particle of momentum p is calculated using De Broglie relation. The de Broglie relation was postulated for what is called a matter waves. Now according to the statistical ...
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190 views

Interpretation of de Broglie wave

Until what point can the de Broglie wave be thought as a real wave? I mean, is it made of something? What amplitude does it have? Is it a sine wave? How can it be related to the wavefunction of the ...
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116 views

Confused over the presence of 2 expressions for $\Psi(x,t)$

I'm following Griffiths' Introduction to Quantum Mechanics, and I see that he's got 2 different expressions for $\Psi(x,t)$. One of them is ...
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1k views

Probability current

Conservation of probability: Suppose a wavefunction has ${\partial \mathbb P \over \partial t} = -t f(x,t)$ and ${\partial j \over \partial x} = i f(x,t)$. How does it follow that ${\partial \mathbb P ...
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Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
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141 views

Does Schrödinger equation have dual-property with Heat equation?

I have experimental data that Schödinger equation maintains high frequencies, while heat equation low. Does Schrödinger equation have some duality property with heat equation?
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186 views

Orbital of Hydrogen molecule

does anybody here know an analytical approximation of the bonding hydrogen orbital MOLECULE? I am looking for a good approximation to this orbital, that might be in some textbooks to get an ...
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557 views

Solving a time independent Schrödinger equation with a given potential

I'm trying to rework this old homework problem, and I am having problems arriving at the same solution on the answer sheet: Let $$V(x)=\begin{cases}\infty &\text{ if } x < 0\\ ...
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2answers
627 views

Vector representation of wavefunction in quantum mechanics?

I am new to quantum mechanics, and I just studied some parts of "wave mechanics" version of quantum mechanics. But I heard that wavefunction can be represented as vector in Hilbert space. In my eye, ...
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191 views

What does the notation $|x_1,x_2\rangle$ mean?

I would like clarification on an equation in the paper "Free matter wave packet teleportation via cold-molecule dynamics", L. Fisch and G. Kurizki, Europhysics Letters 75 (2006), pp. 847-853, DOI: ...
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Why do we consider the evolution (usually in time) of a wave function?

Why do we consider evolution of a wave function and why is the evolution parameter taken as time, in QM. If we look at a simple wave function $\psi(x,t) = e^{kx - \omega t}$, $x$ is a point in ...
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186 views

Why don't cancelling wavefunctions for two different particles give zero total wavefunction?

Let $\left|a\right>=e^{i(kx-\omega t)}$, $\left|b\right>=-e^{i(kx-\omega t)}$ be two neutral particles in the 1D free space without any interaction. Then ...
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178 views

Can a wave possess spin?

Since a matter wave is associated with a particle in quantum mechanics, does the wave spins? I mean, can we visualize the spinning of wave or is it possible that the wave spins?
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44 views

Free particle Schrödinger Equation

Some sources give the free-particle solution to Schrödinger equation as $$\psi(x,t) =Ae^{i(kx-\omega t)} + Be^{-i(kx+\omega t)}$$ while some sources give it as $$\psi(x,t) =Ae^{i(kx-\omega t)}$$ ...
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89 views

Two ways of calculating the expectation value of momentum

The expectation value of momentum is given by: $$ \langle p\rangle = \int_{-\infty}^{\infty}\psi^{*}(x)\left(-i\hbar\frac{\partial}{\partial x}\right)\psi(x)dx $$ How can I show that the above ...
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77 views

Spin state of electron after measurement

I have a system of two spin 1/2 particles in a superposition of spin states in the z-direction given by: $\psi = \frac{1}{2} |+ +\rangle + \frac{1}{2} |+ -\rangle + \frac{1}{\sqrt{2}} |- -\rangle$ ...
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122 views

Is $v(p)\exp(ipx)$ really the positron wave function?

In many textbooks the negative energy solution of the Dirac equation is quoted as describing the positron. Actually I don't understand this. For me $v(p)\exp(ipx)$ is the wave function of an electron ...
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332 views

Wave function collapse

When we try to measure the position of a system, wavefunction collapses to form a spike. After a while, the wavefunction spreads again, and you take another measurement, the results will be different" ...
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Wavefunction as a combination of two stationary states - how to find those states?

Lets say we have a particle in a infinite square well which has a wavefunction like this ($A$ is some constant and $d$ is the width of the well): \begin{align} A\left[ \sin \left(\frac{2 \pi ...
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1answer
550 views

Hydrogen wave function in momentum space

We can seperate the wave function of an hydrogen atom in a radial and an angle part: $$ \phi_{n,l,m} (\mathbf{r}) = R_{n,l,m}(r) Y_{l,m}(\vartheta,\varphi) \, , $$ where $Y_{l,m}$ are the spherical ...
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463 views

Why does a plane wave have definite momentum?

Apologies if this is a little vague. It might not have a good answer. Given the interpretation of $|\psi(x)|^2$ as a probability distribution it's unsurprising that a wave function that is ...
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In the expansion of the scattered wave function, why do these two functions have the same index?

See Griffiths Quantum Mechanics, eq. 11.21. Evidently, $$\psi(r,\theta,\phi)=Ae^{ikz}+A\sum\limits_{l,m}^{\infty}C_{l,m}h_{l}(kr)Y_{l}^{m}(\theta,\phi).$$ But I don't see why the $l$th Hankel function ...
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Does quantum mechanics predict instantaneous action at a distance even without entanglement?

The suggestion that quantum mechanics implies that instantaneous action at a distance occurs is normally based on the contention that this follows from the entanglement of particles that share a ...
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How do I solve these integrals of wave function and operator?

First integral $$\int \Psi^*({\bf r},t)\hat {\bf p} \Psi({\bf r},t)\, d^3r,$$ where the $\Psi({\bf r},t)=e^{i({\bf k}\cdot{\bf r}-\omega t)}\,\,\,$ and $\hat {\bf p}=-i\hbar \nabla$. Second one ...
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Can we impose a boundary condition on the derivative of the wavefunction through the physical assumptions?

Consider the Schrödinger equation for a particle in one dimension, where we have at least one boundary in the system (say the boundary is at $x=0$ and we are solving for $x>0$). Sometimes we want ...
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1answer
538 views

Superposition of wavefunctions

Suppose you have 2 normalized wavefunctions $\psi_1=Ne^{iax}e^{if(x)}e^{i\omega t}$ and $\psi_2=Ne^{-iax}e^{if(x)}e^{i\omega t}$ defined on $x\in [-x_0,x_0]$ and vanishes for $|x|>x_0$. What then ...
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445 views

Simple rotation of an atomic orbital wavefunction

We know that an atomic orbital wavefunction may be written in terms of polar coordinates, $$\psi (r, \theta, \phi) = R(r) A(\theta, \phi)$$ where $R(r)$ is the radial component and $A(\theta, \phi)$ ...
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76 views

Three dimensional wave packets in momentum space

I am given the 3D wave packet: $$\psi(x,y,z)=N\,\exp\left(\frac{-(x^2+y^2+2z^2)}{2a^2}\right).$$ I was asked to find N (easy enough). Then I was asked the probability that we measure $z$ greater than ...
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48 views

Transition from coordinate space to momentum space for SHO

I am given that the ground state of the SHO in position space is given as $$\langle q|\psi_0\rangle=\frac{1}{a^{\frac12}\pi^{\frac14}}e^{-q/4a^2}$$ Where a is a constant with units of length. I am ...
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Solving quantum radial equation for infinite potential spherical annulus for $l=0$

There is a mass $m$ in a potential such that $$ V(r) = \left\{ \begin{array}{lr} 0, & a \leq r \leq b\\ \infty, & \text{everywhere else} \end{array} \right. $$ ...
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99 views

Product of position eigenvectors at different times

I've been thinking about this, and it might sound like a stupid question, but I can't seem to find an answer anywhere, here goes: Whenever we calculate expecation-values between two position ...
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684 views

Overlap integral and probability

I have a question regarding how to extract probability from an overlap integral. Specifically, I am calculating the probability of a particle in a bound state in a delta potential $V=-\alpha ...
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124 views

Workaround to fermion sign problem?

My (rather incomplete) understanding of the NP-hard fermion/numerical sign problem is that it occurs when attempting to converge on a wavefunction for many-body fermion systems (for example, a small ...
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1answer
291 views

A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
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139 views

Decomposition of this wave function in eigenfunctions

I have this wave function of a system on a central potential: $V(r)$: $$\Phi(x,y,z)=C(x+y+z)e^{-\alpha r^2}.$$ And I'm asked a few things about probabilities. I don't have problems with that, because ...
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184 views

Harmonic oscillator - wavefunctions

I understand now how I can derive the lowest energy state $W_0 = \tfrac{1}{2}\hbar \omega$ of the quantum harmonic oscillator (HO) using the ladder operators. What is the easiest way to now derive ...
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Why the hydrogen radial wave function is real?

Why the hydrogen radial wave function is real? Is it a coincidence?
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729 views

Wave function and Dirac bra-ket notation

Would anyone be able to explain the difference, technically, between wave function notation for quantum systems e.g. $\psi=\psi(x)$ and Dirac bra-ket vector notation? How do you get from one to the ...
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In Dirac notation, what do the subscripts represent? (Solution for particle in a box in mind)

So the set of solutions for the particle in a box is given by $$\psi_n(x) = \sqrt{\frac{2}{L}}\sin(\frac{n\pi x}{L}).$$ In Dirac notation $<\psi_i|\psi_j>=\delta_{ij}$ assuming $|\psi_i>$ ...
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What's the physical significance of the inner product of two wave functions in quantum region?

I am a reading a book for beginners of the quantum mechanics. In one section, the author shows the inner product of two wave functions $\langle\alpha\vert\beta\rangle$. I am wondering what's the ...
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2answers
511 views

Non-Degeneracy of Eigenvalues of Number Operator for Simple Harmonic Oscillator [duplicate]

Possible Duplicate: Proof that the One-Dimensional Simple Harmonic Oscillator is Non-Degenerate? I'm trying to convince myself that the eigenvalues $n$ of the number operator ...
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4answers
483 views

If wave packets spread, why don't objects disappear?

If you have an electron moving in empty space, it will be represented by a wave packet. But packets can spread over time, that is, their width increases, with it's uncertainty in position increasing. ...
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1answer
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Does wavefunction reach its largest peak near(not in) the classical forbidden region?

As we can see in the picture in this website: http://ctz116.ust.hk/xyli2/images/animation/quchem73.html It's strange that the bound state wavefunction always reach its largest peak near the boundary ...
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Considering the wave function is not 'real', what is interfering?

I find the idea of the wave function being 'just' a collection of numbers (probabilities) quite alluring, and elegant in explaining away the whole 'collapse' business (see Luboš' answer to this ...
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Why Pauli exclusion instead of electrons canceling out?

To quote Wikipedia, The Pauli exclusion principle is the quantum mechanical principle that no two identical fermions (particles with half-integer spin) may occupy the same quantum state ...
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Angular momentum operator and expectation values

I was reading some notes and it says that $\langle L_z^2\rangle=\langle L^2\rangle$ IFF the system is radially symmetric. I can see that in order that the LHS of the statement implies that $\langle ...
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How to calculate time evolution of a wave function in an 1D infinite square well potential?

A particle in an infinite square well has an initial wavefunction $$\psi (x,0) ~=~ Ax(a-x) \qquad \mathrm{for}\qquad 0\leq x\leq a.$$ Now the question is to calculate $\psi (x,t)$. I have ...
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Are Everettian branchings global or local?

Everett's theory of quantum mechanics is about the wavefunction of the whole universe holistically. If a branching occurs very far away at the Andromeda galaxy, do I also branch? Are branchings global ...