A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Floquet quasienergy spectrum, continuous or discrete?

I haven't got a feeling about Floquet quasienergy, although it is talked by many people these days. Floquet theorem: Consider a Hamiltonian which is time periodic $H(t)=H(t+\tau)$. The ...
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893 views

Bohr-Sommerfeld quantization from the WKB approximation

How can one prove the Bohr-Sommerfeld quantization formula $$ \oint p~dq ~=~2\pi n \hbar $$ from the WKB ansatz solution $$\Psi(x)~=~e^{iS(x)/ \hbar}$$ for the Schroedinger equation? With $S$ the ...
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Does quantum mechanics allow faster than light (FTL) travel?

Let's suppose I initially have a particle with a nice and narrow wave function[1] (I will leave these unnormed): $$e^{-\frac{x^2}{a}}$$ where $a$ is some small number (to make it narrow). Let's also ...
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506 views

Non-separable solution for the Schrödinger equation

Schrödinger solutions are usually if not always of the type: $\psi=\operatorname{T}(t)*\operatorname{X}(x)$ (we use the separation of variables method to arrive at the time independent Schroedinger ...
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178 views

What state the wave function collapses into after an inaccurate measurement?

I'm watching MIT online lectures Quantum Physics I (roughly from one hour mark in the video). The lecturer explains wave functions that describe "Stationary States" that consist of a single energy ...
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210 views

How can I solve this quantum mechanical “paradox”?

Let a (free) particle move in $[0,a]$ with cyclic boundary condition $\psi(0)=\psi(a)$. The solution of the Schrödinger-equation can be put in the form of a plane wave. In this state the standard ...
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523 views

Confusion about wavefunction separability

A wavefunction is inherently a multi-particle function. If you have a container that is perfectly isolated from the external universe (not possible, but just imagine it) and filled with $n$ ...
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Momentum of particle in a box

Take a unit box, the energy eigenfunctions are $\sin(n\pi x)$ (ignoring normalization constant) inside the box and 0 outside. I have read that there is no momentum operator for a particle in a box, ...
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Is it guaranteed that wavefunction is well behaved everywhere?

I don't really know much about Quantum mechanics, but would like to know one simple fact. The state function $\Psi(r, t)$ whose magnitude gives the probability density of the position of the particle ...
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Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ ...
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404 views

Imaginary Eigenvalue Of A Hermitian Operator

The eigenfunctions of a Hermitian operator are real. But consider a function $\psi(x)=e^{-\kappa x}$, $x\in\mathbb{R}$, where $\kappa$ is a real constant. Then, $$\hat p \psi(x)=-i\hbar ...
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778 views

How is the Pauli Exclusion Principle a consequence of antisymmetric wavefunction?

How is the Pauli Exclusion Principle a consequence of antisymmetric wavefunction?
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415 views

Does a wavefunction interact with itself?

Considering the double slit experiment with a charged particle, after the particle passes through the slits, do the two portions of the wavefunctions feel the electromagnetic attraction of the other ...
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286 views

Can general wavefunctions be expressed as kets?

I am confused on bra-ket notation in quantum mechanics. My professor says that a ket is an eigenfunction of some operator. However, for some time now I thought a ket could represent a general ...
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858 views

Meaning of $\int \phi^\dagger \hat A \psi \:\mathrm dx$

While analysing a problem in quantum Mechanics, I realized that I don't fully understand the physical meanings of certain integrals. I have been interpreting: $\int \phi^\dagger \hat A \psi ...
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Speed of a particle in quantum mechanics: phase velocity vs. group velocity

Given that one usually defines two different velocities for a wave, these being the phase velocity and the group velocity, I was asking their meaning for the associated particle in quantum mechanics. ...
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809 views

Is the wave function objective or subjective?

Here is a question I am curious about. Is the wave function objective or subjective, or is such a question meaningless? Conventionally, subjectivity is as follows: if a quantity is subjective then ...
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359 views

Confusion about 1-forms as introduced in “Gravitation” (Kip S. Thorne,…)

In the book Gravitation in chapter 2, paragraph 5, they introduce the concept of 1-forms by thinking about the momentum 4-vector differently. They first introduce the de Broglie 1-form as follows (I ...
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264 views

Inexact measurement and wavefunction collapse

As is usually said, measurement of an observable $q$ leads to collapse of wavefunction to an eigenstate of the corresponding operator $\hat q$. That is, now the wavefunction in $q$ representation is ...
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768 views

How to compute the expectation value $\langle x^2 \rangle$ in quantum mechanics?

$$\langle x^2 \rangle = \int_{-\infty}^\infty x^2 |\psi(x)|^2 \text d x$$ What is the meaning of $|\psi(x)|^2$? Does that just mean one has to multiply the wave function with itself?
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803 views

Can we impose a boundary condition on the derivative of the wavefunction through the physical assumptions?

Consider the Schrödinger equation for a particle in one dimension, where we have at least one boundary in the system (say the boundary is at $x=0$ and we are solving for $x>0$). Sometimes we want ...
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444 views

Physical meaning of quantum operators

Let's say we have a wavefunction $\psi$ and a measurement operator $\hat A$. I understand how eigenvalues and eigenvectors of $\hat A$ describe the possible outcomes of the measurement. I also ...
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664 views

How can particles travel in a straight line?

A particle can be set off in a certain direction by giving them momentum. Momentum is a vector, so the particle heads off in a specific direction. But the wave function of the particle allows it to ...
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323 views

Time Varying Potential, series solution

Suppose we have a time varying potential $$\left( -\frac{1}{2m}\nabla^2+ V(\vec{r},t)\right)\psi = i\partial_t \psi$$ then I want to know why is the general solution written as $\psi = ...
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127 views

Should the differential of a wavefunction have a time partial derivative?

In chapter 1 of Griffths' QM text, he shows that $\frac{\mathrm{d}}{\mathrm{d}t}\int_{-\infty}^{\infty}|\Psi|^2\,\mathrm{d}x=0$ by noting $$\begin{align} ...
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What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess ...
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342 views

No well-defined frequency for a wave packet?

There are similar questions to mine on this site, but not quite what I am asking (I think). The de Broglie relations for energy and momentum $$ \lambda = \frac{h}{p}, \\ \nu = E/h .$$ equate a ...
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125 views

Has anyone published the procedure to generalize ladder operators for any potential in Schrodinger's equation?

I know that the ladder operator for the quantum harmonic oscillator \begin{align} H\psi_m = \left(\dfrac{p^2}{2m}+\dfrac{1}{2}m\omega^2x^2\right)\psi_m=E_m\psi_m \end{align} is \begin{align} A = ...
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412 views

Ground state of Spherical symmetric potential always have $\ell=0$?

I was given a problem where I have a spherically symmetric potential (the exact form is not relevant to this question, I think - but anyway is it 0 for $r\in[a,b]$ and $\infty$ everywhere else) and I ...
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Orthonormality of Radial Wave Function

Is the radial component $R_{n\ell}$ of the hydrogen wavefunction orthonormal? Doing out one of the integrals, I find that $$\int_0^{\infty} R_{10}R_{21}~r^2dr ~\neq~0$$ However, the link below says ...
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345 views

Why must $\Psi (x,t)$ go to zero faster than $\frac{1}{\sqrt{|x|}}$?

Why must $\Psi (x,t)$ go to zero faster than $\frac{1}{\sqrt{|x|}}$ as $|x|$ goes to $\infty$? According to Griffiths' Introduction to Quantum Mechanics, it must. I don't understand why, and this is ...
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390 views

How do we know that electron wave function extends to infinity?

Why do physicists assume this? Is it a proven fact that wave function extends to infinity or just a theory? Would it make sense if they didn't extend to infinity?
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Effect of pressure increase on electron orbital wave functions

One of my nuclear physics exercises was to find out if increasing the pressure of a sample of $^{7}\textrm{Be}$ would increase the chance of electron capture to $^{7}\textrm{Li}$ occur. My reasoning ...
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444 views

Is the electron wave function defined during photon emission

I have heard the term quantum leap to describe the (instantaneous?) transition from a higher energy orbital to a lower energy orbital. Yet, I understand that this transition time has now been ...
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395 views

Boundary conditions from single-valuedness of spherical wavefunctions

This question is a follow-up to David Bar Moshe's answer to my earlier question on the Aharonov-Bohm effect and flux-quantization. What I forgot was that it is not the wavefunction that must be ...
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Physical position eigenfunction normalisation

We know that the Dirac function $$\delta(a)=\lim_{a \rightarrow 0} \delta_{a}(x)$$ can be written as an infinitesimally narrow Gaussian: $$ \delta_{a}(x) := \frac{1}{\sqrt{2\pi a^2}}e^{-x^2/2a^2}$$ ...
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Relativistic contraction for a wave packet and uncertainty on momentum

Consider an electron described by a wave packet of extension $\Delta x$ for experimentalist A in the lab. Now assume experimentalist B is flying at a very high speed with regard to A and observes the ...
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155 views

Do bras and kets have dimensions?

I'm trying to understand more intuitively what bras and kets are, but some aspects of them remain a mystery to me. We usually think of $\psi (x)$ as having dimension of $[1/\sqrt{L}]$ so that ...
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190 views

Is the ground state closest to the uncertainty relation? [duplicate]

For simplicity, suppose we are only talking about discrete energy levels, ie, bound state case. The energy levels are $E_1, E_2\cdots$, and the corresponding wave functions are $\psi_1, \psi_2 ...
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219 views

Which position and momentum distributions arise from some wave function?

Consider a particle in one dimension with wave function $\psi(x)$. The probability density function describing how likely it is to find it in a given position is given by ...
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Is the wave function of a particle re-created after a measurement stops?

Yeah, I haven't quite understood, or been told, what happens to, for example an electron and it's wavefunction, when you stop to measure it? I mean, an electron has a wave function describing it's ...
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Is there a direct physical interpretation for the complex wavefunction?

The Schrodinger equation in non-relativistic quantum mechanics yields the time-evolution of the so-called wavefunction corresponding to the system concerned under the action of the associated ...
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753 views

Can the chance of finding a particle diminish over time?

Let's assume we have a wave function described by a wave equation and it is a function of space and time $\psi : \mathbb{R}^4 \rightarrow \mathbb{C}$. This function needs to be normalized, so if I ...
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534 views

Schroedinger equation for hydrogen atom

I have got a problem understanding the meaning of the Laplace operator in the Schrödinger equation for the hydrogen atom. $$\Big(-\frac{\hbar^2}{2m_e} \Delta_{r_e} - \frac{\hbar^2}{2M_P} \Delta_{r_p} ...
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356 views

Where to place the operator?

I believe it's standard to place the operator in between the conjugate of the wavefunction and the wavefunction itself. For instance, $$\langle p\rangle = \int_{-\infty}^{\infty}\Psi * ...
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Is the free electron wavefunction stable?

The wavefunction of a free electrons is variously described as a plane wave or a wave packet. I am fairly happy with the wave packet, as it is localised. But if we change to the electron's rest ...
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State of a system in Quantum Mechanics and state vectors

I'm taking a course in Quantum Mechanics and there is something I'm not being able to fully understand. On more elementary courses on Quantum Mechanics I've been told that the idea of Quantum ...
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617 views

Help me understand the first equation in Landau & Lifshitz's Quantum Mechanics

While I've covered a basic course in Quantum Mechanics, I'm self-studying Landau & Lifshitz's book to help me understand what's going on. Unfortunately, I'm stuck on the very first equation in ...
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813 views

Why does the wave function have to be continuous? [duplicate]

When solving one dimensional problems in quantum mechanics it is often assumed that the first derivative of the wave function is continuous. What justifies this assumption?
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Vector representation of wavefunction in quantum mechanics?

I am new to quantum mechanics, and I just studied some parts of "wave mechanics" version of quantum mechanics. But I heard that wavefunction can be represented as vector in Hilbert space. In my eye, ...