A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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What is the wavefunction of the Young Double Slit experiment?

I have never seen the wavefunction for this experiment and would like to know how to derive it using the Schrodinger equation. I specifically want to see how the electron wave function leaves the ...
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686 views

When can we assume that the wavefunction is separable

While working out the stationary states of a single particle in a 3d infinite potential box ($V=0$ inside a cuboid of known dimensions, $V=\infty$ everywhere else), I realized I had to assume the ...
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What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess I'...
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451 views

Virial theorem and variational method: a question

I have an hydrogenic atom, knowing that its ground-state wavefunction has the standard form $$ \psi = A e^{-\beta r} $$ with $A = \frac{\beta^3}{\pi}$, I have to find the best value for $\beta$ (...
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Superconducting Wavefunction Phase (Feynman Lectures)

In Volume 3, Section 21-5 of the Feynman lectures (superconductivity), Feynman makes a step that I can't quite follow. To start, he writes the wavefunction of the ground state in the following form (...
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Hydrogen radial wave function infinity at $r=0$

When trying to solve the Schrödinger equation for hydrogen, one usually splits up the wave function into two parts: $$\psi(r,\phi,\theta)= R(r)Y_{l,m}(\phi,\theta).$$ I understand that the radial ...
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487 views

Am I missing a trick to solving a 3D potential well problem?

I was playing around with a 3-D potential $V$ such that $V_{(r)} = 0$ for $r<a$, and $V_{(r)} = V_0>0$ otherwise. By using the Schrödinger Equation, I showed that: $$\frac{-\hbar}{2m}\frac{1}{r^...
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Example of the time-independent Schrödinger equation having a complex solution?

We know $\Psi(x,t)$ is complex, but can $\Psi(x)$ be complex? I have seen particle in a box, well and harmonic oscillator. All have real solutions for time-independent Schrödinger equation. Hence, I ...
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What is the relation between position and momentum wavefunctions in quantum physics?

I have read in a couple of places that $\psi(p)$ and $\psi(q)$ are Fourier transforms of one another (e.g. Penrose). But isn't a Fourier transform simply a decomposition of a function into a sum or ...
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953 views

Meaning of $\int \phi^\dagger \hat A \psi \:\mathrm dx$

While analysing a problem in quantum Mechanics, I realized that I don't fully understand the physical meanings of certain integrals. I have been interpreting: $\int \phi^\dagger \hat A \psi \:\...
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423 views

Why do we must initially assume that the wavefunction is complex?

The sound waves are real, and they can interfere, so corresponding apparat may be used in quantum mechanics. We also may use the time dependence in a form of orthogonal matrix multiplying the initial ...
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598 views

Could quantum mechanics work without the Born rule?

Slightly inspired by this question about the historical origins of the Born rule, I wondered whether quantum mechanics could still work without the Born rule. I realize it's one of the most ...
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Amplitude of Probability amplitude. Which one is it?

QM begins with a Born's rule which states that probability $P$ is equal to a modulus square of probability amplitude $\psi$: $$P = \left|\psi\right|^2.$$ If I write down a wave function like this $\...
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467 views

Wave function in quantum mechanics

I was wondering about something while studying quantum mechanics. If the wave function collapses when measuring a particle and assumes a single position, how do we know that it was a wave in the first ...
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Infinite Wells and Delta Functions

In considering a delta potential barrier in an infinite well, I can just enforce continuity at the potential barrier-it doesn't have to go to zero. Why then does it need to go to zero at the walls of ...
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Speed of a particle in quantum mechanics: phase velocity vs. group velocity

Given that one usually defines two different velocities for a wave, these being the phase velocity and the group velocity, I was asking their meaning for the associated particle in quantum mechanics. ...
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Is the wave function objective or subjective?

Here is a question I am curious about. Is the wave function objective or subjective, or is such a question meaningless? Conventionally, subjectivity is as follows: if a quantity is subjective then ...
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Can expectation value be imaginary?

I was solving a problem and the result of the expectation value of an operator came out to be $-\frac{\hbar}{4}$ $i$. Is this result possible? It seems counter intuitive.
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Why does the wave function have to be continuous? [duplicate]

When solving one dimensional problems in quantum mechanics it is often assumed that the first derivative of the wave function is continuous. What justifies this assumption?
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Physical meaning of quantum operators

Let's say we have a wavefunction $\psi$ and a measurement operator $\hat A$. I understand how eigenvalues and eigenvectors of $\hat A$ describe the possible outcomes of the measurement. I also ...
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Confused over complex representation of the wave

My quantum mechanics textbook says that the following is a representation of a wave traveling in the +$x$ direction:$$\Psi(x,t)=Ae^{i\left(kx-\omega t\right)}\tag1$$ I'm having trouble visualizing ...
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Schrödinger equation in position representation

We start from an abstract state vector $ \newcommand{\ket}[1]{|{#1}\rangle} \ket{\Psi}$ as a description of a state of a system and the Schrödinger equation in the following form $$ \...
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Ground state of Spherical symmetric potential always have $\ell=0$?

I was given a problem where I have a spherically symmetric potential (the exact form is not relevant to this question, I think - but anyway is it 0 for $r\in[a,b]$ and $\infty$ everywhere else) and I ...
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515 views

Floquet quasienergy spectrum, continuous or discrete?

I haven't got a feeling about Floquet quasienergy, although it is talked by many people these days. Floquet theorem: Consider a Hamiltonian which is time periodic $H(t)=H(t+\tau)$. The ...
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Bohr-Sommerfeld quantization from the WKB approximation

How can one prove the Bohr-Sommerfeld quantization formula $$ \oint p~dq ~=~2\pi n \hbar $$ from the WKB ansatz solution $$\Psi(x)~=~e^{iS(x)/ \hbar}$$ for the Schroedinger equation? With $S$ the ...
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Does quantum mechanics allow faster than light (FTL) travel?

Let's suppose I initially have a particle with a nice and narrow wave function[1] (I will leave these unnormed): $$e^{-\frac{x^2}{a}}$$ where $a$ is some small number (to make it narrow). Let's also ...
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Why must $\Psi (x,t)$ go to zero faster than $\frac{1}{\sqrt{|x|}}$?

Why must $\Psi (x,t)$ go to zero faster than $\frac{1}{\sqrt{|x|}}$ as $|x|$ goes to $\infty$? According to Griffiths' Introduction to Quantum Mechanics, it must. I don't understand why, and this is ...
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580 views

Non-separable solution for the Schrödinger equation

Schrödinger solutions are usually if not always of the type: $\psi=\operatorname{T}(t)*\operatorname{X}(x)$ (we use the separation of variables method to arrive at the time independent Schroedinger ...
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What state the wave function collapses into after an inaccurate measurement?

I'm watching MIT online lectures Quantum Physics I (roughly from one hour mark in the video). The lecturer explains wave functions that describe "Stationary States" that consist of a single energy ...
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Physical position eigenfunction normalisation

We know that the Dirac function $$\delta(a)=\lim_{a \rightarrow 0} \delta_{a}(x)$$ can be written as an infinitesimally narrow Gaussian: $$ \delta_{a}(x) := \frac{1}{\sqrt{2\pi a^2}}e^{-x^2/2a^2}$$ ...
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Mathematical definition of wavefront in case of non harmonic waves

What is the general mathematical definition of wavefront? Wavefront is the surface where, at fixed time, the phase is constant But for non-harmonic waves we cannot talk about phase as the ...
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268 views

Which position and momentum distributions arise from some wave function?

Consider a particle in one dimension with wave function $\psi(x)$. The probability density function describing how likely it is to find it in a given position is given by $f(x)=\left|\psi(x)\right|^2$....
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Is the wave function of a particle re-created after a measurement stops?

Yeah, I haven't quite understood, or been told, what happens to, for example an electron and its wavefunction, when you stop to measure it. I mean, an electron has a wave function describing its ...
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Wavefunctions in different Hilbert spaces

The state of a quantum system is represented by a wavefunction usually in some specific Hilbert space, .e.g of position, spin, momentum etc. But before deciding in which of these bases to decompose ...
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601 views

Confusion about wavefunction separability

A wavefunction is inherently a multi-particle function. If you have a container that is perfectly isolated from the external universe (not possible, but just imagine it) and filled with $n$ particles,...
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Momentum of particle in a box

Take a unit box, the energy eigenfunctions are $\sin(n\pi x)$ (ignoring normalization constant) inside the box and 0 outside. I have read that there is no momentum operator for a particle in a box, ...
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Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ $$\hat{p}e^{ipx}=pe^{...
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Imaginary Eigenvalue Of A Hermitian Operator

The eigenfunctions of a Hermitian operator are real. But consider a function $\psi(x)=e^{-\kappa x}$, $x\in\mathbb{R}$, where $\kappa$ is a real constant. Then, $$\hat p \psi(x)=-i\hbar \frac{d}{dx}e^{...
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Is it guaranteed that wavefunction is well behaved everywhere?

I don't really know much about Quantum mechanics, but would like to know one simple fact. The state function $\Psi(r, t)$ whose magnitude gives the probability density of the position of the particle ...
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986 views

How is the Pauli Exclusion Principle a consequence of antisymmetric wavefunction?

How is the Pauli Exclusion Principle a consequence of antisymmetric wavefunction?
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Does a wavefunction interact with itself?

Considering the double slit experiment with a charged particle, after the particle passes through the slits, do the two portions of the wavefunctions feel the electromagnetic attraction of the other ...
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Can general wavefunctions be expressed as kets?

I am confused on bra-ket notation in quantum mechanics. My professor says that a ket is an eigenfunction of some operator. However, for some time now I thought a ket could represent a general ...
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Confusion about 1-forms as introduced in “Gravitation” (Kip S. Thorne,…)

In the book Gravitation in chapter 2, paragraph 5, they introduce the concept of 1-forms by thinking about the momentum 4-vector differently. They first introduce the de Broglie 1-form as follows (I ...
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Inexact measurement and wavefunction collapse

As is usually said, measurement of an observable $q$ leads to collapse of wavefunction to an eigenstate of the corresponding operator $\hat q$. That is, now the wavefunction in $q$ representation is $\...
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Can a physical wavefunction be non-smooth (its first derivative is discontinuous)?

Here's an argument that might support the statement that such a non-smooth wavefunction is not physical: You cannot add a finite number of smooth functions to get a non-smooth function. By fourier ...
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How can particles travel in a straight line?

A particle can be set off in a certain direction by giving them momentum. Momentum is a vector, so the particle heads off in a specific direction. But the wave function of the particle allows it to ...
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How to compute the expectation value $\langle x^2 \rangle$ in quantum mechanics?

$$\langle x^2 \rangle = \int_{-\infty}^\infty x^2 |\psi(x)|^2 \text d x$$ What is the meaning of $|\psi(x)|^2$? Does that just mean one has to multiply the wave function with itself?
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Can we impose a boundary condition on the derivative of the wavefunction through the physical assumptions?

Consider the Schrödinger equation for a particle in one dimension, where we have at least one boundary in the system (say the boundary is at $x=0$ and we are solving for $x>0$). Sometimes we want ...
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Vector representation of wavefunction in quantum mechanics?

I am new to quantum mechanics, and I just studied some parts of "wave mechanics" version of quantum mechanics. But I heard that wavefunction can be represented as vector in Hilbert space. In my eye, ...
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Time Varying Potential, series solution

Suppose we have a time varying potential $$\left( -\frac{1}{2m}\nabla^2+ V(\vec{r},t)\right)\psi = i\partial_t \psi$$ then I want to know why is the general solution written as $\psi = \displaystyle\...