A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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What is the necessity of wave packet in studying matter wave?

I am new to this realm of physics. I have literally understood the matter wave, wave function; read the trapped electron in an infinite potential-well. But what I didn't understand is the concept of ...
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5answers
263 views

Normalizing the solution to free particle Schrödinger equation

I have the one dimensional free particle Schrödinger equation $$i\hbar \frac{\partial}{\partial t} \Psi (x,t) = -\frac{\hbar^2}{2m} \frac{\partial^2}{\partial x^2} \Psi (x,t), \tag{1}$$ with ...
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121 views

Relation between Wave equation of light and photon wave function?

Suppose in our double slit experimental setup with the usual notations $d,D$, we have a beam of light of known frequency $(\nu)$ and wavelength $(\lambda)$ - so we can describe it as $$ξ_0 = ...
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1answer
28 views

How do I interpret the math relating to diffraction?

The following is a quote from the Haifa Lectures (Mendel Sachs) But if both slits are open, the wave function for the electron penetrating screen S1 is the superposition of states, $(\psi_1 + ...
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237 views

Why does the wave function have to be continuous? [duplicate]

When solving one dimensional problems in quantum mechanics it is often assumed that the first derivative of the wave function is contineous. What justifies this assumption?
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29 views

Inverse Fourier Transfrom of a wavefunction

I was reading about how a Fourier transform yields the wave-function expressed in terms of the momenta which constitute it, i.e. the wave-function in momentum space. I'm not so good at calculus yet ...
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133 views

Wave functions as $x$ goes to infinity

This problem emerged when I was going through some QM exercises: I've been asked to find the commutator $[A,B]$ where $A,B$ are defined as $$A\psi(x)=x\frac{\partial }{\partial x}\psi(x),$$ ...
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1answer
65 views

If I want to determine a particle's momentum or position, do I get this information from the wave function?

I am confused about how one measures the dynamical variables (eg position) of a particle. I thought the wave function $\Psi(x,t)$ was the probability amplitude and $|\Psi(x,t)|^2$ represents the ...
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1answer
137 views

Position and momentum expectation values for the stationary states of the infinite square well [closed]

I'm really lost in figuring out how to solve the integral for the expectation value of $x$ and $x^2$ $$\int_0^a x \sin(\frac{n\pi}ax)^2 dx $$ This equation is from the $n$th stationary state ...
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$\newcommand{\b}[1]{\langle#1\rangle}$Is the expectation of an operator written as $\b{\psi|\hat A|\psi}$ or as $\b{\psi|\hat A|\psi}/\b{\psi|\psi}$?

I had presumed that the expectation of an operator is written as $\b{\hat A} = \b{\psi|\hat A|\psi}$, but some online reference insists on dividing the entire expression by $\b{\psi|\psi}$. Since ...
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39 views

Is it ever appropriate to write $| \phi(t)>$

I am trying to solve the Schrodinger's wave equation $\hat H |\psi(x,t)> = E|\psi(x,t)>$ using separation variables so that $\psi(x,t) = \psi(x)\phi(t)$ Solving the equation involves the step ...
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41 views

In the Double Slit Experiment, does the measuring device collapse the wave function?

PLEASE READ Many physicist say that the measuring device collapses the electron wave function because it is firing photons in order to measure the electron position. So, what collapses the electron ...
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“Reality” of EM waves vs. wavefunction of individual photons - why not treat the wave function as equally “Real”?

In thinking how to ask this question (somewhat) succinctly, I keep coming back to a Microwave Oven. A Microwave Oven has a grid of holes over the window specifically designed to be smaller in ...
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2answers
171 views

Calculation of the $\langle H \rangle$ for a particle in a box

I am working through a problem in which a particle is in an infinite potential well of length $L$ at $t=0$ before the spontaneous change of the box being expanded to length $2L$. I have calculated the ...
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4answers
146 views

Projection of wavefunction onto basis function

I am given to believe that one way that one would could represent a wavefunction is by the expansion $$\Psi(x) = \Sigma_n \Psi_n(x) = \Sigma_n f_n\phi_n(x) \tag{1}$$ where $\{\phi_n (x) \}$ is an ...
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1answer
145 views

Is the expression $S=K \log(\Psi)$ appearing in Schrödinger's first paper well defined?

I am currently reading Schrödinger's papers and happen to have some questions that maybe some expert in the field could clarify for me. Like what happens with $$S = K \log(\Psi)$$ when $\Psi<0$. ...
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Exercise about Bethe Ansatz for $N=3$ particles on a ring of length $L$

Suppose there are $3$ bosons living on a 1-dimensional ring of length $L$. The Hamiltonian is given by $$H=-\sum_{i=1}^3\frac{\partial^2}{\partial x_i^2}+\sum_{1\leq j<k\leq ...
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117 views

Rectangular window $\psi$ wave-function and the calculus of $\langle p^2\rangle$ for it

I'm currently considering a rectangular window $\psi$ function: $$ \psi(x) = \begin{cases}\left(2a\right)^{-1/2}&\text{for } |x|<a \\ 0&\text{otherwise.} \end{cases} $$ I am interested in ...
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49 views

Does Clairaut's Theorem apply to the Wave Function?

In Griffiths Intro to Quantum Mechanics, I came across a problem that asks the student to prove one of the consequences of the Ehrenfest theorem: $$\frac{d \langle p \rangle}{dt} = \left\langle - ...
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3answers
79 views

Classical Limit of the Quantum Harmonic Oscillator

The classical harmonic oscillator obeys an arcsine law in that the distribution of positions of the particle over a single time cycle is proportional to $\frac{1}{\sqrt{A^2-x^2}}$, $A$ being the ...
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Calculation of $\langle p\rangle$ and $\langle p^2\rangle$ for wave function [closed]

Given the wave function $$\psi(x)=A\exp\left[-a \left(\frac{mx^{2}}{\hbar}+it\right)\right]$$ I would like to calculate $\sigma_{p}$. \begin{align}\langle p\rangle &=\int ...
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0answers
36 views

Is the associated Laguerre polynomial $L_1^1(x)$ equal to $-1$ or $2 - x$?

I've been reading a book by Normand M. Laurendeau, Statistical Thermodynamics: Fundamentals and Applications, about hydrogen orbitals and in it is an equation that explains how to calculate the ...
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2answers
90 views

Bra-ket of products

I was trying to solve the following problem. (Lifted from Modern Quantum Chemistry: Introduction to Advanced Electronic Structure Theory by Szabo and Ostlund) I came across across a solution for ...
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2answers
117 views

How do you determine the “phase” of a hydrogen eigenfunction?

I've been reading the wikipedia article on the atomic orbitals of hydrogen. They have a nice collection of diagrams, such as this one for n,l,m = 3,1,1 This is apparently showing the wavefunction, ...
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132 views

Why does the electron wave function collapse in a double slit experiment?

Did the electron wave function collapse in the double slit experiment due to being observed, OR is it that the electron wave function collapsed because the instrument used to measure it physically ...
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0answers
93 views

Is hydrogen atom in a box solvable analytically?

Schrödinger's equation for hydrogen atom in free space can be easily solved by switching to center of mass frame, introducing reduced mass and separating variables in the resulting 3D problem. But ...
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1answer
36 views

Finite vs. infinite systems, band structure and wave functions

Why do we need a finite system to find the find the wave function and a infinite system to find the band structure?
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49 views

Is there a mathematical explanation for why there occur bound states if the effective potential falls below zero?

Usually in physics textbooks, if the effective potential of the radial schroedinger equation $$-\frac{d^2}{dr^2}u(r) + \frac{\ell(\ell+1)}{r^2}u(r) + V(r)u(r) = E u(r)$$ falls below zero in some ...
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730 views

Can the chance of finding a particle diminish over time?

Let's assume we have a wave function described by a wave equation and it is a function of space and time $\psi : \mathbb{R}^4 \rightarrow \mathbb{C}$. This function needs to be normalized, so if I ...
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59 views

Simplest fermionic normalized quantum many-particle wavefunction in position representation

What is the simplest fermionic normalized quantum many-particle wavefunction, expressed in the first-quantized position representation, that you can think of? The normal single-particle examples don't ...
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63 views

What happens to the Hamiltonian of the wave function after measurement?

As I understand it, the Hamiltonian is the kinetic plus the potential energy of the wave function. When a measurement is done what happens to the kinetic and potential energy? Does it dissipate? Is ...
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4answers
133 views

Physical meaning of linear combination of possible states in infinite well

The solution of infinite well, positioned from $x=0$ $x=l$, is $$ \Psi_n(x,t)= \sqrt{\frac{2}{l}}\sin\left(\frac{n\pi}{l}x\right)e^{iE_nt} $$ But the most general solution of this problem is : $$ ...
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1answer
94 views

Must the wavefunction be analytic?

In order to show the preservation of normalization of the wave function (in one dimension for now), one shows that the time differential is zero, which entails the following step: $$ ...
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2answers
49 views

Question on wave function of hydrogen

http://physicsworld.com/cws/article/news/2013/may/23/quantum-microscope-peers-into-the-hydrogen-atom http://io9.com/the-first-image-ever-of-a-hydrogen-atoms-orbital-struc-509684901 they are claimed to ...
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What is the physical significance of the two integration constants that appear in the ladder operator decomposition of the Quantum Hamiltonian?

If I have a simple one dimensional Hamiltonian of the form \begin{align} H = V - \partial_x^2 \end{align} and if I know one zero energy state solution $H\psi_0=0$ then I can use the Wronskian to ...
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5answers
492 views

Hilbert space vs. Projective Hilbert space

Hilbert space and rays: In a very general sense, we say that quantum states of a quantum mechanical system correspond to rays in the Hilbert space $\mathcal{H}$, such that for any $c∈ℂ$ the state ...
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2answers
123 views

Is it accurate to say “a wavefunction is a function of particle positions or momenta”?

Something has been bothering me for a while. I encounter this kind of statement everywhere: While a single particle is described by a wave function $\Psi({\vec r};t)$, a system of two particles, ...
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394 views

How is the Pauli Exclusion Principle a consequence of antisymmetric wavefunction?

How is the Pauli Exclusion Principle a consequence of antisymmetric wavefunction?
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Given a wave function $\psi(x)$, is there always a potential $V(x)$ such that $\psi(x)$ is an eigenstate?

Given any unit norm wave function $\psi(x)$ which is in the Hilbert space, can we always find a $V(x)$ such that the $\psi(x)e^{-i\omega t}$ is a solution of the corresponding Schrödinger equation? (I ...
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2answers
328 views

Who is doing the normalization of wave function in the time evolution of wave function?

In the Schrodinger equation, at any given time $t$ we should jointly add another sub equation, like $$||\psi_t(x)|| = 1$$ where $\psi_t(x) = \Psi(x,t)$, and then try to solve the two equations ...
2
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0answers
57 views

Fermion 1D Hubbard Model ground state in the U = 0 limit

I am trying to determine the ground state of the 1D fermionic Hubbard model at half-filling of $2L$ sites with $L$ electrons with spin-$\uparrow$ and $L$ electrons with spin-$\downarrow$ in the $U=0$ ...
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1answer
35 views

Finding a basis for minimal representation of a wavefunction (extracting symmetries)

I asked something like this on Math StackExchange, but now that I think about it, this probably belongs better over here. I want to find all linear operators (non necessarily hermitian) $\{\hat{A}\}$ ...
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1answer
75 views

Quantum Mechanical Wave Functions

Are wave functions, such as those used in the Schroedinger equation just 'guessed' and verified, or are there other theories which tell us the mathematical description of the wave function for ...
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5answers
229 views

General question about the potential barrier problem: Why does $\exp( kx)$ diverge when $x>0$ in the case when $E < V(x)$?

For the two images below, the first potential barrier has particles approaching it where $E > V_o$ & the second has a particle that has $E < V_o$, where $E$ is the energy of the particles ...
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1answer
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Boundary Conditions in a Step Potential

I'm trying to solve problem 2.35 in Griffith's Introduction to Quantum Mechanics (2nd edition), but it left me rather confused, so I hope you can help me to understand this a little bit better. The ...
2
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2answers
59 views

Why don't we have particles whose wavefunctions are symmetric wrt one exchange operator and anti-symmetric wrt other exchange operator?

Consider a system with $n$ identical particles. Let the wavefunction of the system be $\psi(r_1,\ldots, r_2)$. Let $P_{a,b}$ represent the exchange operator which exchanges particle $a$ with particle ...
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50 views

Electron wave function question?

In interpretations of Quantum Mechanics that are Psi Ontic, in which the wave function is REAL ( Objective collapse theories, MWI, ect), does the wave function still physically spread to infinity? I ...
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1answer
60 views

What is the implication that the Schrodinger equation be solved by both real and imaginary part of the wave function? [closed]

Suppose $\psi = \psi_{real} + i \psi_{imag}$ be the wave function, then both $\psi_{real}$ and $\psi_{imag}$ can be used to solve the Schrodinger's equation This can be demonstrated by plugging ...
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5answers
253 views

How do we know that electron wave function extends to infinity?

Why do physicists assume this? Is it a proven fact that wave function extends to infinity or just a theory? Would it make sense if they didn't extend to infinity?
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wavefunction and contextuality

According to the French philosopher Michel Bitbol, the "deep-lying connection between the contextual character of observables, and the wave-like form of probability distributions was demonstrated ...