A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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42 views

Showing two wavefunctions are proportional to one another [duplicate]

I am struggling to answer the following question: Let ψ₁(x) and ψ₂(x) be normalisable energy eigenfunctions for a particle of mass m in one dimension moving in a potential V(x). Suppose that ψ₁ and ...
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1answer
95 views

Schrodinger equation violates mathematics?

By the Hamiltonian formalism of quantum mechanics, given a quantum system in a state $\Psi$ in a Hilbert space $\mathcal H$, the state will instantaneously evolve in time according to ...
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2answers
81 views

How do we decide whether an electron orbital has a non-zero or zero probability of lying inside the nucleus of an hydrogen atom?

How do we decide whether an electron orbital has a non-zero or zero probability of lying inside the nucleus of an hydrogen atom? It is mostly from the radial function, as to what I think but how ...
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33 views

Is the wavefunction of particles inside a gas spread or localized?

For an individual free particle that starts localized, the wave function packet spreads over time, so the particle becomes less localized. Suppose now that we have a gas of those particles inside a ...
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160 views

Why does the wavefunction have to be continuous in the presence of a Dirac delta potential?

Considering the time-independent Schrödinger equation, I can see for a finite potential, why the wavefunction has to be continuous, I can also see why the first derivative of the wavefunction is ...
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2answers
97 views

Time dependent and time independent Schrödinger equations

I'm trying to understand the relation between the time dependent and time dependent Schrödinger equations. In particular, we know that the TDSE is $$H\Psi=i\hbar \frac{\partial \Psi}{\partial t}$$ ...
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1answer
122 views

Minimum uncertainity

I'm confused in finding the condition for minimum uncertainty, The author in the book I refer goes on saying that $|g\rangle=c|f\rangle$ is the condition for minimum uncertainity for some constant ...
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48 views

solutions of wave equation with cubic term

Does the following equation $$ \nabla^\mu \nabla_\mu \psi + a \psi^3 = b \psi $$ where $\psi$ is a real function, $a$ and $b$ are real constants, have other solutions that extend beyond a one ...
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1answer
78 views

Infinite potential well question with wave function $\psi (x) = (x -a/2)^2$

In an infinite potential well with width $a$, a particle in this potential well is at state with wave function is $\psi (x) = (x -a/2)^2$ (not normalized). If you measure the energy of ...
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1answer
65 views

Confused on how to interpret the energy eigenfunction of Hydrogen

So here is an image of the third lowest energy eigenfunction of an electron in a hydrogen atom: Image from http://imgur.com/Lu4MocL I understand well the eigenfunctions given by Schrodinger's ...
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1answer
30 views

Spinor expectation value and measurement

I have a question about the difference between expectation value and probability of measurement. consider the spinor $\zeta = [-3\ \ 4i\ ]^T$ . The expectation value of $S_x$ is zero because : ...
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2answers
71 views

Coefficients and wavefunction in quantum mechanics

In general quantum mechanics we represent the state of a system with a state vector $| \psi \rangle $ in some Hilbert space in some base. Assuming a complete discrete set of bases vectors $ |n \rangle ...
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3answers
87 views

Quick way to compute $\langle n^{'}l^{'}m^{'}|r^k|nlm \rangle$, $k \in I$; $|nlm\rangle$ is $H$ atom eigenfunction [closed]

I want to compute quickly (using maybe some scaling arguments) $\langle n^{'}l^{'}m^{'}|r^k|nlm\rangle$, where $k \in I$. $|nlm \rangle$ is the eigenfunction of the Hydrogen atom ($H$). Example: ...
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3answers
169 views

How can quantum wavefunctions be smooth/continuous when particles are created/destroyed/changed?

My (admittedly limited) understanding of the Schrodinger equation tells me that the vector differential operators are only meaningful over a differentiable phase space. For example, if the dimensions ...
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1answer
100 views

Is a non-degenerate wavefunction real or complex?

In this video it is stated that: It can easily be verified that the wavefunction of a non-degenerate quantum mechanical system will be real. However the presenter does not explain why this ...
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62 views

Why must the probability be the integrated square modulus of the wave function [duplicate]

Quantum mechanics uses the wave function to calculate probabilities by taking the square modulus of the wave function as requirement by Max Born. Why should this (squaring of the wave function) be so, ...
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2answers
117 views

Exact closed form solution to the quantum harmonic oscillator

I came across this question in Griffiths QM, which asked to show that this equation $$\Psi(x,t)=\left(\frac{m\omega}{\pi \hbar}\right)^{1/4} \exp\left[-\frac{m\omega}{2\hbar} ...
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1answer
48 views

Scattering off of a bi-local potential

I am trying to figure out the scattering wave function for the following potential: $$V(x,x')=-A \phi(x)\phi^*(x')$$ Such that the SE can be written as $$[\frac{\hbar^2\partial^2_x}{2m}-E]\psi = ...
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0answers
57 views

Valence bands question

I'm currently doing solid state physics and learning about semiconductors. During the course, I have seen a lot of energy/wavevector graphs, like this one (pic from Kittel): I did not have a ...
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0answers
56 views

Does wave function of an electron itself move?

As far as I know quantum mechanics, electrons in an atom in vacuum move accordingly a wave function (a complex scalar field), but the wave function itself does not move (except that the atom may ...
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1answer
49 views

Are Neutrons and anti-Neutrons attracted to each other over distance?

Lets create a scenario where you have a total vacuum and you're shooting into this vacuum two streams, one, a Neutron stream and the other an anti-Neutron stream and because you're curious what will ...
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3answers
73 views

Particle in a box: value for wave function $u(x)$ when potential $V(x)$ is infinity

The time-independent Schrödinger equation (TISE) is: $$ -\frac{\hbar^2}{2m}\frac{d^2 u(x)}{dx^2}+V(x)u(x)=Eu(x) \hspace{15pt}$$ where $E$ is a constant. Imagine now a infinity potential well as ...
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1answer
40 views

What is the main difference between a free particle on a line and a free particle on a circle?

The energy spectrum for a free particle in a circle with radius $r$ is $$E_n=\frac{n^2\hbar^2}{2mr^2}.$$ The energy spectrum for a free particle on an infinite line is similar. If so, what is the ...
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2answers
56 views

Angular momentum for a given Wavefunction [closed]

Problem: Give a particle in the state $\Psi = e^{\frac{-(x^{2}+y^{2}+z^{2})}{a^{2}}}(\frac{x}{a} + \frac{yz}{a^{2}})$, what are the allowed values for $l_{x}$ (and later for $l_{y}, l_{z}$). Attempt: ...
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1answer
99 views

Why are eigenspaces of a Hermitian operator mutually orthogonal? [closed]

In Quantum Mechanics, from the properties of the solution of Schrodinger's Equation inside the infinite well, is that they are: Mutually orthogonal for different eigenvalues. Orthonormal. Complete. ...
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1answer
58 views

The boundary condition for delta function

Beginning with the Schr\"odinger equation for $N$ particles in one dimension interacting via a $\delta$-function potential $$(-\sum_{1}^{N}\frac{\partial^2}{\partial ...
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Width of a Gaussian wave function [closed]

Consider the wave function with probably density given in position space as follows: $$P(x,t)=|\Psi(x,t)|^2=\frac{\pi^{-1/2}\Delta p_x/\hbar}{[1+(\Delta ...
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1answer
71 views

Particle in a double delta potential, scatter states

I was studying the scatter states of a particle in a double delta potential given in this link: Double delta function well – scattering states But I dont understand how equations (20) and (21) were ...
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1answer
50 views

Quantum States, Hilbert Space and Time

I'm having troubles with the assertion "(normalizable) wave-functions constitutes (projective) Hilbert space". The standard argument I find for this seems to go as following: say $\Psi(\vec{x},t)$ is ...
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2answers
233 views

Importance of Schrodinger equation [closed]

Louis de Broglie suggested that for microparticles like electrons, wave-like properties can be applied in order to explain some phenomena. Schrodinger wrote down an equation, a wave equation, ...
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60 views

Electrons are 3 dimensional quantized waves (wave functions)?

I thought that electron wave functions were only mathematical of were to find the electron. ...
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53 views

In what cases and with what method does one find a time dependent probability density for a quantum system in an infinite square well?

How can one find the time dependent probability density function of a quantum system given $\Psi(x,t=0)$? Say, $\psi(x) \sim x^4$ for $0 < x < L$. How can one find the time dependant probability ...
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81 views

Relationship between nodes in wavefunction and orthogonality

I read that if I want to construct a wavefunction orthogonal to given $n$ orthogonal wavefunctions, then the new wavefunction should have $n$ nodes. Is this valid under all conditions? Is there a ...
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3answers
90 views

Finite square wall with $E > V_0$

I'm working through a problem for homework and feel as if there is a typo or I am confused. The problem is with a one sided finite square wall such as this: So the energy is more than $V_0$. I'm ...
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3answers
93 views

What are the functions of these coefficients $c_1,c_2,c_3,c_4$ in $ \psi_{sp^3}= c_1\psi_{2s}+ c_2\psi_{2p_{x}} + c_3\psi_{2p_y}+ c_4\psi_{2p_{z}}$?

Hybridised orbitals are linear combinations of atomic orbitals of same or nearly-same energies. Atomic orbitals interfere constructively or destructively to give rise to a new orbital which is what we ...
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1answer
91 views

Is it okay to put singularities into the wave function to test behavior around unstable potentials? [closed]

$$ \psi(r)=\sqrt[4]{\frac{ a}{8\pi^3 }}\frac{ \exp (-a r)}{r^{1.25}} $$ The wave function above is an example of a function that is normalizable in 3D space and $r=\sqrt{x^2+y^2+z^2}$. $$ -\psi ...
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242 views

Normalized wave functions in position and momentum space

Using the following expression for the Dirac delta function: $$\delta(k-k')=\frac{1}{2\pi}\int_{-\infty}^{\infty}e^{i(k-k')x}\mathrm{d}x$$ show that if $\Psi(x,t)$ is normalized at time $t=0$, ...
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1answer
76 views

A wave function that is normalized initially remains normalized

Suppose that $\Psi(x,t)$ is normalized at time $t=0$. Show that this implies that $\Psi(x,t)$ is normalized at all other times. I know that this makes intuitive sense, and we'd certainly want our ...
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1answer
31 views

What is the equation of motion for multiple simultaneous pressure waves in a medium? (In the context of stimulated Brillouin scattering)

My overall motivation is to derive the behavior of Brillouin scattering in a birefringent fiber. Brillouin scattering is a nonlinear interaction between light and sound. In classic Brillouin ...
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1answer
76 views

Wave packet and group velocity?

While finding the wave function of a free particle say $\psi(x)$, my textbook says that this is nonphysical because the wave velocity is not same as particle velocity of the free-particle. I don't ...
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2answers
47 views

Quantum harmonic oscillator - Where am I going wrong?

Find the relationship between $a_+\psi_n$ and $\psi_{n+1}$ My attempt: I was able to prove that $\int{(a_+\psi)^*(a_+\psi)dx} = \int{\psi^*({a_-a_+\psi})dx}\qquad\qquad (1)$ And, ...
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3answers
197 views

What is the connection between gravitons and geometry?

I know there are two ways to do quantum gravity. One can pick a background space-time (usually Minkowski flat space-time) and then at any time slice one can define the state of the universe as the ...
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41 views

Where do we get an initial wavefunction for a particle or a system?

In many QM text books, a numerical problem starts with the statement that "a particle has an initial wave function of ..." My question is how do we find the initial wave function in the first place?
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How is charge separation in a polarized vacuum possible?

How is Charge Separation in a Polarized Vacuum possible? The Uehling potential provides the first correction term to the classical coulomb potential from QFT vacuum polarization: $$ V(r) \approx ...
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129 views

Mathematical confusion in quantum mechanics

During a class about Ehrenfest theorem, my teacher use an equation to proceed its derivation (to prove $\frac{d<r>}{dt}=\frac{<p>}{m}$ ) and that is: ...
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80 views

Uncertainity principle and double slit experiment?

My Understanding of uncertainty principle goes that if some particles are in same state, then their measurement of certain property (say $x$ and $p$) will be different for different particles. ...
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1answer
90 views

Normalizing a wave function [closed]

A particle with mass $m$ is moving in one dimension. The wave function of the particle is $$\Psi(x,t)=Axe^{-(\sqrt{km}/2\hbar)x^2}e^{-i\sqrt{k/m}(3/2)t}$$ for $-\infty<x<\infty$, ...
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1answer
111 views

QM and relative phases

I recently started formally learning about QM. I have studied thus far that any global phase difference is irrelevant when taking energy expectation values. However, that is not evidently the case for ...
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2answers
130 views

Where are the worlds in many-worlds interpretation?

What does it mean in MWI for other universes to exist? Are they in some sector of spacetime beyond our cosmic horizon or is it more complicated? I'm not asking this on Philosophy SE because people ...
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1answer
120 views

Normalization of potential barrier solution

I don't understand a point in the solution attached to this barrier potential problem. Below equation 4.209, they say Assume first that the wave function on the right side of the barrier in the ...