A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Why does $\ell=0$ correspond to spherically symmetric solutions for the spherical harmonics?

In quantum mechanics why do states with $\ell=0$ in the Hydrogen atom correspond to spherically symmetric spherical harmonics?
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1answer
90 views

Is there a way to prove that a bound state wavefunction can always be chosen real for an arbitrary potential in Quantum Mechanics?

As we can prove many things that always (at least in introductory quantum mechanical problems) apply using an arbitrary potential (like that $E>V_{\rm min}$ or else the solutions are non-...
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1answer
363 views

Help me to visualize this wave equation in time, to which direction it moves?

The wave is $\bar{E} = E_{0} sin(\frac{2\pi z}{\lambda} + wt) \bar{i} + E_{0} cos(\frac{2 \pi z}{\lambda}+wt) \bar{j}$ Let's simplify with $z = 1$. Now the xy-axis is defined by parametrization $(...
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2answers
329 views

Why is $ \psi = A \cos(kx) $ not an acceptable wave function for a particle in a box?

Why is $ \psi = A \cos(kx) $ not an acceptable wave function for a particle in a box with rigid walls at $x=0$ and $x=L$ where $$ k = \frac {(2mE)^{1/2}} {\hbar} \, ?$$ I had plugged the wave ...
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2answers
3k views

Schrödinger's Equation and its complex conjugate

I would like to know why there is a minus sign on the right-hand side of the Schrödinger's complex conjugate equation, whereas in the Schrödinger's equation there isn't. I know it is a simple question,...
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6answers
3k views

Does Heisenberg's uncertainty under time evolution always grow?

Recently there have been some interesting questions on standard QM and especially on uncertainty principle and I enjoyed reviewing these basic concepts. And I came to realize I have an interesting ...
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6answers
2k views

Is there a direct physical interpretation for the complex wavefunction?

The Schrodinger equation in non-relativistic quantum mechanics yields the time-evolution of the so-called wavefunction corresponding to the system concerned under the action of the associated ...
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1answer
4k views

Plane wave expansion in cylindrical coordinates

I am trying to solve scattering problem in 2D and got to expand the wave function in cylindrical system which comes out to be Hankel function. Can you tell me how to expand the plane wave $\exp(i {\...
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4answers
1k views

What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess I'...
7
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3answers
203 views

What do the wave functions associated to the Fock states of each mode of a bound state system mean?

$\renewcommand{\ket}[1]{\left \lvert #1 \right \rangle}$ Consider a string of length $L$ under tension and clamped on each end. This system is described by the wave equation and has a set of modes. ...
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4answers
612 views

Why complex functions for explaining wave particle duality?

I have this very bad habit of going to the scratch, discarding all the developments of a theory and worldly knowledge, and ask some fundamental (mostly stupid and naive, as some may say) questions as ...
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4answers
614 views

Reconstruction of “wavefunction” phases from $|\psi(x)|$ and $|\tilde \psi(p)|$

Consider a "wavefunction" $\psi(x)$, which has a Fourier transform $\tilde \psi(p)$ Suppose that we know, for each $x$, $|\psi(x)|^2$, and that we know, for each $p$, $|\tilde \psi(p)|^2$. Have we ...
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2answers
2k views

Particle in a 1-D box and the correspondence principle

Consider the particle in a 1-d box, we know very well the solutions of it. I'd like to see how the correspondence principle will work out in this case, if we consider position probability density ...
5
votes
2answers
282 views

Wavefunctions in different Hilbert spaces

The state of a quantum system is represented by a wavefunction usually in some specific Hilbert space, .e.g of position, spin, momentum etc. But before deciding in which of these bases to decompose ...
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1answer
2k views

Wave function and Dirac bra-ket notation

Would anyone be able to explain the difference, technically, between wave function notation for quantum systems e.g. $\psi=\psi(x)$ and Dirac bra-ket vector notation? How do you get from one to the ...
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3answers
593 views

Could quantum mechanics work without the Born rule?

Slightly inspired by this question about the historical origins of the Born rule, I wondered whether quantum mechanics could still work without the Born rule. I realize it's one of the most ...
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2answers
2k views

Coupled quantum harmonic oscillator

Given the following Hamiltonian for two identical linear oscillators with spring constant $k$ and interaction potential $\alpha x_1x_2$; I was asked to find the expectation value $\langle x_1x_2\...
3
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5answers
667 views

How does a Wavefunction collapse?

I have been wondering and researching... How does a wavefunction collapse into one state?More specifically, what conditions cause a wavefunction for a quantum particle to collapse? Does this have to ...
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4answers
10k views

Differences between wavefunction, probability and probability density?

I am trying to understand the differences between wavefunction, probability and probability density. There are different definitions on the internet. For example: http://inside.mines.edu/~fsarazin/...
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5answers
496 views

Why do we need a wave function?

Assuming our only aim is to solve double slit experiment (or other problems that can be mapped into that). Knowing that electron does some strange thing not expected of a particle, we need a function ...
7
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1answer
439 views

What is the wavefunction of the Young Double Slit experiment?

I have never seen the wavefunction for this experiment and would like to know how to derive it using the Schrodinger equation. I specifically want to see how the electron wave function leaves the ...
7
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5answers
881 views

Quantum Wave Mechanics

I am studying QM-I these days. Now, I just think of the wave function as just a mathematical function that defines the state of the particle at an instant and from it you can extract various ...
7
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1answer
443 views

Virial theorem and variational method: a question

I have an hydrogenic atom, knowing that its ground-state wavefunction has the standard form $$ \psi = A e^{-\beta r} $$ with $A = \frac{\beta^3}{\pi}$, I have to find the best value for $\beta$ (...
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2answers
515 views

Ground state of Spherical symmetric potential always have $\ell=0$?

I was given a problem where I have a spherically symmetric potential (the exact form is not relevant to this question, I think - but anyway is it 0 for $r\in[a,b]$ and $\infty$ everywhere else) and I ...
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2answers
2k views

Vector representation of wavefunction in quantum mechanics?

I am new to quantum mechanics, and I just studied some parts of "wave mechanics" version of quantum mechanics. But I heard that wavefunction can be represented as vector in Hilbert space. In my eye, ...
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Confused over complex representation of the wave

My quantum mechanics textbook says that the following is a representation of a wave traveling in the +$x$ direction:$$\Psi(x,t)=Ae^{i\left(kx-\omega t\right)}\tag1$$ I'm having trouble visualizing ...
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1answer
393 views

Majorana wavefunction

I'm trying to compute the wavefunction for a Majorana state in an nanowire/superconductor hybrid system, like arXiv: Majorana Fermions and a Topological Phase Transition in Semiconductor-...
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4answers
199 views

Isn't the 'slit' in a double-slit experiment also a wave?

I'm new to QM so excuse my naivety. I was watching an online MIT QM course that described the double-slit experiment (with electrons) when it occurred to me that I have a question. In the video, the ...
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3answers
2k views

Born Interpretation of Wave Function

I have just started Griffiths Intro to QM. I was studying Born's interpretation of Wave function and it says that the square of the modulus of the wave function is a measure of the probability of ...
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1answer
3k views

3D Quantum harmonic oscillator

For an isotropic 3D QHO in a potential $$V(x,y,z)={1\over 2}m\omega^2(x^2+y^2+z^2).$$ I can see by independence of the potential in the $x,y,z$ coordinates that the solution to the Schrodinger ...
3
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1answer
88 views

How do we find the number of bounded states in this potential?

for the potential $$V(x)=-\frac{1}{1+\frac{x^2}{m^2}}$$ we can approximate the wave function and bounded state accurately for $x << m$ as simple harmonic oscillator, so what are we gonna do if ...
2
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4answers
356 views

Does the wave nature of a particle refer to the wave function?

In quantum mechanics when we talk about the wave nature of particles are we referring in fact to the wave function? Does the wave function describes the probability of finding a particle (ex: photons)...
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1answer
878 views

Solution of 1-D Schrodinger equation for the potential $V(x) = -\frac{1}{|x|}$

May be this question might have already been asked but i couldn't find it, so let me know if its already there. Consider a potential, $V(x) = -\frac{1}{|x|}$ and if we apply this to a one dimensional ...
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2answers
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Matter waves and de Broglie wave length

The wavelength of a particle of momentum p is calculated using De Broglie relation. The de Broglie relation was postulated for what is called a matter waves. Now according to the statistical ...
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1answer
6k views

A Simple Explanation for the Schrödinger Equation and Model of Atom? [closed]

I tried reading the Wikipedia article to no avail - I simply cannot understand the Schrödinger Equation (what does each of the variables mean, especially the wave function), and the Schrödinger Model ...
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1answer
359 views

Boundary Conditions in a Step Potential

I'm trying to solve problem 2.35 in Griffith's Introduction to Quantum Mechanics (2nd edition), but it left me rather confused, so I hope you can help me to understand this a little bit better. The ...
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1answer
3k views

How to prove dp/dt = -dV/dx? Quantum mechanics [closed]

I got this problem from a book called Introduction to quantum mechanics, griffin 2nd edition. and I did not get why the solution says first term integrates to zero, integration by parts twice?! ...
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4answers
228 views

Connection between Hamiltonian version of the least action principle and probability amplitude in the Schrödinger equation

If I'm not mistaken, Schrödinger was influenced to look at wave equations because of de Broglie's assertion about particles having a wavelength. He started with the Hamiltonian equation which is ...
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2answers
744 views

Was uncertainty principle inferred by Fourier analysis?

I would like to know: did Heisenberg chance upon his Uncertainty Principle by performing Fourier analysis of wavepackets, after assuming that electrons can be treated as wavepackets?
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867 views

Can we impose a boundary condition on the derivative of the wavefunction through the physical assumptions?

Consider the Schrödinger equation for a particle in one dimension, where we have at least one boundary in the system (say the boundary is at $x=0$ and we are solving for $x>0$). Sometimes we want ...
5
votes
3answers
134 views

Can a physical wavefunction be non-smooth (its first derivative is discontinuous)?

Here's an argument that might support the statement that such a non-smooth wavefunction is not physical: You cannot add a finite number of smooth functions to get a non-smooth function. By fourier ...
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3answers
370 views

No well-defined frequency for a wave packet?

There are similar questions to mine on this site, but not quite what I am asking (I think). The de Broglie relations for energy and momentum $$ \lambda = \frac{h}{p}, \\ \nu = E/h .$$ equate a ...
5
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3answers
767 views

How can particles travel in a straight line?

A particle can be set off in a certain direction by giving them momentum. Momentum is a vector, so the particle heads off in a specific direction. But the wave function of the particle allows it to ...
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2answers
266 views

What is the physical reason behind linearity of Schrodinger's equation?

What is the physical reason for Schrodinger equation to be linear? Though in physics many interactions or dynamics are found non linear.
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2answers
144 views

Time evolution of a wavepacket

I do not understand why if $H\psi = E\psi$, then the time-evolution of the wavefunction is given by $e^{-iEt/h}\psi(x)$.
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1answer
2k views

Hydrogen wave function in momentum space

We can seperate the wave function of an hydrogen atom in a radial and an angle part: $$ \phi_{n,l,m} (\mathbf{r}) = R_{n,l,m}(r) Y_{l,m}(\vartheta,\varphi) \, , $$ where $Y_{l,m}$ are the spherical ...
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How do I figure out the probability of finding a particle between two barriers?

Given a delta function $\alpha\delta(x+a)$ and an infinite energy potential barrier at $[0,\infty)$, calculate the scattered state, calculate the probability of reflection as a function of $\alpha$, ...
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1answer
937 views

Simple Quantum Mechanics question about the Free particle, (part1)

I am reading Introduction to Quantum Mechanics by David Griffiths and I am in Ch2 page 59. He starts out writing the time dependent Schrödinger equation and the solution for $\psi(x,t)$ for the free ...
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2answers
413 views

Finite Square Well Inside an Infinite Square Well

Ok here's a potential I invented and am trying to solve: $$ V(x) = \begin{cases} -V_0&0<x<b \\ 0&b<x<a \\ \infty&x>a \\ \end{cases}$$ and $V(-x) = V(x)$ (Even ...
3
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2answers
255 views

What is the analogy of $|x\rangle$ in quantum field theory?

Let me start from path integral formulation in quantum mechanics and quantum field theory. In QM, we have $$ U(x_b,x_a;T) = \langle x_b | U(T) |x_a \rangle= \int \mathcal{D}q e^{iS} \tag{1} $$ $|...