A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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401 views

Finite Square Well Inside an Infinite Square Well

Ok here's a potential I invented and am trying to solve: $$ V(x) = \begin{cases} -V_0&0<x<b \\ 0&b<x<a \\ \infty&x>a \\ \end{cases}$$ and $V(-x) = V(x)$ (Even ...
2
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2answers
199 views

Logic of the 'imaginary wave function collapse' argument in Double Slit experiment

My question is in regards to the stance that the 'wave function collapse' is not an actual physical occurrence. That is, you are not, by observation, changing the particles position from a wave to a ...
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1answer
524 views

Sign of the wave function in orbital representation?

I have some fog in my head and a rather simple question for you: When the sign of the wave function is representated on orbitals, what is this sign? I mean is it the sign of the real part of the ...
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1answer
260 views

Finite potential well, parity of solutions

I'm working through some problems for a QM exam and I've realised I don't really understand the concept of parity of solutions. I'm looking at a simple finite potential well problem: $$V(x)=0, \quad ...
3
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1answer
291 views

Probability of measuring momentum [closed]

Suppose we have this wavefunction: $$ \psi = A \left( cos(kx) + cos (2kx) \right) $$ I have to find the possible results of measurement of momentum and their probabilities. Attempt For a momentum ...
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2answers
165 views

Representations in quantum mechanics [closed]

This might be a very simple question. I just want someone to point me the right direction to understand things like this: $$ \langle x|x'\rangle=\delta(x-x') \\ \psi(x)=\langle x|\psi\rangle \\ ...
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5answers
788 views

Is there any operator behind probability, in quantum mechanics?

In Quantum mechanics, the probability of finding a particle at position $x$ is given by $|\psi(x)|^2$, where $\psi$ is the wave function. Wonder what is the operator which gives this probability? Is ...
2
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2answers
284 views

Quick question on sketching wavefunction in well

Usually for an infinite well, the sketch for n=3 level is this: Now I think if one side of the potential barrier is higher, the particle will be more likely to spend time on the left side than ...
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0answers
332 views

Ground State Functional and Vacuum-Vacuum Transition Amplitude

In Path Integral formalism, the vacuum-vacuum transition amplitude is defined to be (the functional integration is over all field configurations in the whole spacetime; $\Phi_{\vec{x}}(\tau)$ is the ...
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2answers
232 views

Stationary state of time-independent Schroedinger equation is always real valued function?

I am reflecting on the solution of the time-independent Schroedinger equation. My reasoning is that the stationary state of the time-independent Schroedinger equation must be a real valued function ...
1
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2answers
236 views

details for the double slit experiment

In the double slit experiment with electrons, are all electrons going through the slits? If the electron gun is directed between two slits, than it should hit the central part between the slits, isn't ...
3
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1answer
165 views

How does a unique electron probability distribution correspond to one wavefunction?

I'm reading the Wikipedia article on DFT, and it says that there is a one-to-one correspondence between the ground state particle density $$n_0(\vec{r}) = N \int \text{d}^3 r_2 \int \text{d}^3 r_3 ...
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1answer
464 views

How to determine the transmission coefficient of a gaussian wave packet scattering on an finite square well?

I am doing a scattering simulation of a Gaussian wave packet on a finite square well. I have solved numerically the Schroedinger equation and I know the values of the wave function after the ...
3
votes
4answers
843 views

Double slit experiment and single particles. Is the wave function just a mathematical model?

I really do want to apologize in advance, I know this question has been 'answered' before. I have this 'problem' of feeling negatively toward much of today's 'mystical' interpretations of physics, ...
2
votes
1answer
122 views

On use of Hamiltonians for Helium

The Hamiltonian of helium can be expressed as the sum of two hydrogen Hamiltonians and that of the Coulomb interaction of two electrons. $$\hat H = \hat H_1 + \hat H_2 + \hat H_{1,2}.$$ The wave ...
2
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2answers
4k views

Particle in a 1D Box with Symmetric potential: How find solutions?

I am working on a problem in which I shall find the normalised solution to the 1D particle in a box. Solving for the particle in an asymmetric potential is quite straight forward, but I run into ...
0
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1answer
129 views

Is it possible to find the hydrogen atom's radial wavefunctions?

Is there a way to actually find the equation of $R(r)$ without looking at a table with these equations already given? I'm given $n$, $\ell$, and $m$.
2
votes
1answer
108 views

Does the wave function of a particle completely describe the state of the particle?

In classical mechanics, if you know the position and momentum of a particle at time $t$ and the Hamiltonian, you can predict the particle's position and momentum at any time. In quantum mechanics, if ...
2
votes
1answer
218 views

Kronig-Penney model

I am studying the Kronig-Penney model as treated in the book by Kittel: Introduction to Solid State Physics. In this model one considers a period potential which is zero in the region $[0,a]$ ...
2
votes
2answers
507 views

Bloch's theorem

I am studying Bloch's theorem, which can be stated as follows: The eigenfunctions of the wave equation for a period potential are the product of a plane wave $e^{ik \cdot r}$ times a modulation ...
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1answer
373 views

Understanding wave functions

I'm currently writing an essay on the measurement problem, and I'm not quite certain that I've fully understood the purpose of the wave function, in that does the following sentence make sense with ...
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3answers
568 views

Double slit experiment observation

In the double-slit experiment, if you shoot particles through the slits one by one and observe which slit they travel through, is there still an interference pattern on the screen behind the slits? If ...
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1answer
144 views

Obtain the eigenfunction of Jz for the wave function of an electron in a hydrogen atom? [closed]

The wave function of an electron in a hydrogen atom is given by Is this wave function an eigenfunction of Jz , the z-component of the electron’s total angular momentum? If yes, find the ...
5
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4answers
2k views

Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ ...
2
votes
1answer
134 views

Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
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2answers
623 views

When can we assume that the wavefunction is separable

While working out the stationary states of a single particle in a 3d infinite potential box ($V=0$ inside a cuboid of known dimensions, $V=\infty$ everywhere else), I realized I had to assume the ...
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1answer
174 views

Why don't we need to normalize wavefunction to find probability distribution?

Consider an unormalized wavefunction of a rotor at $t = 0$, a combination of $n=0$ and $n=2$ states: $$\psi(\phi) = 3 - 2 \cos (2\phi).$$ Find the probability distribution in angle. The ...
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1answer
5k views

Calculating the expectation value of a Hamiltonian

I want to calculate the expectation value of a Hamiltonian. I have a wave function that is $$\psi = \frac{1}{\sqrt{5}}(1\phi_1 + 2\phi_2).$$ I want to know if I set this up properly. The ...
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3answers
241 views

Can a wave possess spin?

Since a matter wave is associated with a particle in quantum mechanics, does the wave spins? I mean, can we visualize the spinning of wave or is it possible that the wave spins?
2
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2answers
104 views

How do I describe two entangled electrons in the same state except for a different spin

I am trying to formulate the wave function that describes two entangled electons having the same position but opposite spin. According to the Pauli exclusion principle this should be possible. And ...
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1answer
137 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
0
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1answer
1k views

Normalizing the sum of wavefunctions and calculating probabilty - understanding concepts

A state of a particle bounded by infinite potential walls at x=0 and x=L is described by a wave function $\psi = a\phi_1 + b\phi_2 $ where $\phi_i$ are the stationary states. So let's say we want to ...
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3answers
711 views

Why is $|\Psi|^2$ the probability density?

I am starting with Quantum Mechanics, learning online. I can't seem to find the reason for $|\Psi|^2$ being the probability density of finding an electron. They've just taken it for granted ...
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1answer
232 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
2
votes
2answers
4k views

Calculating the most probable radius for an electron of a hydrogen atom in the ground state

This link describes a method for determining the most probable radius of an electron for a Hydrogen atom in the ground state. It states that : The radial probability density for the hydrogen ...
2
votes
2answers
123 views

How will a particle with energy less than $V_{\rm min}$ behave?

Consider e.g. the finite square well: $V = -V_o$ between $x=-a$ and $x=a$, $V=0$ elsewhere Now for scattering states, $E$ must be $> 0$. For normalizable bound states, $E$ must be $< 0$ and ...
2
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3answers
2k views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
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2answers
53 views

Potential Step - Choosing Wavefunctions

http://uqu.edu.sa/files2/tiny_mce/plugins/filemanager/files/4190016/Quantum_Mechanics_1/ch4-virtual-book.pdf On page 2 of the above pdf they describe how they select their wavefunctions. Finding the ...
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1answer
512 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
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2answers
127 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
0
votes
1answer
206 views

Calculating the Reflection Coefficient of a Potential Step Explicitly

So I'm using the following definition for the Reflection coefficient, $R$ : $$R=\frac{\left\rvert\ \vec{j}_{reflected}\right\rvert}{\left\rvert\ \vec{j}_{incident}\right\rvert}$$ where ...
0
votes
1answer
399 views

Solving the 1D Schrodinger Equation for a Free Particle - Two Different Methods?

So starting from the time dependent schrodinger equation I perform separation of variables and obtain a time and spatial part. The spatial part is in effect the time independent schrodinger equation. ...
8
votes
2answers
782 views

Has the collapse of wave function due to observation been recorded?

I've seen pictures like this one, which depict the outcome of the Double-slit experiment with wave-like or particle features, depending how measurement has taken place. The graphic showing ...
0
votes
2answers
95 views

Calculating the Probability Current of a Travelling Wave

Calculate the probability current density vector $\vec{j}$ for the wave function : $$\psi = Ae^{-i(wt-kx)}.$$ From my very poor and beginner's understanding of probability density current it is : ...
2
votes
1answer
124 views

Electron distribution around atom when moving

I do not have much experience on this but if an atom has some electrons around nucleus and the atom itself it is moving at some speed does that affect the distribution of electrons around? I am ...
2
votes
3answers
296 views

Expectation Values and Derivation of Heisenberg Equation?

Consider a system of particles with wave function $\psi$(x) (x can be understood to stand for all degrees of freedom of the system; so, if we have a system of two particles then x should represent ...
4
votes
1answer
900 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
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votes
1answer
139 views

Apply the Heisenberg Equation to the Hamiltonian [closed]

$\frac{d}{dt}$$\hat{H}$ = $\frac{i}{\hbar}$$[\hat{H},\hat{H}]$ +$\frac{\partial{\hat{H}}}{\partial{t}}$ That's as far as I've got. I do not know much about the Heisenberg equation or even what it ...
0
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1answer
80 views

Wave function - Working towards Orthonormal solution

As you can see below, the two pages attached describe how to obtain the final solution of orthonormality. I do not completely follow the discussion but I will talk you through what I DO understand ...
5
votes
1answer
117 views

Effect of pressure increase on electron orbital wave functions

One of my nuclear physics exercises was to find out if increasing the pressure of a sample of $^{7}\textrm{Be}$ would increase the chance of electron capture to $^{7}\textrm{Li}$ occur. My reasoning ...