A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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2
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36 views

Estimate of the second shallowest bound state?

Suppose we have a 1D potential $V(x)$ of finite range, i.e., $$ V(x) ~=~0 $$ for $|x| > b $. The potential is assume to support at least two bound states, but might have more, say $n\geq 2$. ...
29
votes
11answers
8k views

About the complex nature of the wave function?

1. Why is the wave function complex? I've collected some layman explanations but they are incomplete and unsatisfactory. However in the book by Merzbacher in the initial few pages he provides an ...
1
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2answers
190 views

How to know if a wave function is physically acceptable solution of a Schrödinger equation?

How does one decide whether a wave function is a physically acceptable solution of the Schrödinger equation? For example: $\tan x$ , $\sin x$, $1/x$, and so on.
2
votes
2answers
322 views

Bloch wave function orthonormality?

there is this text book that is giving me a hard time for a while now: It shows that Bloch wave functions can be written as $$\Psi_{n\vec{k}}\left(\vec{r}\right) = \frac{1}{\sqrt{V}}e^{i\vec k \vec ...
0
votes
1answer
37 views

Introductory Quantum, trouble with this boundary condition and potential

Working on problem 2.40 from Griffiths but can't seem to understand the first boundary condition. We are given the potential $V(x) = \left\{\begin{matrix} \infty & x < 0\\ ...
5
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1answer
113 views

Which position and momentum distributions arise from some wave function?

Consider a particle in one dimension with wave function $\psi(x)$. The probability density function describing how likely it is to find it in a given position is given by ...
3
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1answer
114 views

1D Finite potential well: solutions with $\sinh$ and $\cosh$?

So I am studying the (one dimensional) quantum mechanical finite potential well defined by: $$ V(x) = \cases{0, &|x|>a\cr -V_0, &|x|<a} $$ where $V_0>0$ is a real number. I know ...
1
vote
1answer
111 views

Deriving a Useful Solution of the Schrödinger Equation [on hold]

How does one derive the fact that $$\psi(t,x) = (\tfrac{2 \pi \hbar t}{m})^{-d/2}\int_{\mathbb{R}^d} e^{im\tfrac{(x-y)^2}{2\hbar t}}\psi_0(y)dy$$ is a solution of the time-dependent Schrödinger ...
4
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0answers
1k views

Solution for the Finite 2D Potential Well - Rotational Symmetry [closed]

I was searching for the eigensolutions of the two-dimensional Schrödinger equation $$\mathrm{i}\hbar \partial_t \mid \psi \rangle = \frac{\mathbf{p}^2}{2m_e}\mid \psi \rangle + V \mid \psi ...
2
votes
1answer
99 views

Electron distribution around atom when moving

I do not have much experience on this but if an atom has some electrons around nucleus and the atom itself it is moving at some speed does that affect the distribution of electrons around? I am ...
1
vote
1answer
39 views

Wave packets and half-width at half-maximum

Suppose we have a Gaussian wave function and amplitude distribution function $$\psi(x) = (\frac{2}{\pi a^{2}})^{1/4}e^{-x^{2}/a^{2}}e^{ik_{0}x}, \qquad \phi(k) = (\frac{a^{2}}{2\pi})^{1/4}e^{-a^{2} ...
4
votes
4answers
3k views

Confused over complex representation of the wave

My quantum mechanics textbook says that the following is a representation of a wave traveling in the +$x$ direction:$$\Psi(x,t)=Ae^{i\left(kx-\omega t\right)}\tag1$$ I'm having trouble visualizing ...
1
vote
1answer
65 views

Bohr-Sommerfeld quantization for different potentials

Let's have Bohr-Sommerfeld quantization for one-dimensional case: $$ \int \limits_{a}^{b} p(x)dx ~=~ \pi \hbar (n + \nu ). $$ Here $p(x) = \sqrt{2m(E - U)}$, $a, b$ are turning points, and the area ...
1
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1answer
191 views

Energy difference between symmetric and antisymmetric wavefunctions

Is there any energy difference between a particle in a symmetric wavefunction and an identical particle in an identical potential but in a state with an anti-symmetric wavefunction? Or is it ...
1
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1answer
2k views

Plane wave expansion in cylindrical coordinates

I am trying to solve scattering problem in 2D and got to expand the wave function in cylindrical system which comes out to be Hankel function. Can you tell me how to expand the plane wave $\exp(i ...
1
vote
1answer
153 views

photon polarization, uncertainty in Energy

A beam of red light is sent along the $z$ axis through a polaroid filter that passes only $x$ polarized light. The beam is initially polarized at $30$°, and the total energy is $10$ Joules. Estimate ...
3
votes
3answers
105 views

A misunderstanding regarding infinite square well

Here is a picture of the energy states of infinite potential well. We can see That the first level have a half wavelength which fittes with a full wave of the second level. $$\frac{ \lambda _{1} ...
0
votes
3answers
68 views

Question about derivation of the Heisenberg Uncertainty Principle?

I am looking at the derivation presented here. The first thing I am unsure about is where the form of $\psi_0=Ae^{\frac{-m\omega x^2}{2\hbar}}$ came from. Also, is this form for all $\psi$, or just ...
6
votes
1answer
532 views

Bohr-Sommerfeld quantization from the WKB approximation

How can one prove the Bohr-Sommerfeld quantization formula $$ \oint p~dq ~=~2\pi n \hbar $$ from the WKB ansatz solution $$\Psi(x)~=~e^{iS(x)/ \hbar}$$ for the Schroedinger equation? With $S$ the ...
2
votes
2answers
42 views

Does an excited state wave function depend on state preparation?

Consider a quantum system with a ground state and many excited states (e.g. an atom). If the system is in an excited state, to what extent does its wave function depend on the method of state ...
5
votes
2answers
103 views

Ground state of Spherical symmetric potential always have $\ell=0$?

I was given a problem where I have a spherically symmetric potential (the exact form is not relevant to this question, I think - but anyway is it 0 for $r\in[a,b]$ and $\infty$ everywhere else) and I ...
1
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2answers
108 views

Why is time evolution of wavefunctions non-trivial?

(Note: This post focuses on a single simple example, however I'm asking about the error in general in my logic). Consider the infinite potential well "particle in a box" system described by ...
0
votes
4answers
79 views

Complex Conjugate of Wave Function

I've been reading through Griffiths QM book, and the only thing bugging me is they never fully described what $\Psi^* $ should be for any given function. I know it's the complex conjugate at the same ...
0
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4answers
49 views

Question about interpreting probabilities in QM [duplicate]

For the example of an infinite square well, $\psi(x)=0$ for $x$ outside the well/interval, and we are to interpret this as the particle cannot be found outside the well because ...
7
votes
3answers
421 views

Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
-2
votes
0answers
35 views

Derivation of Schrodingers equation [duplicate]

I need some help as i don't have any textbook available at the moment and only tech I have got is a old cell phone so could anyone show me the derivation of the Schrodingers equation?
0
votes
2answers
71 views

Indistinguishable particles and probability density

I am given the following (probably simple) exercise, but I think I misunderstand something: Let $\psi_{a,b}(r_1,r_2)$ be a two-particle state, calculate the probability density for distinguishable ...
1
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2answers
307 views

Coupled Quantum Harmonic Oscillator

Given the following Hamiltonian for two identical linear oscillators with spring constant $k$ and interaction potential $\alpha x_1x_2$; I was asked to find the expectation value $\langle ...
0
votes
1answer
233 views

Integers, Energy levels, and wavenumbers for a particle in a 2D box

(This question is not about coding) I have built a little code in Python that allows the user to plot the energy vs the wave number of particle in a 2D box, depending on what values for the integers ...
3
votes
3answers
514 views

Wavefunction, probability and impossible events

A friend of mine asked me a question, which I considered trivial at first, but after a while gave rise to some doubts. For instance, we have a potential well in 1 dimension defined by $$ V(x)= ...
1
vote
1answer
465 views

Density of classical states in quantum theory

Let's first treat electrons as classical objects. I can evaluate the classical energy of each state in a configurational space (3N real numbers and, say, spins) using just Coulomb's law. Then I ...
0
votes
1answer
105 views

Quantum Mechanics in Electric Field

I am working on a problem which looks like this. Consider a charged particle with charge $q$ trapped in a box of length $L$ with finite constant potential $ V_0 $ on both ends. A constant (static) ...
3
votes
4answers
610 views

Is the wave function of a particle re-created after a measurement stops?

Yeah, I haven't quite understood, or been told, what happens to, for example an electron and it's wavefunction, when you stop to measure it? I mean, an electron has a wave function describing it's ...
1
vote
0answers
25 views

Why isn't there a different phase after fourier transformation in two lattices

I am trying to understand some solutions for graphenes energy dispersion. While most of it is clear, I don't get one step, when changing into k-space. Consindering two sublattices A and B with ...
6
votes
4answers
257 views

Why the statement “there exist at least one bound state for negative potential” doesn't hold for 3D case?

Previously I thought this is a universal theorem, for one can prove it in the one dimensional case using variational principal. However, today I'm doing a homework considering a potential like ...
2
votes
2answers
121 views

Linear vs. quadratic dispersion relation

In wave mechanics the dispersion relation between frequency $\omega$ and wave number $k$ is linear: $$\omega_n=c k_n$$ But in quantum mechanics, based on Schrödinger's equation, one can show that we ...
0
votes
1answer
53 views

Do quantum physics apply universally at all scales? [duplicate]

Do quantum physics apply universally at all scales? Where do quantum physics apply? Does the nucleus of an atom abide by the laws of quantum physics? Like do we know the definitive/velocity ...
1
vote
2answers
83 views

How would you go about evaluating $\langle \psi \mid 100 \mid \psi \rangle$? [closed]

How would you go about evaluating $\langle \psi \mid 100 \mid \psi \rangle$? I just can't seem to figure this out, and I know it isn't hard.
1
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0answers
33 views

In Quantum Physics would a camera count an observer that causes wave collapse? [duplicate]

Would the observation from a camera have the same effect on wave function as the observation from a living being?
-2
votes
1answer
71 views

Quantum mechanics: Finite square well problem

What will happen if the potential is less than 0, for instance $V(x)=-10eV$. Is this means there will be no bound states? Since solution to the time independent Schrodinger equation (those discrete ...
2
votes
2answers
86 views

Wavefunction of isomers

In quantum chemistry, the wavefunction for a molecule can be viewed as the output of a function $\xi(m, n_1,..., n_k)$ with $m, n_i \in \mathbb{Z}^+$ that returns a $|\psi\rangle$ that satisfies a ...
1
vote
4answers
267 views

Having trouble understanding some stuff about delta functions [closed]

I was going through one of the examples in Griffith's Quantum book and there was a few things in Example 3.3 that I didn't understand that I was hoping to get some clarification on. For instance, we ...
1
vote
3answers
99 views

Variational Theorem proof

I have been trying to prove variational theorem in quantum mechanics for a couple of days but I can't understand the logic behind certain steps. Here is what I have so far: \begin{equation} ...
0
votes
1answer
49 views

Two Particle System with Identical Particles

I'm studying for an exam in quantum mechanics and tried to calculate the ground state and the first two excited states of two identical bosons (spin 0) in an infinite one dimensional potential well. ...
2
votes
2answers
77 views

Minimum information necessary to represent a pure quantum state

I was thinking about how quantum states are represented for various types of systems, and how the amount of classical information (bits) required to represent a state depends on its basis. Let's take ...
5
votes
5answers
875 views

Infinite Wells and Delta Functions

In considering a delta potential barrier in an infinite well, I can just enforce continuity at the potential barrier-it doesn't have to go to zero. Why then does it need to go to zero at the walls of ...
2
votes
1answer
78 views

Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
0
votes
1answer
50 views

Few particle fermion system wavefuction

Suppose I have 3 fermions($\left|\psi_1\right\rangle$, $\left|\psi_2\right\rangle$, $\left|\psi_3\right\rangle$) and a system with 3 states ( $\left|1\right\rangle$, $\left|2\right\rangle$, ...
2
votes
1answer
113 views

Normalization of a wavefunction that's superposition of two unknown energy eigenfunctions

Question:$$\psi(x)=A(3u_1(x)+4u_2(x))$$where $u_1(x)$ and $u_2(x)$ are energy eigenfunctions. How to normalize function $\psi(x)$? My intuitive solution: I got ...
0
votes
1answer
50 views

Scattering and bound States

So from my understanding, as long as $E>0$ you will have scattering states and these scattering states will always result in an imaginary $\psi$, but bound states can also have an imaginary ...