2
votes
1answer
48 views

Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
0
votes
1answer
30 views

Few particle fermion system wavefuction

Suppose I have 3 fermions($\left|\psi_1\right\rangle$, $\left|\psi_2\right\rangle$, $\left|\psi_3\right\rangle$) and a system with 3 states ( $\left|1\right\rangle$, $\left|2\right\rangle$, ...
1
vote
0answers
35 views
+100

Wavefunction of isomers

In quantum chemistry, the wavefunction for a molecule can be viewed as the output of a function $\xi(m, n_1,..., n_k)$ with $m, n_i \in \mathbb{Z}^+$ that returns a $|\psi\rangle$ that satisfies a ...
2
votes
1answer
81 views

Linear vs. quadratic dispersion relation

In wave mechanics the dispersion relation between frequency $\omega$ and wave number $k$ is linear: $$\omega_n=c k_n$$ But in quantum mechanics, based on Schrödinger's equation, one can show that we ...
0
votes
2answers
30 views

Finding out time $t$ when a particle is more likely to be on the right half than the left half of the box [closed]

Question: A particle with mass $m$ is trapped in a box of length $L$. At $t=0$, it has wavefunction as following: $$\psi(x,t=0)=\sqrt[]{\frac2{41\pi}}(3u_1(x)+4u_2(x))$$ where $u_1(x)$ and ...
2
votes
1answer
75 views

Normalization of a wavefunction that's superposition of two unknown energy eigenfunctions

Question:$$\psi(x)=A(3u_1(x)+4u_2(x))$$where $u_1(x)$ and $u_2(x)$ are energy eigenfunctions. How to normalize function $\psi(x)$? My intuitive solution: I got ...
0
votes
1answer
30 views

Introductory Quantum, trouble with this boundary condition and potential

Working on problem 2.40 from Griffiths but can't seem to understand the first boundary condition. We are given the potential $V(x) = \left\{\begin{matrix} \infty & x < 0\\ ...
0
votes
1answer
37 views

Scattering and bound States

So from my understanding, as long as $E>0$ you will have scattering states and these scattering states will always result in an imaginary $\psi$, but bound states can also have an imaginary ...
1
vote
2answers
116 views

The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...
1
vote
0answers
18 views

Can anyone give me a simple proof for the sign change of electronic wavefunction when taken around a loop containing a conical intersection?

How and why does the sign of the electronic wavefunction changes when it is taken around a contour? For example, suppose the initial wavefunction is $f(s;S_0)$ at nuclear configuration $S_0$ and now ...
-1
votes
0answers
45 views

What does the wavefunction actually show?

I.e. when someone says they've solved the Schrödinger equation for something, or that the equation can be used to show how the wave function develops over time, what do they mean? I know that its to ...
0
votes
2answers
105 views

Particle in a Box: Energy Less than the Potential Energy

I am reading quantum mechanics from Shankar's Principles of Quantum Mechanics. On page 157 he defines the box potential $V(x)$ as $$ V(x) = \left\{ \begin{array}{rl} 0 &\mbox{ if $|x|< L/2$} ...
0
votes
1answer
46 views

How can an electron be fired at a target when uncertainty principle says it will spread out around axis of motion?

Consider an electron fired at a target. Taking the axis of motion to be $x$, and position to be $(x,y,z)$ then $\Delta y = \Delta z = 0$ Therefore by the uncertainty principle $\Delta p_y = ...
2
votes
1answer
102 views

Quantum harmonic oscillator solved by analytic method using Schrödinger equation and wave function

I'm having trouble understanding the recursion formula. Using $\xi \equiv \sqrt{m\omega/\hbar}x$ and $K = 2E/\hbar\omega$, the time-independent Schrödinger equation becomes $$\frac{d^2\psi}{d\xi ^2} ...
15
votes
4answers
647 views

Why do electrons in an atom occupy only the stationary states?

When we talk about the elementary problems in quantum mechanics like particle in a box, we first calculate the energy eigen-function. Then we say that the most general state is the linear combination ...
1
vote
1answer
70 views

Turning a finite difference equation into code (2d Schrodinger equation)

I am trying to convert the following finite difference equations into code (taken from the bottom of page 12 of this thesis by Maike Schulte Numerical Solution of the Schrodinger Equation on Unbounded ...
1
vote
0answers
51 views

Find Equation of Motion given Hamiltonian

So I am given a harmonic oscillator in an electric field. At $t=0$, we are given that the oscillator is in the ground state. The Hamiltonian is: $$H=\hbar \omega[a^{\dagger}a+\frac12+\kappa ...
4
votes
1answer
82 views

Why can we leave off half of the general solution?

In these pdf notes, it says at the bottom of the first page and beginning of the second: [...] whose solution is: $$\Psi(\theta) = c_1 e^{i\omega\theta} + c_2 e^{-i\omega\theta}$$ Since we are ...
0
votes
1answer
54 views

Correct approach for calculating excited states of circular quantum dot under effective mass approximation

From Asnani, Mahajan et al, Pramana Journal Of Physics 73 #3 (2009) p574-580 "Effective mass theory of a two-dimensional quantum dot in the presence of magnetic field", which can be seen here: ...
1
vote
1answer
162 views

Particle Outside the Box

What prohibits, mathematically, that a particle cannot be found outside the box ? Here, I am referring to particle in a box problem (infinite potential on both ends & zero potential along the ...
4
votes
2answers
342 views

Where to place the operator?

I believe it's standard to place the operator in between the conjugate of the wavefunction and the wavefunction itself. For instance, $$\langle p\rangle = \int_{-\infty}^{\infty}\Psi * ...
3
votes
1answer
146 views

Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
2
votes
1answer
134 views

Normalizing wavefunction

If you are trying to normalize $\psi = A\sin kx$, and you find that $|A|^2 = \frac{2}{a}$, why do you take the positive square root and not the negative? What happens if you take the negative square ...
1
vote
1answer
335 views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
-1
votes
0answers
19 views

Schrodinger equation with unknown potential function [duplicate]

How to find wave function if potential function is unknown. I have only the scattering data: time and coordinates of scattering particle.
5
votes
3answers
98 views

Is the ground state closest to the uncertainty relation? [duplicate]

For simplicity, suppose we are only talking about discrete energy levels, ie, bound state case. The energy levels are $E_1, E_2\cdots$, and the corresponding wave functions are $\psi_1, \psi_2 ...
1
vote
1answer
142 views

Complex Quantum Wave [closed]

Can the complex nature of quantum wave arise from the fact that particle is represented as wave packet in spatial frequency and particle's total energy is represented as wave packet in time frequency? ...
1
vote
1answer
57 views

Degeneracy in One Dimension

I'm reading this wikipedia article and I'm trying to understand the proof under "Degeneracy in One Dimension". Here's what it says: Considering a one-dimensional quantum system in a potential ...
3
votes
2answers
142 views

Infinitely many degeneracy of Landau level: Countable or Uncountable?

Description of Landau levels can be found in many standard textbooks of quantum mechanics and here. Two ubiquitous solutions apply either the symmetric gauge $\vec{A}=(-\frac{1}{2}By,\frac{1}{2}Bx,0)$ ...
5
votes
3answers
374 views

What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess ...
2
votes
0answers
27 views

How does a photon travel through an electron cloud?

We all know that the exact position and exact velocity of an electron in an atom cannot be determined simultaneously, as per the Heisenberg uncertainty principle. We only talk about the probability of ...
2
votes
1answer
43 views

Why is the full eigen function is product of eigen functions and not addition?

For example suppose there is a two electron system. Why is the full eigen function product of the spatial eigen function and spin wave function for the two electron system?
0
votes
1answer
36 views

Probability to be in a particular state

If I have a wavefunction $\psi = \sum_{n=0}^{\infty} a_n e^{i \phi_n} | n \rangle$ and $(|n \rangle)$ is a set of orthonormal functions. Is it correct that the probability to be in a state $|k\rangle ...
4
votes
1answer
323 views

Am I missing a trick to solving this differential equation?

I was playing around with a 3-D potential $V$ such that $V_{(r)} = 0$ for $r<a$, and $V_{(r)} = V_0$ otherwise. By using the Schrödinger Equation, I showed that: ...
4
votes
2answers
145 views

What is the physical reason behind linearity of Schrodinger's equation?

What is the physical reason for Schrodinger equation to be linear? Though in physics many interactions or dynamics are found non linear.
1
vote
1answer
70 views

Different mathematical methods in quantum mechanics?

My understanding is that in quantum mechanics the wavefunction may be expressed as a function or as a ket vector (composed of many orthogonal ket vectors). I'm not too sure about the further ...
0
votes
0answers
39 views

Question about Hartle and Hawking's universal wavefunction?

My apologies in advance if this question is poorly worded or doesn't make any sense, however I have just finished reading into this theory and it seems as though Hawkings No Boundary Universe is ...
2
votes
3answers
60 views

Koopmann von Neumann (KvN) Theory

I was just wondering does anyone have any informative sources apart from the obvious wikipedia articles regarding Koopmann von Neumann (KvN) theory? Or if its possible could someone explain the basic ...
0
votes
3answers
57 views

What does “coherent wave function of a macroscopic body” mean?

What is meant by the "coherent wave function of a macroscopic body"? I found this phrase in a paper on QM, but am unfamiliar with the terminology.
3
votes
1answer
111 views

What does the notation $\Psi_k/(\Psi_k,\Psi_k)^{1/2} $ mean?

I am currently reading the paper "Gravitation and quantum mechanics for macroscopic objects" by F. Karolyhazy (1966). In his paper, he uses certain notation that I haven't come across before (he also ...
1
vote
0answers
57 views

1-particle momentum eigenfunction in terms of field operator for real Klein-Gordon field

Suppose $\phi(x)$ is a real Klein-Gordon field, then the single-particle wave function $\psi(x)$ corresponding to a momentum $p$ is given by (QFT, Ryder) $$\psi_p(x)=\langle0|\phi(x)|p\rangle.$$ The ...
1
vote
1answer
111 views

Doubt in a certain equation of a research paper [closed]

In the given paper, I am stuck at equation (7). The equation that I am trying to solve for particle outside the well is : (1/g)*(g'') + (1/(r*g))*g' - (k_o)^2 = 0 where g = Radial wave function. r = ...
0
votes
1answer
41 views

Expected value $<\hat{x}>$ of: $\Phi(x,t)=Ne^{-a[(Mx^2/\hbar)+it]}$ is infinite, why?

The problem says: A particle of mass $M$ is described by the wave function: $$\Phi(x,t)=Ne^{-a[(Mx^2/\hbar)+it]}$$ where a is a positive constant. Asked to determine such things as the ...
2
votes
1answer
47 views

Eigenfunctions corresponding to degenerate spectra

It is well knwon that an eigenstate can be obtained by superposing wavepackets. In other words, if $\Psi({\bf x},t)$ is the solution of the time dependent Schroedinger equation for an initial ...
0
votes
1answer
62 views

Wavefunctions and Quark Confinement

While I have a decent knowledge of general relativity (and, of course, classical mechanics), I am quite a novice when it comes to quantum mechanics, so I apologize if this is a rather basic question. ...
1
vote
2answers
134 views

Determining the Wave Function From Initial Conditions

This is Problem 2.6 (b) in Griffiths, Intro to QM: A particle in an infinite square well has its initial wave function an even mixture of the first two stationary states: $\Psi(x,0) = ...
4
votes
2answers
296 views

Does a wavefunction interact with itself?

Considering the double slit experiment with a charged particle, after the particle passes through the slits, do the two portions of the wavefunctions feel the electromagnetic attraction of the other ...
3
votes
1answer
113 views

Why is $\omega = \sqrt{K/m}$ valid for a quantum oscillator?

I'm working in the 3rd edition of Modern Physics by Serway, Moses, and Moyer. In 6.6, it talks about a quantum oscillator. I don't fully understand how the definition of frequency works. Now, we ...
0
votes
1answer
126 views

Determine the normalisation constant of a piecewise wavefunction

I'm trying to find the normalisation constant $N$ for the following wavefunction: $$ \psi\left(x\right) = \left\{ \begin{array}{lr} N \left(x^2 - l^2\right)^2 &\: \left|x\right| \le l ...
1
vote
2answers
84 views

Is the mechanics of the wave function in the quantum mechanics deterministic?

Is possible a non-deterministic propagation of the wave function in the QM?