1
vote
3answers
94 views

Expectation Values and Derivation of Heisenberg Equation?

Consider a system of particles with wave function $\psi$(x) (x can be understood to stand for all degrees of freedom of the system; so, if we have a system of two particles then x should represent ...
-1
votes
1answer
79 views

Apply the Heisenberg Equation to the Hamiltonian [closed]

$\frac{d}{dt}$$\hat{H}$ = $\frac{i}{\hbar}$$[\hat{H},\hat{H}]$ +$\frac{\partial{\hat{H}}}{\partial{t}}$ That's as far as I've got. I do not know much about the Heisenberg equation or even what it ...
1
vote
2answers
66 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
3
votes
3answers
112 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
0
votes
2answers
71 views

Momentum Operator in Quantum Mechanics

1) What is the difference between these two momentum operators: $\frac{\hbar}{i}\frac{\partial}{\partial x}$ and $-i\hbar\frac{\partial}{\partial x}$? How are these two operators the same? My ...
9
votes
2answers
173 views

The formal solution of the Schrodinger equation

Let's have Schrodinger equation (or some equation in Schrodinger form) $$ \tag 1 i \partial_{0} \Psi ~=~ \hat{H} \Psi . $$ One likes to write that it has formal solution $$ \tag 2 \Psi (t) ~=~ ...
4
votes
1answer
218 views

Imaginary Eigenvalue Of A Hermitian Operator

The eigenfunctions of a Hermitian operator are real. But consider a function $\psi(x)=e^{-\kappa x}$, $x\in\mathbb{R}$, where $\kappa$ is a real constant. Then, $$\hat p \psi(x)=-i\hbar ...
2
votes
3answers
192 views

Implicit Postulate of Quantum Mechanics

Consider the following quantum system: a particle in a one dimensional box (= infinite potential well). The energy eigenstates wave functions all vanish outside the box. But the position eigenstates ...
4
votes
2answers
289 views

Schrödinger equation in position representation

$$ \DeclareMathOperator{\dif}{d \!} \newcommand{\ramuno}{\mathrm{i}} \newcommand{\exponent}{\mathrm{e}} \newcommand{\ket}[1]{|{#1}\rangle} \newcommand{\bra}[1]{\langle{#1}|} ...
0
votes
1answer
970 views

Expectation value of position in infinite square well

I'm looking for some help to a question. I'm working in the infinite square well, and I have the wavefunction: $$\psi(x,t=0)=A\left( i\sqrt{2}\phi_{1}+\sqrt{3}\phi_{2} \right).$$ For every time t, ...
1
vote
1answer
88 views

Question about the linearity of wave functions

For piece-wise constant potential, the potential energy is constant so the time dependent wave function can take the form $\psi(x,t)=C_1e^{i(kx- \omega t)}+C_2e^{i(-kx-\omega t)}$ where ...
1
vote
1answer
186 views

Once I have the eigenvalues and the eigenvectors, how do I find the eigenfunctions?

I am using Mathematica to construct a matrix for the Hamiltonian of some system. I have built this matrix already, and I have found the eigenvalues and the eigenvectors, I am uncertain if what I did ...
2
votes
1answer
457 views

How do I solve these integrals of wave function and operator?

First integral $$\int \Psi^*({\bf r},t)\hat {\bf p} \Psi({\bf r},t)\, d^3r,$$ where the $\Psi({\bf r},t)=e^{i({\bf k}\cdot{\bf r}-\omega t)}\,\,\,$ and $\hat {\bf p}=-i\hbar \nabla$. Second one ...
0
votes
1answer
468 views

Weird operator and wavefunctions

How can one show that $\int_{-\infty}^{\infty}\psi^*(x)(d/dx+\tanh x)(-d/dx+\tanh x)\psi(x) dx=\int_{-\infty}^{\infty} |(d/dx+\tanh x)\psi(x)|^2 dx$, where $\psi$ is normalized?