0
votes
0answers
32 views

Uncertainty in the hydrogen ground state [closed]

The following question is put forward by one of my students. 1.In spherical polar coordinates, can radial momentum have the form $(h/2\pi i)[\partial/\partial r - 1/r]$? 2. If it is so, what is the ...
0
votes
0answers
36 views

Finite Square Well Inside an Infinite Square Well

Ok here's a potential I invented and am trying to solve: $$ V(x) = \begin{cases} -V_0&0<x<b \\ 0&b<x<a \\ \infty&x>a \\ \end{cases}$$ and $V(-x) = V(x)$ (Even ...
3
votes
1answer
34 views

Probability of measuring momentum [closed]

Suppose we have this wavefunction: $$ \psi = A \left( cos(kx) + cos (2kx) \right) $$ I have to find the possible results of measurement of momentum and their probabilities. Attempt For a momentum ...
1
vote
1answer
65 views

Obtain the eigenfunction of Jz for the wave function of an electron in a hydrogen atom? [closed]

The wave function of an electron in a hydrogen atom is given by Is this wave function an eigenfunction of Jz , the z-component of the electron’s total angular momentum? If yes, find the ...
1
vote
1answer
87 views

Why don't we need to normalize wavefunction to find probability distribution?

Consider an unormalized wavefunction of a rotor at $t = 0$, a combination of $n=0$ and $n=2$ states: $$\psi(\phi) = 3 - 2 \cos (2\phi).$$ Find the probability distribution in angle. The ...
0
votes
1answer
118 views

Calculating the expectation value of a Hamiltonian

I want to calculate the expectation value of a Hamiltonian. I have a wave function that is $$\psi = \frac{1}{\sqrt{5}}(1\phi_1 + 2\phi_2).$$ I want to know if I set this up properly. The ...
0
votes
1answer
64 views

Normalizing the sum of wavefunctions and calculating probabilty - understanding concepts

A state of a particle bounded by infinite potential walls at x=0 and x=L is described by a wave function $\psi = a\phi_1 + b\phi_2 $ where $\phi_i$ are the stationary states. So let's say we want to ...
1
vote
1answer
84 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
1
vote
2answers
95 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
0
votes
2answers
36 views

Calculating the Probability Current of a Travelling Wave

Calculate the probability current density vector $\vec{j}$ for the wave function : $$\psi = Ae^{-i(wt-kx)}.$$ From my very poor and beginner's understanding of probability density current it is : ...
4
votes
1answer
89 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
-1
votes
1answer
101 views

Apply the Heisenberg Equation to the Hamiltonian [closed]

$\frac{d}{dt}$$\hat{H}$ = $\frac{i}{\hbar}$$[\hat{H},\hat{H}]$ +$\frac{\partial{\hat{H}}}{\partial{t}}$ That's as far as I've got. I do not know much about the Heisenberg equation or even what it ...
0
votes
1answer
51 views

Wave function - Working towards Orthonormal solution

As you can see below, the two pages attached describe how to obtain the final solution of orthonormality. I do not completely follow the discussion but I will talk you through what I DO understand ...
0
votes
1answer
52 views
0
votes
0answers
83 views

Difference between expectation values of $L^2$, $L_z$ and measuring $L^2$, $L_z$

I was given with this hydrogen radial wavefunction $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ and was asked to find a) What are the expectation values of the ...
0
votes
1answer
125 views

Expectation value of energy from the position state of hydrogen atom [closed]

I was given with the position state of hydrogen atom: $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ I am getting confused about getting the expectation value of ...
3
votes
1answer
176 views

Harmonic Oscillator potential, proof that Gaussians remain Gaussians?

I read in several papers that for a Harmonic Oscillator Hamiltonian in the time dependent Schrödinger equation a Gaussian wave packet remains Gaussian. Unfortunately I could not find any proof for ...
2
votes
1answer
109 views

Two ways of calculating the expectation value of momentum

The expectation value of momentum is given by: $$ \langle p\rangle = \int_{-\infty}^{\infty}\psi^{*}(x)\left(-i\hbar\frac{\partial}{\partial x}\right)\psi(x)dx $$ How can I show that the above ...
0
votes
1answer
57 views

Group velocity of localized wavepacket

This is a Homework problem so please feel free to not answer and just give pointers. A localized wavepacket is given as: $$\Phi(r,t=0 ) = \frac { e^{-\large\frac {r^2}{2s^2}} e^{\large\frac{i\pi ...
0
votes
2answers
313 views

Schrödinger's Equation and the depth of a finite potential well

Before I ask my question, I have to stress: I have absolutely no idea what the math is going on. I've read my textbook, several Wikipedia articles, scoured the internet, and don't feel anymore ...
1
vote
1answer
139 views

Energy difference between symmetric and antisymmetric wavefunctions

Is there any energy difference between a particle in a symmetric wavefunction and an identical particle in an identical potential but in a state with an anti-symmetric wavefunction? Or is it ...
5
votes
2answers
88 views

Physical position eigenfunction normalisation

We know that the Dirac function $$\delta(a)=\lim_{a \rightarrow 0} \delta_{a}(x)$$ can be written as an infinitesimally narrow Gaussian: $$ \delta_{a}(x) := \frac{1}{\sqrt{2\pi a^2}}e^{-x^2/2a^2}$$ ...
0
votes
1answer
105 views

Wavefunction Problem wrong in solutions manual? [closed]

Well there is a problem in my book which lists this problem: Calculate the probability that a particle will be found at $0.49L$ and $0.51L$ in a box of length $L$ when it has (a) $n = 1$. Take the ...
2
votes
1answer
96 views

Three dimensional wave packets in momentum space

I am given the 3D wave packet: $$\psi(x,y,z)=N\,\exp\left(\frac{-(x^2+y^2+2z^2)}{2a^2}\right).$$ I was asked to find N (easy enough). Then I was asked the probability that we measure $z$ greater than ...
2
votes
0answers
83 views

Momentum representation of a state

I am trying to figure out the momentum representation of the state which has the properties $$\langle \psi |\hat q |\psi \rangle=-q_0,$$ $$\langle\psi|\hat p|\psi \rangle=p_0, $$$$\Delta q\Delta ...
2
votes
1answer
66 views

Transition from coordinate space to momentum space for SHO

I am given that the ground state of the SHO in position space is given as $$\langle q|\psi_0\rangle=\frac{1}{a^{\frac12}\pi^{\frac14}}e^{-q/4a^2}$$ Where a is a constant with units of length. I am ...
0
votes
1answer
108 views

photon polarization, uncertainty in Energy

A beam of red light is sent along the $z$ axis through a polaroid filter that passes only $x$ polarized light. The beam is initially polarized at $30$°, and the total energy is $10$ Joules. Estimate ...
2
votes
2answers
105 views

Infinite well particle subject to additional time dep. potential

I am asked to find the wavefunction of the particle in a well subject to an additional potential $$V(x,t)=\frac{\pi x \hbar}{L}\delta(t).$$ I have already solved that ...
0
votes
1answer
66 views

Question on measuring expectation value of spin with time variation

I have a particle with the following wave function: $$\psi(t) = \frac12 |\uparrow \rangle e^{-i(\omega_1+\omega_2)t/\hbar} +\frac12 |\uparrow \rangle e^{-i(\omega_1-\omega_2)t/\hbar} ...
1
vote
0answers
115 views

Basic introductory quantum mechanics question [closed]

Given that $\psi = \frac{1}{\sqrt{32 \pi a_{0}^{3}}}(2-\frac{r}{a_0})exp(\frac{-r}{2a_0})$ is a wavefunction of the hydrogen atom, write down the probability density for r and calculate the ratio ...
2
votes
2answers
254 views

Solving quantum radial equation for infinite potential spherical annulus for $l=0$

There is a mass $m$ in a potential such that $$ V(r) = \left\{ \begin{array}{lr} 0, & a \leq r \leq b\\ \infty, & \text{everywhere else} \end{array} \right. $$ ...
4
votes
1answer
167 views

Virial theorem and variational method: an exercise (re-edited)

I have a hydrogen atom, knowing that its Hamiltonian has been modified turning the standard potential $$ V_{0}(r) = -\frac{Z}{r} $$ into $$ V(r) = -\frac{g}{r^{\frac{3}{2}}} $$ with $g$ a positive ...
1
vote
1answer
143 views

Spin eigenvalues and eigenvectors problem. Is this the correct way to solve it?

An electron is described by the Hamiltonian $ H=\frac{e}{mc}\bar{S}\cdot\bar{B} $ where $\bar{S} =(S_x,S_y,S_z)$ is the spin operator and $\bar{B}$ the magnetic field. For $t>0$ ...
1
vote
1answer
171 views

Energy and time evolution of a particle in a potential well

Hoping this is not a silly and stupid question let me ask for help in this problem. I have a particle in an infinite square well (the box is from 0 to a), in the state described by the function ...
7
votes
1answer
252 views

Virial theorem and variational method: a question

I have an hydrogenic atom, knowing that its ground-state wavefunction has the standard form $$ \psi = A e^{-\beta r} $$ with $A = \frac{\beta^3}{\pi}$, I have to find the best value for $\beta$ ...
1
vote
2answers
161 views

Bloch wave function orthonormality?

there is this text book that is giving me a hard time for a while now: It shows that Bloch wave functions can be written as $$\Psi_{n\vec{k}}\left(\vec{r}\right) = \frac{1}{\sqrt{V}}e^{i\vec k \vec ...
1
vote
1answer
1k views

Ground State Wavefunction of Two Particles in a Harmonic Oscillator Potential

Question: Two identical, non-interacting spin-$1/2$ particles are in a 1D Harmonic Oscillator Potential. Their Hamiltonian is given by ...
-3
votes
2answers
63 views

Which number should I suppose to $a$ (width of well) and $m$ (mass of particle) in potential well problem? [closed]

I tried to plot a complete of state functions of potential well problem but graph was so weird. I thought a cause was variables a and ...
1
vote
1answer
133 views

Modulus Square of the Gaussian Wave Packet for uncertainty in $p$

Upon evaluating the integral (2.67) and obtaining the complex valued equation given in box 2.4, the author performs the modulus square to obtain the Gaussian distribution (2.68). How does one go about ...
0
votes
2answers
251 views

Normalising a wavefunction where $\psi$ is equal to a sum of functions [closed]

The wavefunction $\psi(x)$ = $\phi_1(x)$ + $2\phi_2(x)$ + $3\phi_3(x)$ is to be normalised. The functions $\phi_1(x)$, $\phi_2(x)$, $\phi_3(x)$ are normalised eigenfunctions of a Hermitian operator ...
3
votes
2answers
282 views

Formulation and probability of a wave-function [closed]

I have got this problem where I have been given the following wave function: $$\Psi = 0\quad\text{if}~|x| > a\quad\text{and}\quad A(a^2-x^2)\quad \text{if} \quad |x|< a$$ Now the first question ...
2
votes
1answer
129 views

Possible Outcomes from Measuring a Hydrogen Atom

A hydrogen atom is characterized by the wavefunction $$\mid \psi \rangle =\sqrt{\frac{2}{7}}\mid 4\,2\,1\rangle +\sqrt{\frac{1}{7}}\mid 2 \,1\,\bar{1}\rangle+\sqrt{\frac{4}{7}}\mid 3\,2\,0\rangle$$ ...
0
votes
1answer
90 views

Momentum representation of a function with discontinuous derivative [closed]

Consider the following wave packet $$\psi = Ce^{2\pi i p_0x/h}e^{-|x|/(2\Delta x)}$$ where $h$ is the Planck's constant and $C$ is the normalization constant. The derivative of this function is ...
2
votes
1answer
218 views

Probability current vs. direction of wave function

I did an exercise for my Quantum-Mechanics Lecture: Let $\hbar$=2m=1. A particle in 1 dimension has $j(x)=2\ Im(\overline{\psi} (x) \ \psi'(x))$ and it's to show that there are superpositions $\psi ...
5
votes
1answer
404 views

Orthonormality of Radial Wave Function

Is the radial component $R_{n\ell}$ of the hydrogen wavefunction orthonormal? Doing out one of the integrals, I find that $$\int_0^{\infty} R_{10}R_{21}~r^2dr ~\neq~0$$ However, the link below says ...
1
vote
1answer
451 views

Writing a Wavefunction as a Linear Combination of Eigenstates

We have the following wavefunction for the hydrogen atom: $$\psi(r,\theta,\phi)=\frac{1}{\sqrt{4\pi}}\frac{1}{(2a)^{3/2}}\frac{r}{a}e^{-r/2a}\sin(\theta)\sin(\phi)$$ where $a$ is the Bohr radius. ...
1
vote
1answer
289 views

Tunnelling through a Dirac potential barrier

I am reading a QM book by Griffiths, which says it is possible for wave particle to tunnel through a barrier formulated by a Dirac function. This function is known to peak at infinity and also ...
1
vote
1answer
1k views

How to find the wavefunction that solves an infinite square well with a delta function well in the middle?

Solutions for the wavefunction in an infinite square well with a delta function barrier in the middle are easily found online (see here for an example). I am wondering what the wavefunction is for an ...
2
votes
1answer
241 views

Given wave function at $t=0$, what is the process of deriving time dependent wave equation? [closed]

Suppose $$\Psi (x, t=0)=Ae^{i\alpha _1}\psi _1(x)+Be^{i\alpha _2}\psi_2(x)+Ce^{i\alpha _3}\psi_3(x).$$ If $\psi _n$ are the energy eigenfunctions how would I derive $\Psi (x,t)$? I am having trouble ...
2
votes
1answer
869 views

Overlap integral and probability

I have a question regarding how to extract probability from an overlap integral. Specifically, I am calculating the probability of a particle in a bound state in a delta potential $V=-\alpha ...