2
votes
1answer
75 views

Normalization of a wavefunction that's superposition of two unknown energy eigenfunctions

Question:$$\psi(x)=A(3u_1(x)+4u_2(x))$$where $u_1(x)$ and $u_2(x)$ are energy eigenfunctions. How to normalize function $\psi(x)$? My intuitive solution: I got ...
15
votes
4answers
649 views

Why do electrons in an atom occupy only the stationary states?

When we talk about the elementary problems in quantum mechanics like particle in a box, we first calculate the energy eigen-function. Then we say that the most general state is the linear combination ...
4
votes
2answers
342 views

Where to place the operator?

I believe it's standard to place the operator in between the conjugate of the wavefunction and the wavefunction itself. For instance, $$\langle p\rangle = \int_{-\infty}^{\infty}\Psi * ...
2
votes
1answer
134 views

Normalizing wavefunction

If you are trying to normalize $\psi = A\sin kx$, and you find that $|A|^2 = \frac{2}{a}$, why do you take the positive square root and not the negative? What happens if you take the negative square ...
5
votes
3answers
98 views

Is the ground state closest to the uncertainty relation? [duplicate]

For simplicity, suppose we are only talking about discrete energy levels, ie, bound state case. The energy levels are $E_1, E_2\cdots$, and the corresponding wave functions are $\psi_1, \psi_2 ...
3
votes
2answers
142 views

Infinitely many degeneracy of Landau level: Countable or Uncountable?

Description of Landau levels can be found in many standard textbooks of quantum mechanics and here. Two ubiquitous solutions apply either the symmetric gauge $\vec{A}=(-\frac{1}{2}By,\frac{1}{2}Bx,0)$ ...
4
votes
2answers
145 views

What is the physical reason behind linearity of Schrodinger's equation?

What is the physical reason for Schrodinger equation to be linear? Though in physics many interactions or dynamics are found non linear.
2
votes
3answers
60 views

Koopmann von Neumann (KvN) Theory

I was just wondering does anyone have any informative sources apart from the obvious wikipedia articles regarding Koopmann von Neumann (KvN) theory? Or if its possible could someone explain the basic ...
3
votes
1answer
111 views

What does the notation $\Psi_k/(\Psi_k,\Psi_k)^{1/2} $ mean?

I am currently reading the paper "Gravitation and quantum mechanics for macroscopic objects" by F. Karolyhazy (1966). In his paper, he uses certain notation that I haven't come across before (he also ...
1
vote
2answers
135 views

Determining the Wave Function From Initial Conditions

This is Problem 2.6 (b) in Griffiths, Intro to QM: A particle in an infinite square well has its initial wave function an even mixture of the first two stationary states: $\Psi(x,0) = ...
6
votes
5answers
595 views

Differences between probability density and expectation value of position

The expression $\int | \Psi\left(x\right)|^2dx$ gives the probability of finding a particle at a given position. If wave function gives the probabilities of positions, why do we calculate ...
0
votes
1answer
51 views

Observables in Quantum Mechanics

Studying on own quantum mechanics I came across: Preceeding text: A basic postulate of quantum mechanics tells us how to set up the operator corresponding to a given observable. Observables, ...
2
votes
2answers
121 views

Differences between wave function and set of orthonormal wave functions?

I'm reading a QM book. It first says for wave function: "The state of a physical system (or particle) is completely specified by an entity associated with it called a wave function, Ψ , that in ...
0
votes
1answer
51 views

(Level: Undergrad) Continuity Conditions on the Wavefunction and Initial Values

I know that a physically meaningful $\Psi$ needs to be continuous. However, recently I came across a problem in which they were considering a wavefunction for the infinite square well potential and ...
3
votes
2answers
134 views

What is the analogy of $|x\rangle$ in quantum field theory?

Let me start from path integral formulation in quantum mechanics and quantum field theory. In QM, we have $$ U(x_b,x_a;T) = \langle x_b | U(T) |x_a \rangle= \int \mathcal{D}q e^{iS} \tag{1} $$ ...
2
votes
3answers
118 views

I am learning Quantum Mechanics and I have some questions about some basic concept [closed]

What does a "STATE" exactly mean in quantum mechanics? What is the equivalence of "STATE" in classical mechanics? If we have a wave function $\Psi$ , its absolute square $|\Psi|^2$ is the ...
0
votes
2answers
113 views

Representations in quantum mechanics [closed]

This might be a very simple question. I just want someone to point me the right direction to understand things like this: $$ \langle x|x'\rangle=\delta(x-x') \\ \psi(x)=\langle x|\psi\rangle \\ ...
4
votes
4answers
400 views

Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ ...
1
vote
1answer
117 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
1
vote
1answer
120 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
2
votes
3answers
275 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
1
vote
1answer
116 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
1
vote
2answers
103 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
4
votes
1answer
112 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
1
vote
2answers
104 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
1
vote
1answer
153 views

Quantum Mechanics - Rectangular Potential Barrier - Normalisation

I have a quick question regarding the normalisation of the wave function of a particle incident on a potential barrier specifically regarding the normalisation of the wave functions. The problem is ...
3
votes
3answers
362 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
1
vote
1answer
275 views

Correspondence between wave function and state vector

I am confused with connection between state $| \psi \rangle$ of a quantum system and corresponding wave function $\psi(x)$ (at a given time). I have been told that for every state $| \psi \rangle$ we ...
4
votes
1answer
288 views

Imaginary Eigenvalue Of A Hermitian Operator

The eigenfunctions of a Hermitian operator are real. But consider a function $\psi(x)=e^{-\kappa x}$, $x\in\mathbb{R}$, where $\kappa$ is a real constant. Then, $$\hat p \psi(x)=-i\hbar ...
6
votes
2answers
473 views

Does the wave function always asymptotically approach zero?

I'm new to quantum physics (and to this site), so please bear with me. I know that quantum mechanics allows particles to appear in regions that are classically forbidden; for example, an electron ...
1
vote
2answers
269 views

General wavefunction and Schrödinger Equation

I'm starting with quantum mechanics and the book I follow (Griffiths) first introduces the wavefunction as the probability density of the position of a 0-spin single particle. Later on I've realized ...
4
votes
1answer
117 views

Can general wavefunctions be expressed as kets?

I am confused on bra-ket notation in quantum mechanics. My professor says that a ket is an eigenfunction of some operator. However, for some time now I thought a ket could represent a general ...
1
vote
1answer
611 views

Writing a Wavefunction as a Linear Combination of Eigenstates

We have the following wavefunction for the hydrogen atom: $$\psi(r,\theta,\phi)=\frac{1}{\sqrt{4\pi}}\frac{1}{(2a)^{3/2}}\frac{r}{a}e^{-r/2a}\sin(\theta)\sin(\phi)$$ where $a$ is the Bohr radius. ...
1
vote
1answer
117 views

Wavefunction's inner product

When two wavefunctions are orthogonal we can write that $$\langle\Psi_n|\Psi_m\rangle=\delta_{mn}$$ This means that $$\langle\Psi_1|\Psi_2\rangle=\langle\Psi_2|\Psi_1\rangle=0$$ But if the two ...
1
vote
2answers
353 views

Wave function decomposition

Problem: Given the wave function $\Psi_0=A\sin^2(\theta)$ along with the Hamiltonian operator of a physical system: $H=\frac{L^2}{2I}+g B L_z$, find the eigenvalues and eigenfunctions of $\hat{H}$ ...
7
votes
2answers
255 views

Quantum states as rays as opposed to vectors

I recently read that a quantum state is actually defined by a ray and not a vector. That is it is possible to multiply a state $\psi$ by any complex number $c\in \mathbb{C}$ and you won't be changing ...
2
votes
3answers
234 views

Implicit Postulate of Quantum Mechanics

Consider the following quantum system: a particle in a one dimensional box (= infinite potential well). The energy eigenstates wave functions all vanish outside the box. But the position eigenstates ...
0
votes
2answers
459 views

Basic question on bra-ket notation

Which of the following corresponds to a $ \psi(x)$, a wavefunction written in the position basis: $ x| \psi\rangle $ or $ \langle x| \psi\rangle $? If it is the second expression (which my textbook ...
4
votes
2answers
414 views

Schrödinger equation in position representation

$$ \DeclareMathOperator{\dif}{d \!} \newcommand{\ramuno}{\mathrm{i}} \newcommand{\exponent}{\mathrm{e}} \newcommand{\ket}[1]{|{#1}\rangle} \newcommand{\bra}[1]{\langle{#1}|} ...
9
votes
3answers
1k views

Meaning of inner product $\langle \vec{r} | \psi(t)\rangle $

I have come across the equation which comes out of the nothing in Zettili's book Quantum mechanics concepts and applications p. 167: $$\psi(\vec{r},t) ~=~ \langle \vec{r} \,|\, \psi(t) \rangle.$$ ...
3
votes
2answers
896 views

Vector representation of wavefunction in quantum mechanics?

I am new to quantum mechanics, and I just studied some parts of "wave mechanics" version of quantum mechanics. But I heard that wavefunction can be represented as vector in Hilbert space. In my eye, ...
1
vote
1answer
234 views

What does it mean for something to be a ket?

Ok so I will provide the following example, which I am choosing at random from Sabio et al(2010): $$\psi(r,\phi)~=~\left[ \begin{array}{c} A_1r\sin(\theta-\phi)\\ ...
2
votes
1answer
986 views

Wave function and Dirac bra-ket notation

Would anyone be able to explain the difference, technically, between wave function notation for quantum systems e.g. $\psi=\psi(x)$ and Dirac bra-ket vector notation? How do you get from one to the ...
1
vote
1answer
200 views

Once I have the eigenvalues and the eigenvectors, how do I find the eigenfunctions?

I am using Mathematica to construct a matrix for the Hamiltonian of some system. I have built this matrix already, and I have found the eigenvalues and the eigenvectors, I am uncertain if what I did ...
2
votes
2answers
362 views

In Dirac notation, what do the subscripts represent? (Solution for particle in a box in mind)

So the set of solutions for the particle in a box is given by $$\psi_n(x) = \sqrt{\frac{2}{L}}\sin(\frac{n\pi x}{L}).$$ In Dirac notation $<\psi_i|\psi_j>=\delta_{ij}$ assuming $|\psi_i>$ ...
0
votes
3answers
625 views

Normalisation factor $\psi_0$ for wave function $\psi = \psi_0 \sin(kx-\omega t)$

I know that if I integrate probabilitlity $|\psi|^2$ over a whole volume $V$ I am supposed to get 1. This equation describes this. $$\int \limits^{}_{V} \left|\psi \right|^2 \, \textrm{d} V = 1\\$$ ...
1
vote
2answers
1k views

What does the quantum state of a system tell us about itself?

In quantum mechanics, quantum state refers to the state of a quantum system. A quantum state is given as a vector in a vector space, called the state vector. The state vector theoretically ...
2
votes
2answers
2k views

What's the physical significance of the inner product of two wave functions in quantum region?

I am a reading a book for beginners of the quantum mechanics. In one section, the author shows the inner product of two wave functions $\langle\alpha\vert\beta\rangle$. I am wondering what's the ...
4
votes
2answers
679 views

Where does the wave function of the universe live? Please describe its home

Where does the wave function of the universe live? Please describe its home. I think this is the Hilbert space of the universe. (Greater or lesser, depending on which church you belong to.) Or maybe ...