A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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Quantum vector space - A complex vector space [duplicate]

Why is vector space of states, a complex vector space? and not a real vector space or perhaps a space based on a new field altogether, which we would have to create specifically for quantum mechanics? ...
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67 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
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34 views

Normalizing the sum of wavefunctions and calculating probabilty - understanding concepts

A state of a particle bounded by infinite potential walls at x=0 and x=L is described by a wave function $\psi = a\phi_1 + b\phi_2 $ where $\phi_i$ are the stationary states. So let's say we want to ...
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$\psi^*$ if you have sine or cosine function [closed]

If my $\psi$ function is $\sin(\pi x/L)$. What is $\psi^*$ going to be?
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3answers
173 views

Why is $|\Psi|^2$ the probability density?

I am starting with Quantum Mechanics, learning online. I can't seem to find the reason for $|\Psi|^2$ being the probability density of finding an electron. They've just taken it for granted ...
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81 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
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85 views

Calculating the most probable radius for an electron of a hydrogen atom in the ground state

This link describes a method for determining the most probable radius of an electron for a Hydrogen atom in the ground state. It states that : The radial probability density for the hydrogen ...
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2answers
36 views

How will a particle with energy less than $V_{\rm min}$ behave?

Consider e.g. the finite square well: $V = -V_o$ between $x=-a$ and $x=a$, $V=0$ elsewhere Now for scattering states, $E$ must be $> 0$. For normalizable bound states, $E$ must be $< 0$ and ...
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3answers
112 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
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35 views

Potential Step - Choosing Wavefunctions

http://uqu.edu.sa/files2/tiny_mce/plugins/filemanager/files/4190016/Quantum_Mechanics_1/ch4-virtual-book.pdf On page 2 of the above pdf they describe how they select their wavefunctions. Finding the ...
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1answer
58 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
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2answers
81 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
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27 views

Calculating the Reflection Coefficient of a Potential Step Explicitly

So I'm using the following definition for the Reflection coefficient : $$\frac{\vec{j}_{reflected}}{\vec{j}_{incident}}$$ Hence, since : $$\psi_{reflected}=Be^{-ikx}$$ and ...
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1answer
39 views

Solving the 1D Schrodinger Equation for a Free Particle - Two Different Methods?

So starting from the time dependent schrodinger equation I perform separation of variables and obtain a time and spatial part. The spatial part is in effect the time independent schrodinger equation. ...
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391 views

Has the collapse of wave function due to observation been recorded?

I've seen pictures like this one, which depict the outcome of the Double-slit experiment with wave-like or particle features, depending how measurement has taken place. The graphic showing ...
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2answers
26 views

Calculating the Probability Current of a Travelling Wave

Calculate the probability current density vector $\vec{j}$ for the wave function : $$\psi = Ae^{-i(wt-kx)}.$$ From my very poor and beginner's understanding of probability density current it is : ...
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1answer
36 views

Electron distribution around atom when moving

I do not have much experience on this but if an atom has some electrons around nucleus and the atom itself it is moving at some speed does that affect the distribution of electrons around? I am ...
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3answers
94 views

Expectation Values and Derivation of Heisenberg Equation?

Consider a system of particles with wave function $\psi$(x) (x can be understood to stand for all degrees of freedom of the system; so, if we have a system of two particles then x should represent ...
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70 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
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1answer
80 views

Apply the Heisenberg Equation to the Hamiltonian [closed]

$\frac{d}{dt}$$\hat{H}$ = $\frac{i}{\hbar}$$[\hat{H},\hat{H}]$ +$\frac{\partial{\hat{H}}}{\partial{t}}$ That's as far as I've got. I do not know much about the Heisenberg equation or even what it ...
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1answer
41 views

Wave function - Working towards Orthonormal solution

As you can see below, the two pages attached describe how to obtain the final solution of orthonormality. I do not completely follow the discussion but I will talk you through what I DO understand ...
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1answer
41 views

Effect of pressure increase on electron orbital wave functions

One of my nuclear physics exercises was to find out if increasing the pressure of a sample of $^{7}\textrm{Be}$ would increase the chance of electron capture to $^{7}\textrm{Li}$ occur. My reasoning ...
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46 views
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KdV equation and classical linear wave equation

Like we know, the standard form of KdV equation is $$u_{t}-6uu_{x}+u_{xxx}=0,\tag{1}$$ where this equation describes a solitary wave propagation and $u=u(x,t)$. On the other hand, we know the ...
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66 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
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Quantum Mechanics - Rectangular Potential Barrier - Normalisation

I have a quick question regarding the normalisation of the wave function of a particle incident on a potential barrier specifically regarding the normalisation of the wave functions. The problem is ...
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1answer
44 views

Free particle Schrödinger Equation

Some sources give the free-particle solution to Schrödinger equation as $$\psi(x,t) =Ae^{i(kx-\omega t)} + Be^{-i(kx+\omega t)}$$ while some sources give it as $$\psi(x,t) =Ae^{i(kx-\omega t)}$$ ...
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Why do we must initially assume that the wavefunction is complex?

The sound waves are real, and they can interfere, so corresponding apparat may be used in quantum mechanics. We also may use the time dependence in a form of orthogonal matrix multiplying the initial ...
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What is probability current in quantum mechanics?

What is probability current in quantum mechanics? Why define such a thing? I mean the meaning of probability current. I know the formula for it but I just don't get the idea of a flow of probability ...
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36 views

Entropy before and after collapse of the wavefunction/ and interpretation?

Seems like it might be pretty rudimentary but I want to see if my thinking is on the right track as well as what the result means. The question is, is the entropy of the collapse of a wavefunction or ...
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35 views

Reflection of an evanescent matter wave within a finite barrier?

To my understanding if I have a finite barrier with potential $V(x)>E$, then to the left of the barrier, the wavefunction can be represented as two exponentials: $$\psi= e^{(ik_{left} x)} + ...
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114 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
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71 views

Momentum Operator in Quantum Mechanics

1) What is the difference between these two momentum operators: $\frac{\hbar}{i}\frac{\partial}{\partial x}$ and $-i\hbar\frac{\partial}{\partial x}$? How are these two operators the same? My ...
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Difference between expectation values of $L^2$, $L_z$ and measuring $L^2$, $L_z$

I was given with this hydrogen radial wavefunction $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ and was asked to find a) What are the expectation values of the ...
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1answer
73 views

Expectation value of energy from the position state of hydrogen atom [closed]

I was given with the position state of hydrogen atom: $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ I am getting confused about getting the expectation value of ...
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1answer
150 views

Harmonic Oscillator potential, proof that Gaussians remain Gaussians?

I read in several papers that for a Harmonic Oscillator Hamiltonian in the time dependent Schrödinger equation a Gaussian wave packet remains Gaussian. Unfortunately I could not find any proof for ...
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The formal solution of the Schrodinger equation

Let's have Schrodinger equation (or some equation in Schrodinger form) $$ \tag 1 i \partial_{0} \Psi ~=~ \hat{H} \Psi . $$ One likes to write that it has formal solution $$ \tag 2 \Psi (t) ~=~ ...
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82 views

Correspondence between wave function and state vector

I am confused with connection between state $| \psi \rangle$ of a quantum system and corresponding wave function $\psi(x)$ (at a given time). I have been told that for every state $| \psi \rangle$ we ...
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63 views

Confusion about state of a quantum system

I am confused with the concept of state of a quantum system. First postulate of QM ussualy says that the wave function of the system contains all information about the state of the system. But reading ...
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Learning about group velocity, phase velocity and particle velocity [duplicate]

I am studying quantum physics and I would like to know a bit more in detail about group velocity, particle velocity and phase velocity. Can you guys suggest some books/online resources where I can ...
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4answers
542 views

Quantum Wave Mechanics

I am studying QM-I these days. Now, I just think of the wave function as just a mathematical function that defines the state of the particle at an instant and from it you can extract various ...
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1answer
81 views

Two ways of calculating the expectation value of momentum

The expectation value of momentum is given by: $$ \langle p\rangle = \int_{-\infty}^{\infty}\psi^{*}(x)\left(-i\hbar\frac{\partial}{\partial x}\right)\psi(x)dx $$ How can I show that the above ...
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1answer
45 views

Group velocity of localized wavepacket

This is a Homework problem so please feel free to not answer and just give pointers. A localized wavepacket is given as: $$\Phi(r,t=0 ) = \frac { e^{-\large\frac {r^2}{2s^2}} e^{\large\frac{i\pi ...
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Regarding derivation of Probability Current

The question for the full derivation of Probability Conservation -> Probability Current was already asked here: Probability current. I apologize for not retyping it out, but it's already beautifully ...
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Conduction and propagation

What is the difference between conduction of electric wave in conductor and propagation of electromagnetic wave in dielectric? Why propagation term is used for dielectric and conduction for ...
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227 views

Schrödinger's Equation and the depth of a finite potential well

Before I ask my question, I have to stress: I have absolutely no idea what the math is going on. I've read my textbook, several Wikipedia articles, scoured the internet, and don't feel anymore ...
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How does a complex wavefunction “hold” energy?

Feynmann Lectures Vol 3 Ch 8 Sec 6 describes how an ammonia molecule can have two definite energy states. If the amplitudes of the base states are $ C_1(t) ...
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88 views

Energy difference between symmetric and antisymmetric wavefunctions

Is there any energy difference between a particle in a symmetric wavefunction and an identical particle in an identical potential but in a state with an anti-symmetric wavefunction? Or is it ...
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Setting the normalization volume to 1

In graphene, free electrons can have the following wavefunctions (there are other options, with minus signs in various places, but this will serve as an example): ...
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Why do we use $\psi$ instead of a straightforward probability?

What is the advantage/purpose of using $\psi$ for wavefunctions and getting the probability with $|\psi|^2$ as opposed to just defining and using the probability function?