A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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How to minimize the wavepacket dispersion?

This is a final exam problem. Here is what I can remember: We know that if an electron's wavefunction starts out as a narrow wavepacket, and moving in a region of constant potential, then the ...
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24 views

Double well potential [on hold]

A particle is in the following double-well potential with $E<0$: $$V(x)=0 \quad for \quad x<-a, x>a; -V_0 \quad for \quad -a<x<-b, b<x<a; 0 \quad for \quad -b<x<b$$ I am ...
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26 views

Wavefunction renormalisation in first order perturbation theory

I just read the following in the context of scattering amplitudes in QFT: Note that the wavefunction renormalisation factor $Z$ itself is of the form $1 + \mathcal{O}(\lambda)$ in perturbation ...
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1answer
25 views

Allowed energies for semi-harmonic oscillator

Question: If a particle is attached to a semi-harmonic oscillator (that is, for example, the spring is stretchable but not compressible) such that the potential $V(x)$ is infinity for $x\leq0$ and ...
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2answers
66 views

Is $\phi_n =\left\langle \vec r | n \right\rangle $ the photon wave function?

I am a bit confused about this issue and I am still not clear whether is there is a photon wave function or not. Since we use Fock states $| n \rangle$ to represent the state of a quantized ...
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3answers
40 views

Does there exist a hyperbolic relationship between frequency $\omega$ and wavenumber $k$?

As the title states, is it possible to derive a hyperbolic relationship in the form of $\frac{x^2}{a^2} - \frac{y^2}{b^2} = 1$ between frequency $\omega$ and wavenumber $k$ I have tried to start this ...
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5answers
187 views

How does a Wavefunction collapse?

I have been wondering and researching... How does a wavefunction collapse into one state?More specifically, what conditions cause a wavefunction for a quantum particle to collapse? Does this have to ...
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2answers
251 views

Hilbert space and Hamiltonians

Assume a system described by a Hamiltonian H, and assume that the eigenstates of H, $φ_i$(r) are integrable in absolute square. We say that these states belong to a Hilbert space (they can even form a ...
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1answer
69 views

Quantum Wavefunctions Without Space

A handful of physicists have a rather peculiar definition of 'nothing' in terms of cosmology. Their claim is that the Universe, assuming it has 0 total energy, could have arisen from nothing but ...
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0answers
47 views

Estimate of the second shallowest bound state?

Suppose we have a 1D potential $V(x)$ of finite range, i.e., $$ V(x) ~=~0 $$ for $|x| > b $. The potential is assume to support at least two bound states, but might have more, say $n\geq 2$. ...
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2answers
253 views

How to know if a wave function is physically acceptable solution of a Schrödinger equation?

How does one decide whether a wave function is a physically acceptable solution of the Schrödinger equation? For example: $\tan x$ , $\sin x$, $1/x$, and so on.
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1answer
127 views

1D Finite potential well: solutions with $\sinh$ and $\cosh$?

So I am studying the (one dimensional) quantum mechanical finite potential well defined by: $$ V(x) = \cases{0, &|x|>a\cr -V_0, &|x|<a} $$ where $V_0>0$ is a real number. I know ...
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1answer
113 views

Deriving a Useful Solution of the Schrödinger Equation [closed]

How does one derive the fact that $$\psi(t,x) = (\tfrac{2 \pi \hbar t}{m})^{-d/2}\int_{\mathbb{R}^d} e^{im\tfrac{(x-y)^2}{2\hbar t}}\psi_0(y)dy$$ is a solution of the time-dependent Schrödinger ...
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1answer
46 views

Wave packets and half-width at half-maximum

Suppose we have a Gaussian wave function and amplitude distribution function $$\psi(x) = (\frac{2}{\pi a^{2}})^{1/4}e^{-x^{2}/a^{2}}e^{ik_{0}x}, \qquad \phi(k) = (\frac{a^{2}}{2\pi})^{1/4}e^{-a^{2} ...
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3answers
110 views

A misunderstanding regarding infinite square well

Here is a picture of the energy states of infinite potential well. We can see That the first level have a half wavelength which fittes with a full wave of the second level. $$\frac{ \lambda _{1} ...
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3answers
79 views

Question about derivation of the Heisenberg Uncertainty Principle?

I am looking at the derivation presented here. The first thing I am unsure about is where the form of $\psi_0=Ae^{\frac{-m\omega x^2}{2\hbar}}$ came from. Also, is this form for all $\psi$, or just ...
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2answers
53 views

Does an excited state wave function depend on state preparation?

Consider a quantum system with a ground state and many excited states (e.g. an atom). If the system is in an excited state, to what extent does its wave function depend on the method of state ...
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2answers
111 views

Why is time evolution of wavefunctions non-trivial?

(Note: This post focuses on a single simple example, however I'm asking about the error in general in my logic). Consider the infinite potential well "particle in a box" system described by ...
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2answers
139 views

Ground state of Spherical symmetric potential always have $\ell=0$?

I was given a problem where I have a spherically symmetric potential (the exact form is not relevant to this question, I think - but anyway is it 0 for $r\in[a,b]$ and $\infty$ everywhere else) and I ...
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4answers
50 views

Question about interpreting probabilities in QM [duplicate]

For the example of an infinite square well, $\psi(x)=0$ for $x$ outside the well/interval, and we are to interpret this as the particle cannot be found outside the well because ...
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4answers
96 views

Complex Conjugate of Wave Function

I've been reading through Griffiths QM book, and the only thing bugging me is they never fully described what $\Psi^* $ should be for any given function. I know it's the complex conjugate at the same ...
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1answer
67 views

Bohr-Sommerfeld quantization for different potentials

Let's have Bohr-Sommerfeld quantization for one-dimensional case: $$ \int \limits_{a}^{b} p(x)dx ~=~ \pi \hbar (n + \nu ). $$ Here $p(x) = \sqrt{2m(E - U)}$, $a, b$ are turning points, and the area ...
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2answers
80 views

Indistinguishable particles and probability density

I am given the following (probably simple) exercise, but I think I misunderstand something: Let $\psi_{a,b}(r_1,r_2)$ be a two-particle state, calculate the probability density for distinguishable ...
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3answers
519 views

Wavefunction, probability and impossible events

A friend of mine asked me a question, which I considered trivial at first, but after a while gave rise to some doubts. For instance, we have a potential well in 1 dimension defined by $$ V(x)= ...
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25 views

Why isn't there a different phase after fourier transformation in two lattices

I am trying to understand some solutions for graphenes energy dispersion. While most of it is clear, I don't get one step, when changing into k-space. Consindering two sublattices A and B with ...
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330 views

Why the statement “there exist at least one bound state for negative potential” doesn't hold for 3D case?

Previously I thought this is a universal theorem, for one can prove it in the one dimensional case using variational principal. However, today I'm doing a homework considering a potential like ...
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1answer
55 views

Do quantum physics apply universally at all scales? [duplicate]

Do quantum physics apply universally at all scales? Where do quantum physics apply? Does the nucleus of an atom abide by the laws of quantum physics? Like do we know the definitive/velocity ...
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2answers
86 views

How would you go about evaluating $\langle \psi \mid 100 \mid \psi \rangle$? [closed]

How would you go about evaluating $\langle \psi \mid 100 \mid \psi \rangle$? I just can't seem to figure this out, and I know it isn't hard.
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0answers
33 views

In Quantum Physics would a camera count an observer that causes wave collapse? [duplicate]

Would the observation from a camera have the same effect on wave function as the observation from a living being?
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1answer
127 views

Quantum Mechanics in Electric Field

I am working on a problem which looks like this. Consider a charged particle with charge $q$ trapped in a box of length $L$ with finite constant potential $ V_0 $ on both ends. A constant (static) ...
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1answer
79 views

Quantum mechanics: Finite square well problem

What will happen if the potential is less than 0, for instance $V(x)=-10eV$. Is this means there will be no bound states? Since solution to the time independent Schrodinger equation (those discrete ...
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4answers
269 views

Having trouble understanding some stuff about delta functions [closed]

I was going through one of the examples in Griffith's Quantum book and there was a few things in Example 3.3 that I didn't understand that I was hoping to get some clarification on. For instance, we ...
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1answer
51 views

Two Particle System with Identical Particles

I'm studying for an exam in quantum mechanics and tried to calculate the ground state and the first two excited states of two identical bosons (spin 0) in an infinite one dimensional potential well. ...
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3answers
106 views

Variational Theorem proof

I have been trying to prove variational theorem in quantum mechanics for a couple of days but I can't understand the logic behind certain steps. Here is what I have so far: \begin{equation} ...
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2answers
78 views

Minimum information necessary to represent a pure quantum state

I was thinking about how quantum states are represented for various types of systems, and how the amount of classical information (bits) required to represent a state depends on its basis. Let's take ...
2
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1answer
80 views

Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
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1answer
52 views

Few particle fermion system wavefuction

Suppose I have 3 fermions($\left|\psi_1\right\rangle$, $\left|\psi_2\right\rangle$, $\left|\psi_3\right\rangle$) and a system with 3 states ( $\left|1\right\rangle$, $\left|2\right\rangle$, ...
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2answers
91 views

Wavefunction of isomers

In quantum chemistry, the wavefunction for a molecule can be viewed as the output of a function $\xi(m, n_1,..., n_k)$ with $m, n_i \in \mathbb{Z}^+$ that returns a $|\psi\rangle$ that satisfies a ...
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2answers
133 views

Linear vs. quadratic dispersion relation

In wave mechanics the dispersion relation between frequency $\omega$ and wave number $k$ is linear: $$\omega_n=c k_n$$ But in quantum mechanics, based on Schrödinger's equation, one can show that we ...
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1answer
122 views

Normalization of a wavefunction that's superposition of two unknown energy eigenfunctions

Question:$$\psi(x)=A(3u_1(x)+4u_2(x))$$where $u_1(x)$ and $u_2(x)$ are energy eigenfunctions. How to normalize function $\psi(x)$? My intuitive solution: I got ...
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1answer
42 views

Introductory Quantum, trouble with this boundary condition and potential

Working on problem 2.40 from Griffiths but can't seem to understand the first boundary condition. We are given the potential $V(x) = \left\{\begin{matrix} \infty & x < 0\\ ...
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1answer
53 views

Scattering and bound States

So from my understanding, as long as $E>0$ you will have scattering states and these scattering states will always result in an imaginary $\psi$, but bound states can also have an imaginary ...
2
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2answers
144 views

The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...
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0answers
23 views

Can anyone give me a simple proof for the sign change of electronic wavefunction when taken around a loop containing a conical intersection?

How and why does the sign of the electronic wavefunction changes when it is taken around a contour? For example, suppose the initial wavefunction is $f(s;S_0)$ at nuclear configuration $S_0$ and now ...
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2answers
172 views

Particle in a Box: Energy Less than the Potential Energy

I am reading quantum mechanics from Shankar's Principles of Quantum Mechanics. On page 157 he defines the box potential $V(x)$ as $$ V(x) = \left\{ \begin{array}{rl} 0 &\mbox{ if $|x|< L/2$} ...
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1answer
50 views

How can an electron be fired at a target when uncertainty principle says it will spread out around axis of motion?

Consider an electron fired at a target. Taking the axis of motion to be $x$, and position to be $(x,y,z)$ then $\Delta y = \Delta z = 0$ Therefore by the uncertainty principle $\Delta p_y = ...
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1answer
189 views

Quantum harmonic oscillator solved by analytic method using Schrödinger equation and wave function

I'm having trouble understanding the recursion formula. Using $\xi \equiv \sqrt{m\omega/\hbar}x$ and $K = 2E/\hbar\omega$, the time-independent Schrödinger equation becomes $$\frac{d^2\psi}{d\xi ^2} ...
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4answers
730 views

Why do electrons in an atom occupy only the stationary states?

When we talk about the elementary problems in quantum mechanics like particle in a box, we first calculate the energy eigen-function. Then we say that the most general state is the linear combination ...
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1answer
121 views

Turning a finite difference equation into code (2d Schrodinger equation)

I am trying to convert the following finite difference equations into code (taken from the bottom of page 12 of this thesis by Maike Schulte Numerical Solution of the Schrodinger Equation on Unbounded ...
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63 views

Find Equation of Motion given Hamiltonian

So I am given a harmonic oscillator in an electric field. At $t=0$, we are given that the oscillator is in the ground state. The Hamiltonian is: $$H=\hbar \omega[a^{\dagger}a+\frac12+\kappa ...