Tagged Questions

A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state.

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6
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4answers
157 views

Why the statement “there exist at least one bound state for negative potential” doesn't hold for 3D case?

Previously I thought this is a universal theorem, for one can prove it in the one dimensional case using variational principal. However, today I'm doing a homework considering a potential like ...
-1
votes
1answer
22 views

Is the probability density of a finite potential well independent of time or not? [on hold]

The probability of the first excited state of a finite potential well is time independent or not? Why?
0
votes
1answer
48 views

Do quantum physics apply universally at all scales? [duplicate]

Do quantum physics apply universally at all scales? Where do quantum physics apply? Does the nucleus of an atom abide by the laws of quantum physics? Like do we know the definitive/velocity ...
1
vote
2answers
72 views

How would you go about evaluating $\langle \psi \mid 100 \mid \psi \rangle$? [on hold]

How would you go about evaluating $\langle \psi \mid 100 \mid \psi \rangle$? I just can't seem to figure this out, and I know it isn't hard.
1
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0answers
33 views

In Quantum Physics would a camera count an observer that causes wave collapse? [duplicate]

Would the observation from a camera have the same effect on wave function as the observation from a living being?
0
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0answers
11 views

Time-dependent wavefunction for hydrogen molecule $H_2$ and hydrogen ion $H_2^+$ in the presense of laser field

I want to perform calculations for an electron-impact single ionization of the hydrogen molecule in the presence of a laser field. Basically, it boils down to evaluating the following integral $$ S = ...
0
votes
1answer
84 views

Quantum Mechanics in Electric Field

I am working on a problem which looks like this. Consider a charged particle with charge $q$ trapped in a box of length $L$ with finite constant potential $ V_0 $ on both ends. A constant (static) ...
-2
votes
1answer
57 views

Quantum mechanics: Finite square well problem

What will happen if the potential is less than 0, for instance $V(x)=-10eV$. Is this means there will be no bound states? Since solution to the time independent Schrodinger equation (those discrete ...
1
vote
4answers
263 views

Having trouble understanding some stuff about delta functions [closed]

I was going through one of the examples in Griffith's Quantum book and there was a few things in Example 3.3 that I didn't understand that I was hoping to get some clarification on. For instance, we ...
0
votes
1answer
40 views

Two Particle System with Identical Particles

I'm studying for an exam in quantum mechanics and tried to calculate the ground state and the first two excited states of two identical bosons (spin 0) in an infinite one dimensional potential well. ...
1
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3answers
93 views

Variational Theorem proof

I have been trying to prove variational theorem in quantum mechanics for a couple of days but I can't understand the logic behind certain steps. Here is what I have so far: \begin{equation} ...
2
votes
2answers
69 views

Minimum information necessary to represent a pure quantum state

I was thinking about how quantum states are represented for various types of systems, and how the amount of classical information (bits) required to represent a state depends on its basis. Let's take ...
2
votes
1answer
71 views

Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
0
votes
1answer
44 views

Few particle fermion system wavefuction

Suppose I have 3 fermions($\left|\psi_1\right\rangle$, $\left|\psi_2\right\rangle$, $\left|\psi_3\right\rangle$) and a system with 3 states ( $\left|1\right\rangle$, $\left|2\right\rangle$, ...
2
votes
2answers
79 views

Wavefunction of isomers

In quantum chemistry, the wavefunction for a molecule can be viewed as the output of a function $\xi(m, n_1,..., n_k)$ with $m, n_i \in \mathbb{Z}^+$ that returns a $|\psi\rangle$ that satisfies a ...
2
votes
2answers
103 views

Linear vs. quadratic dispersion relation

In wave mechanics the dispersion relation between frequency $\omega$ and wave number $k$ is linear: $$\omega_n=c k_n$$ But in quantum mechanics, based on Schrödinger's equation, one can show that we ...
2
votes
1answer
81 views

Normalization of a wavefunction that's superposition of two unknown energy eigenfunctions

Question:$$\psi(x)=A(3u_1(x)+4u_2(x))$$where $u_1(x)$ and $u_2(x)$ are energy eigenfunctions. How to normalize function $\psi(x)$? My intuitive solution: I got ...
0
votes
1answer
30 views

Introductory Quantum, trouble with this boundary condition and potential

Working on problem 2.40 from Griffiths but can't seem to understand the first boundary condition. We are given the potential $V(x) = \left\{\begin{matrix} \infty & x < 0\\ ...
0
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1answer
42 views

Scattering and bound States

So from my understanding, as long as $E>0$ you will have scattering states and these scattering states will always result in an imaginary $\psi$, but bound states can also have an imaginary ...
2
votes
2answers
119 views

The Delta-Function Potential

I'm reading through Griffiths Intro to QM 2nd Ed. and when it comes to bound/scattering states (2.5) they say: $E<0 \implies$ bound state $E>0 \implies$ scattering state Why doesn't this ...
1
vote
0answers
19 views

Can anyone give me a simple proof for the sign change of electronic wavefunction when taken around a loop containing a conical intersection?

How and why does the sign of the electronic wavefunction changes when it is taken around a contour? For example, suppose the initial wavefunction is $f(s;S_0)$ at nuclear configuration $S_0$ and now ...
-1
votes
0answers
46 views

What does the wavefunction actually show?

I.e. when someone says they've solved the Schrödinger equation for something, or that the equation can be used to show how the wave function develops over time, what do they mean? I know that its to ...
0
votes
2answers
109 views

Particle in a Box: Energy Less than the Potential Energy

I am reading quantum mechanics from Shankar's Principles of Quantum Mechanics. On page 157 he defines the box potential $V(x)$ as $$ V(x) = \left\{ \begin{array}{rl} 0 &\mbox{ if $|x|< L/2$} ...
0
votes
1answer
47 views

How can an electron be fired at a target when uncertainty principle says it will spread out around axis of motion?

Consider an electron fired at a target. Taking the axis of motion to be $x$, and position to be $(x,y,z)$ then $\Delta y = \Delta z = 0$ Therefore by the uncertainty principle $\Delta p_y = ...
2
votes
1answer
122 views

Quantum harmonic oscillator solved by analytic method using Schrödinger equation and wave function

I'm having trouble understanding the recursion formula. Using $\xi \equiv \sqrt{m\omega/\hbar}x$ and $K = 2E/\hbar\omega$, the time-independent Schrödinger equation becomes $$\frac{d^2\psi}{d\xi ^2} ...
15
votes
4answers
663 views

Why do electrons in an atom occupy only the stationary states?

When we talk about the elementary problems in quantum mechanics like particle in a box, we first calculate the energy eigen-function. Then we say that the most general state is the linear combination ...
1
vote
1answer
74 views

Turning a finite difference equation into code (2d Schrodinger equation)

I am trying to convert the following finite difference equations into code (taken from the bottom of page 12 of this thesis by Maike Schulte Numerical Solution of the Schrodinger Equation on Unbounded ...
1
vote
0answers
51 views

Find Equation of Motion given Hamiltonian

So I am given a harmonic oscillator in an electric field. At $t=0$, we are given that the oscillator is in the ground state. The Hamiltonian is: $$H=\hbar \omega[a^{\dagger}a+\frac12+\kappa ...
4
votes
1answer
82 views

Why can we leave off half of the general solution?

In these pdf notes, it says at the bottom of the first page and beginning of the second: [...] whose solution is: $$\Psi(\theta) = c_1 e^{i\omega\theta} + c_2 e^{-i\omega\theta}$$ Since we are ...
0
votes
1answer
56 views

Correct approach for calculating excited states of circular quantum dot under effective mass approximation

From Asnani, Mahajan et al, Pramana Journal Of Physics 73 #3 (2009) p574-580 "Effective mass theory of a two-dimensional quantum dot in the presence of magnetic field", which can be seen here: ...
1
vote
1answer
164 views

Particle Outside the Box

What prohibits, mathematically, that a particle cannot be found outside the box ? Here, I am referring to particle in a box problem (infinite potential on both ends & zero potential along the ...
4
votes
2answers
343 views

Where to place the operator?

I believe it's standard to place the operator in between the conjugate of the wavefunction and the wavefunction itself. For instance, $$\langle p\rangle = \int_{-\infty}^{\infty}\Psi * ...
3
votes
1answer
150 views

Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
2
votes
1answer
143 views

Normalizing wavefunction

If you are trying to normalize $\psi = A\sin kx$, and you find that $|A|^2 = \frac{2}{a}$, why do you take the positive square root and not the negative? What happens if you take the negative square ...
1
vote
1answer
685 views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
5
votes
3answers
99 views

Is the ground state closest to the uncertainty relation? [duplicate]

For simplicity, suppose we are only talking about discrete energy levels, ie, bound state case. The energy levels are $E_1, E_2\cdots$, and the corresponding wave functions are $\psi_1, \psi_2 ...
1
vote
1answer
142 views

Complex Quantum Wave [closed]

Can the complex nature of quantum wave arise from the fact that particle is represented as wave packet in spatial frequency and particle's total energy is represented as wave packet in time frequency? ...
1
vote
1answer
62 views

Degeneracy in One Dimension

I'm reading this wikipedia article and I'm trying to understand the proof under "Degeneracy in One Dimension". Here's what it says: Considering a one-dimensional quantum system in a potential ...
3
votes
2answers
148 views

Infinitely many degeneracy of Landau level: Countable or Uncountable?

Description of Landau levels can be found in many standard textbooks of quantum mechanics and here. Two ubiquitous solutions apply either the symmetric gauge $\vec{A}=(-\frac{1}{2}By,\frac{1}{2}Bx,0)$ ...
5
votes
1answer
100 views

Which position and momentum distributions arise from some wave function?

Consider a particle in one dimension with wave function $\psi(x)$. The probability density function describing how likely it is to find it in a given position is given by ...
5
votes
3answers
388 views

What does the Schrodinger Equation really mean?

I understand that the Schrodinger equation is actually a principle that cannot be proven. But can someone give a plausible foundation for it and give it some physical meaning/interpretation. I guess ...
2
votes
0answers
27 views

How does a photon travel through an electron cloud?

We all know that the exact position and exact velocity of an electron in an atom cannot be determined simultaneously, as per the Heisenberg uncertainty principle. We only talk about the probability of ...
2
votes
1answer
43 views

Why is the full eigen function is product of eigen functions and not addition?

For example suppose there is a two electron system. Why is the full eigen function product of the spatial eigen function and spin wave function for the two electron system?
0
votes
1answer
36 views

Probability to be in a particular state

If I have a wavefunction $\psi = \sum_{n=0}^{\infty} a_n e^{i \phi_n} | n \rangle$ and $(|n \rangle)$ is a set of orthonormal functions. Is it correct that the probability to be in a state $|k\rangle ...
4
votes
1answer
325 views

Am I missing a trick to solving this differential equation?

I was playing around with a 3-D potential $V$ such that $V_{(r)} = 0$ for $r<a$, and $V_{(r)} = V_0$ otherwise. By using the Schrödinger Equation, I showed that: ...
4
votes
2answers
151 views

What is the physical reason behind linearity of Schrodinger's equation?

What is the physical reason for Schrodinger equation to be linear? Though in physics many interactions or dynamics are found non linear.
1
vote
1answer
70 views

Different mathematical methods in quantum mechanics?

My understanding is that in quantum mechanics the wavefunction may be expressed as a function or as a ket vector (composed of many orthogonal ket vectors). I'm not too sure about the further ...
0
votes
0answers
40 views

Question about Hartle and Hawking's universal wavefunction?

My apologies in advance if this question is poorly worded or doesn't make any sense, however I have just finished reading into this theory and it seems as though Hawkings No Boundary Universe is ...
2
votes
3answers
63 views

Koopmann von Neumann (KvN) Theory

I was just wondering does anyone have any informative sources apart from the obvious wikipedia articles regarding Koopmann von Neumann (KvN) theory? Or if its possible could someone explain the basic ...
0
votes
3answers
59 views

What does “coherent wave function of a macroscopic body” mean?

What is meant by the "coherent wave function of a macroscopic body"? I found this phrase in a paper on QM, but am unfamiliar with the terminology.