The quantum mechanical time evolution operator governs how observables and/or states evolve during finite time steps, and is always unitary. Use this tag for questions about the time evolution operator, or the different equations of motion in the Schrödinger/Heisenberg/Dirac pictures. For ...

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Who is doing the normalization of wave function in the time evolution of wave function?

In the Schrodinger equation, at any given time $t$ we should jointly add another sub equation, like $$||\psi_t(x)|| = 1$$ where $\psi_t(x) = \Psi(x,t)$, and then try to solve the two equations ...
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What does a unitary transformation mean in the context of an evolution equation?

Let be the unitary evolution operator of a quantum system be $U(t)=\exp(itH)$ for $t >0$. Then what is the meaning of the equation $$\det\bigl(I-U(t)e^{itE}\bigr)=0$$ where $E$ is a real ...
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Evolution operator for time-dependent Hamiltonian

When I studied QM I'm only working with time independent Hamiltonians. In this case the unitary evolution operator has the form $$\hat{U}=e^{-\frac{i}{\hbar}Ht}$$ that follows from this equation $$ ...
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Heisenberg picture of QM as a result of Hamilton formalism

Consider the formula for the total time-derivative of a physical value in Poisson's formalism: $$\tag{1} \frac{dA}{dt} = -\{H, A\}_{P.B.} + \frac{\partial A}{\partial t}, $$ where $\{A, B\}_{P.B.}$ is ...
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Time evolution in quantum mechanics

We know that an operator A in quantum mechanics has time evolution given by Heisenberg equation: $$ \frac{i}{\hbar}[H,A]+\frac{\partial A}{\partial t}=\frac{d A}{d t} $$ Can we derive from this ...
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Which Schrödinger equation is correct?

In the coordinate representation, in 1D, the wave function depends on space and time, $\Psi(x,t)$, accordingly the time dependent Schrödinger equation is $$H\Psi(x,t) = ...
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Which derivative with respect to time is which in the Heisenberg picture of quantum mechanics?

For an observable $A$ and a Hamiltonian $H$, Wikipedia gives the time evolution equation for $A(t) = e^{iHt/\hbar} A e^{-iHt/\hbar}$ in the Heisenberg picture as $$\frac{d}{dt} A(t) = \frac{i}{\hbar} ...
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Is it possible to derive Schrodinger equation in this way?

Let's have wave-function $\lvert \psi \rangle$. The full probability is equal to one: $$\langle \Psi\lvert\Psi \rangle = 1.\tag{1}$$ We need to introduce time evolution of $\Psi $; we know it in ...
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Does Heisenberg equation of motion imply the Schrodinger equation for evolution operator?

Let us choose to postulate (e.g. considering the analogy of the Hamiltonian being a generator of time evolution in classical mechanics) $$ i\hbar \frac{d\hat{U}}{dt}=\hat{H}\hat{U}\tag{1} $$ where ...
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Does Peskin & Schroeder Eq. (4.26), $U(t_1,t_2)U(t_2,t_3) = U(t_1,t_3)$ imply $[H_0,H_{int}] = 0$?

Peskin & Schroeder equation (4.17) define the operator, \begin{equation} U(t,t_{0})~=~e^{i(t-t_{0})H_{0}}e^{-i(t-t_{0})H} \tag{4.17} \end{equation} where $$H~=~H_0+H_{\text{int}}\tag{4.12}$$ is ...
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Find Equation of Motion given Hamiltonian

So I am given a harmonic oscillator in an electric field. At $t=0$, we are given that the oscillator is in the ground state. The Hamiltonian is: $$H=\hbar \omega[a^{\dagger}a+\frac12+\kappa ...
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How to find the time evolution for two-component spinor? [closed]

I would like to find the time evolution for the given Hamiltonian, the initial state of the system we choose two spinor wavefunction $\psi_{+}(t=0)$ and $\psi_{-}(t=0)$ as given below: The effective ...
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Solving the Schrödinger equation where the initial wave function is an energy eigenfunction

I was watching Allan Adams' lecture on energy eigenfunctions, and there's one part (around 43 minutes into the lecture) that confuses me. Suppose we have the initial wave function $\Psi (x,0)$ such ...
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Why is time evolution unitary

Is the reason why the time evolution operator is unitary based on purely physical arguments, i.e. that the physical processes that an isolated system undergoes shouldn't depend on any particular ...
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Unitary evolution operator

Assume we have a system in a state $\psi$ that is a superposition of eigenvectors of some observable $A$. Now we make a measurement of the observable $A$; the state after the measurement $\phi$ is a ...