The quantum mechanical time evolution operator governs how observables and/or states evolve during finite time steps, and is always unitary. Use this tag for questions about the time evolution operator, or the different equations of motion in the Schrödinger/Heisenberg/Dirac pictures. For time-...

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The formal solution of the Schrödinger equation

Consider the Schrödinger equation (or some equation in Schrödinger form) written down as $$ \tag 1 i \partial_{0} \Psi ~=~ \hat{ H}~ \Psi . $$ Usually, one likes to write that it has a formal solution ...
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3answers
994 views

Who is doing the normalization of wave function in the time evolution of wave function?

In the Schrodinger equation, at any given time $t$ we should jointly add another sub equation, like $$||\psi_t(x)|| = 1$$ where $\psi_t(x) = \Psi(x,t)$, and then try to solve the two equations ...
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1answer
8k views

Evolution operator for time-dependent Hamiltonian

When I studied QM I'm only working with time independent Hamiltonians. In this case the unitary evolution operator has the form $$\hat{U}=e^{-\frac{i}{\hbar}Ht}$$ that follows from this equation $$ i\...
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6answers
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Why does time evolution operator have the form $U(t) = e^{-itH}$?

Let's denote by $|\psi(t)\rangle$ some wavefunction at time $t$. Then let's define the time evolution operator $U(t_1,t_2)$ through $$ U(t_2,t_1) |\psi(t_1)\rangle = |\psi(t_2)\rangle \tag{1}$$ and ...
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6answers
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What does a unitary transformation mean in the context of an evolution equation?

Let be the unitary evolution operator of a quantum system be $U(t)=\exp(itH)$ for $t >0$. Then what is the meaning of the equation $$\det\bigl(I-U(t)e^{itE}\bigr)=0$$ where $E$ is a real ...
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2answers
586 views

Heisenberg picture of QM as a result of Hamilton formalism

Consider the formula for the total time-derivative of a physical value in Poisson's formalism: $$\tag{1} \frac{dA}{dt} = -\{H, A\}_{P.B.} + \frac{\partial A}{\partial t}, $$ where $\{A, B\}_{P.B.}$ is ...
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5answers
864 views

State collapse in the Heisenberg picture

I've been studying quantum mechanics and quantum field theory for a few years now and one question continues to bother me. The Schrödinger picture allows for an evolving state, which evolves through ...
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4answers
2k views

Which derivative with respect to time is which in the Heisenberg picture of quantum mechanics?

For an observable $A$ and a Hamiltonian $H$, Wikipedia gives the time evolution equation for $A(t) = e^{iHt/\hbar} A e^{-iHt/\hbar}$ in the Heisenberg picture as $$\frac{d}{dt} A(t) = \frac{i}{\hbar} ...
3
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1answer
734 views

Time evolution in quantum mechanics

We know that an operator A in quantum mechanics has time evolution given by Heisenberg equation: $$ \frac{i}{\hbar}[H,A]+\frac{\partial A}{\partial t}=\frac{d A}{d t} $$ Can we derive from this ...
10
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1answer
655 views

Is it possible to derive Schrodinger equation in this way?

Let's have wave-function $\lvert \psi \rangle$. The full probability is equal to one: $$\langle \Psi\lvert\Psi \rangle = 1.\tag{1}$$ We need to introduce time evolution of $\Psi $; we know it in ...
12
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1answer
441 views

How do I enforce the no-slip boundary condition in time dependent incompressible pipe flow?

This is a technical problem which must have been solved already. It won't be in beginners textbooks but there should be a solution somewhere. I welcome reading suggestions. Maybe someone with ...
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2answers
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Extending the ergodic theorem to non-equilibrium systems

I try to make this as short and concise as possible. For equilibrium systems in statistical mechanics, we have the Liouville's theorem which says that the volume in phase space is conserved when the ...
8
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4answers
876 views

Does Heisenberg equation of motion imply the Schrodinger equation for evolution operator?

Let us choose to postulate (e.g. considering the analogy of the Hamiltonian being a generator of time evolution in classical mechanics) $$ i\hbar \frac{d\hat{U}}{dt}=\hat{H}\hat{U}\tag{1} $$ where $\...
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2answers
2k views

Why is time evolution unitary?

Is the reason why the time evolution operator is unitary based on purely physical arguments, i.e. that the physical processes that an isolated system undergoes shouldn't depend on any particular ...
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3answers
208 views

Does Peskin & Schroeder Eq. (4.26), $U(t_1,t_2)U(t_2,t_3) = U(t_1,t_3)$ imply $[H_0,H_{int}] = 0$?

Peskin & Schroeder equation (4.17) define the operator, \begin{equation} U(t,t_{0})~=~e^{i(t-t_{0})H_{0}}e^{-i(t-t_{0})H} \tag{4.17} \end{equation} where $$H~=~H_0+H_{\text{int}}\tag{4.12}$$ is ...
2
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2answers
640 views

The equivalence between Heisenberg and Schroedinger pictures

In quantum mechanics, the two pictures of Schroedinger and Heisenberg are taken as equivalent, where in the former wavefunctions are time variants and operators are not, and in the latter it is the ...
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1answer
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How/Why did Feynman relate the element of Hamiltonian matrix $H_{12}$ to the amplitude to go from $|1\rangle$ to $| 2\rangle$?

$$ \newcommand{\bk}[2]{\left\langle #1 | #2 \right\rangle} \newcommand{\ket}[1]{\left| #1 \right\rangle} \newcommand{\bra}[1]{\left\langle #1 \right|} \newcommand{\biik}[3]{\left\langle #1 | #2| #3\...
3
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2answers
146 views

Time evolution of a wavepacket

I do not understand why if $H\psi = E\psi$, then the time-evolution of the wavefunction is given by $e^{-iEt/h}\psi(x)$.
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1answer
413 views

How to find the time evolution for two-component spinor? [closed]

I would like to find the time evolution for the given Hamiltonian, the initial state of the system we choose two spinor wavefunction $\psi_{+}(t=0)$ and $\psi_{-}(t=0)$ as given below: The effective ...
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3answers
452 views

Is the superposition of stationary states a stationary state? If not, then why not?

I am a beginner in Quantum mechanics and as I understand,the superposition of stationary states is also a solution of time-independent Schrödinger equation (TISE). The wave functions that are the ...