The quantum mechanical time evolution operator governs how observables and/or states evolve during finite time steps, and is always unitary. Use this tag for questions about the time evolution operator, or the different equations of motion in the Schrödinger/Heisenberg/Dirac pictures. For ...

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Time evolution of expectation value of an operator

I'm studying QM from Sakurai, and I have a doubt regarding the proof given that in the case of time independent Hamiltonian the expectation value of an observable doesn't change with time. The ...
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The curious case of the time derivative of the expectation value of the position

Having defined the expectation value of position as follows $$ \langle x \rangle = \int x {\lvert\Psi(x,t)\rvert}^2dx $$ The time derivative of the expectation value is derived in my literature in ...
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What is time evolution operator?

Could you explain to me (level 1 years undergrade) what is a time evolution operator? I read on Wikipedia, and it confuses me.
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Effective theories and unbounded operators

If you have two operators, one the true Hamiltonian $H$ and one we call an effective Hamiltonian $H_{eff}$ and say they agree on every eigenvector with eigenvalue up to $E_{eff}.$ Above that, they can ...
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Time-ordering and Dyson series

In Dyson series we use a time-ordered exponential by arguing that a Hamiltonian at two different instants of time does not commute. Why is it that so? Can anyone explain with example why should the ...
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Evolution of a 'state' in the Heisenberg picture

Suppose that we have a Hamiltonian, $\hat{H}$, and an operator $\hat{A}$ which satisfies the Heisenberg equation$^{[a]}$ $$i \frac{d}{dt} \hat{A} = [\hat{A},\hat{H}].$$ Can we create a 'state' by ...
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How can a solution of the time-independent Schrödinger equation evolve in space?

I understand that if the Hamiltonian does not depend on the time, the Schrödinger Equation becomes separable, so you get $$ H \psi(x) = E \psi(x) $$ and $$ \Psi(x,t) = ...
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Lindblad equation solution

I have been trying to solve a Lindblad Equation and then thought about whether there is a closed form Lindblad Equation solution for most types. Googling hasn't lead me to anything useful. So, is ...
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Why does Hamiltonian follow the property $H^*_{ij} = H_{ji} $?

I was reading Feynman's Lectures III's Hamiltonian Matrix. There I found this property of Hamiltonian Matrix: The Hamiltonian has one property that can be deduced right away, namely, that ...
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Why does time evolution operator have the form $U(t) = e^{-itH}$?

Let's denote by $|\psi(t)\rangle$ some wavefunction at time $t$. Then let's define the time evolution operator $U(t_1,t_2)$ through $$ U(t_2,t_1) |\psi(t_1)\rangle = |\psi(t_2)\rangle \tag{1}$$ and ...
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How to get Heisenberg Equation of Motion?

If a system Hamiltonian is given by, $$ ...
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Time evolution of scalar field

Consider the quantized real scalar field acting on the vacuum state $\vert 0 \rangle $. We can interpret the state $\phi(\textbf{x})\vert 0 \rangle $ (defined in the Schrodinger picture at $t=0$) as a ...
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Entropy change in Heisenberg picture

If we stick with Heisenberg picture where density matrix $\rho$ is constant, how do we account for entropy increase? I've read the answer to State collapse in the Heisenberg picture but I don't see ...
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Constructing solutions to the time-dependent Schrödinger's equation

The following question is from David Griffiths' Introduction to Quantum Mechanics: Problem 2.13 A particle in the harmonic oscillator potential starts out in the state $$\Psi(x,0) = A[3 ...
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Does measurement change the evolution of wave function?

Basically any measurement is on wave function $|\psi\rangle$ is done by operator $X$ such that $X|\psi\rangle$ results observable $x$ with some probability. But what happens to $|\psi\rangle$? Does ...
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94 views

Field expansion in Peskin & Schroeder

Peskin and Schroeder state something which I'm not fully understanding. More specificially I think it's just phrased in a way I'm not understanding. In the Schrodinger picture we can expand the real ...
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A trace formula of two noncommutative operators

In many cases of quantum many-body problems, the Hamiltonian $H$ can always be divided into two parts, i.e. $H_0$ and $H'$. In this occasion, one can systemically calculate the partition function ...
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Time evolution of a classical system

For a harmonic oscillator the Liouville operator is given by $$L = p \partial_q- q \partial_p.$$ Now I have a phase space distribution $f(t,q,p)$ for which it holds (in general) $$f(t+\tau,q,p)= ...
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Time evolution of a wavepacket

I do not understand why if $H\psi = E\psi$, then the time-evolution of the wavefunction is given by $e^{-iEt/h}\psi(x)$.
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Does the time Evolution operator commute with the both free and interaction Hamiltonian?

Consider a quantum system (finite dimensional) which has overall Hamiltonian: $H_s = H_0 + w(s)H_c$ with $H_0, H_c$ constant in time and traceless and $w(t)$ a, not too badly behaved, function of ...
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61 views

Kraus operators + path integrals = Lindblad equation?

The other day our professor was talking about Kraus representation of density operator and the derivation of Lindblad equation. He told that this was related to the Feynman path integrals and that we ...
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Time Evolution of Position Operator

I am trying to understand why $$e^{-it\triangle}xe^{it\triangle}=x-2it\nabla$$ where $x$ is just multiplication operator by $x$. In particular, the text says this can be seen by differentiating with ...
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Time evolution of interaction Hamiltonian in the Heisenberg picture

How does the interaction Hamiltonian of a (finite dim) quantum system with Hamiltonian: $H(t) = H_0 + w(t) H_I$ evolve in time in the Heisenberg picture. Is there anything special about the way ...
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Why is probabilty conserved under time evolution of a system in quantum mechanics?

I've studied quantum mechanics to a certain degree, but one question that I've never been able to get a fully satisfactory answer to is why probability is conserved (by this I mean that it has either ...
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Unitary evolution operator

Assume we have a system in a state $\psi$ that is a superposition of eigenvectors of some observable $A$. Now we make a measurement of the observable $A$; the state after the measurement $\phi$ is a ...
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How to do time evolution of operators in the Heisenberg Picture while staying in the Heisenberg Picture

Consider the time evolution of an operator in the Heisenberg picture: $$\tag{1}i\hbar \frac{d}{d t} \hat{A}_{H}(t) = \left([ \hat{A}_S(t), \hat H_S (t)] + i\hbar \frac{d}{d t} \hat{A}_S(t) ...
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Does Peskin & Schroeder Eq. (4.26), $U(t_1,t_2)U(t_2,t_3) = U(t_1,t_3)$ imply $[H_0,H_{int}] = 0$?

Peskin & Schroeder equation (4.17) define the operator, \begin{equation} U(t,t_{0})~=~e^{i(t-t_{0})H_{0}}e^{-i(t-t_{0})H} \tag{4.17} \end{equation} where $$H~=~H_0+H_{\text{int}}\tag{4.12}$$ is ...
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Why does the density matrix $\rho$ obey a wrong-signed Heisenberg equation of motion?

The density matrix is defined as $$ \rho_\psi ~:=~ \frac{\lvert\psi(t)\rangle \langle \psi(t)\vert}{ \langle \psi(t) |\psi(t)\rangle }$$ in the Schrödinger picture. $\rho_\psi$ is obviously a time ...
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64 views

Commuting with time evolution operator implies commuting with Hamiltonian

Consider a quantum system (finite dimensional) has overall Hamiltonian: $H_t = H_0 + w(t)H_c$ with $H_0, H_c$ constant in time and traceless and $w(t)$ a, not too badly behaved, function of time. ...
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2answers
216 views

The equivalence between Heisenberg and Schroedinger pictures

In quantum mechanics, the two pictures of Schroedinger and Heisenberg are taken as equivalent, where in the former wavefunctions are time variants and operators are not, and in the latter it is the ...
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367 views

How to find the time evolution for two-component spinor? [closed]

I would like to find the time evolution for the given Hamiltonian, the initial state of the system we choose two spinor wavefunction $\psi_{+}(t=0)$ and $\psi_{-}(t=0)$ as given below: The effective ...
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Why isn't the Time-Independent Schrödinger Equation an equation of motion?

I thought an equation of motion was something where you are given a Lagrangian and, using the Euler-Lagrange equation, you then find the equations of motion for that system. Same basic idea for the ...
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How to solve the inverse square law equation of motion

From $$m\boldsymbol{\ddot{r}}=\boldsymbol{\hat{r}} f(r)$$ I can get $$r''-r \theta '^2=-\frac{k}{m r^2}$$ $$2 r' \theta '+r \theta ''=0$$ Now it seems that all the books tells me the method to solve ...
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Why is time evolution unitary

Is the reason why the time evolution operator is unitary based on purely physical arguments, i.e. that the physical processes that an isolated system undergoes shouldn't depend on any particular ...
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Why does $tr \ e^{-\frac{i}{h}\hat{H}t}= \int d^nr \left< \textbf{r}| e^{-\frac{i}{h}\hat{H}t} | \textbf{r} \right>$ hold?

I would like to consider the trace of the time evolution operator $e^{-\frac{i}{\hbar}\hat{H}t}$ Apparently in single-particle quantum mechanics is can be represented as $$ tr \ ...
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Can the chance of finding a particle diminish over time?

Let's assume we have a wave function described by a wave equation and it is a function of space and time $\psi : \mathbb{R}^4 \rightarrow \mathbb{C}$. This function needs to be normalized, so if I ...
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Why $E=mc^2$ formula does not include time?

For $E=mc^2$ formula, if an object of mass $m$ kg goes with speed of light (in theory), it transforms energy according to $E=mc^2$ but if there is no time complexity this will not happen. So I think ...
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About imaginary time evolution method

When I try to work out the ground state of a system, there is a method making use of imaginary time and splitting operators, I wan to know, when the ground state is fine and satisfying for my purpose? ...
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Who is doing the normalization of wave function in the time evolution of wave function?

In the Schrodinger equation, at any given time $t$ we should jointly add another sub equation, like $$||\psi_t(x)|| = 1$$ where $\psi_t(x) = \Psi(x,t)$, and then try to solve the two equations ...
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Boltzmann equation (Number density)

I'm trying to understand the Boltzmann equations use in the early Universe. The derivation is somewhat tedious, but in the end I end up with: $$a^{-3}\frac{d}{dt}\left(n_1a^3\right) = ...
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Why discrepancies in the Schrödinger equation? [duplicate]

Why is there seemingly two definitions of the Schrödinger equation? \begin{equation} i\hbar\frac{\partial}{\partial t}\Psi=\hat H\Psi. \end{equation} And \begin{equation} i\hbar ...
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124 views

What is the most agreed upon quantum mechanical equation of motion?

On multiple Wikipedia articles, it mentions several quantum mechanical equations of motion, namely those by Schrödinger and Heisenberg. Which one is the most accurate and agreed upon quantum ...
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147 views

Why is time evolution of wavefunctions non-trivial?

(Note: This post focuses on a single simple example, however I'm asking about the error in general in my logic). Consider the infinite potential well "particle in a box" system described by ...
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128 views

What really generates time evolution?

A fundamental principle of quantum mechanics, as far as I can tell, states that the Hamiltonian generates time evolution. A common result about generators are the following: let $\mathrm T$ be the ...
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Find Equation of Motion given Hamiltonian

So I am given a harmonic oscillator in an electric field. At $t=0$, we are given that the oscillator is in the ground state. The Hamiltonian is: $$H=\hbar \omega[a^{\dagger}a+\frac12+\kappa ...
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144 views

Time evolution of a quantum system

A quantum system has Hamiltonian $H$ with normalised eigenstates $\psi_n$ and corresponding energies $E_n$ ($n = 1,2,3...$). A linear operator $Q$ is defined by its action on these states: $$ ...
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What exactly does the Hamiltonian operator tell us?

I'm confused about how energy and time are linked. On the one hand, the Hamiltonian seems to describe the time evolution of the system because in the time dependent Schrodinger equation, $$ \hat H ...
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Creation and Annihilation Operators

Let $\widehat{a}^{+}_{i}$ and $\widehat{a}_{i}$ be the usual bosonic creation and annihilation operators. Consider $$\widehat{q}_{i} = \sqrt{\frac{\hbar}{2m_{i}w_{i}}}(\widehat{a}_{i}+ ...
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How do I enforce the no-slip boundary condition in time dependent incompressible pipe flow?

This is a technical problem which must have been solved already. It won't be in beginners textbooks but there should be a solution somewhere. I welcome reading suggestions. Maybe someone with ...
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370 views

How to get the time derivative of an expectation value in quantum mechanics?

The textbook computes the time derivative of an expectation value as follows: $$\frac{d}{dt}\langle Q\rangle=\frac{d}{dt}\langle \Psi|\hat Q\Psi\rangle=\langle \frac{\partial\Psi}{\partial t}|\hat ...