Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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160
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19answers
55k views

Cooling a cup of coffee with help of a spoon

During the breakfast with my colleagues, a question popped into my head: What is the fastest method to cool a cup of coffee, if your only available instrument is a spoon? A qualitative answer would ...
47
votes
14answers
69k views

How Does Mass Leave the Body When you Lose Weight?

When your body burns calories and you lose weight, obviously mass is leaving your body. In what form does it leave? In other words, what is the physical process by which the body loses weight when ...
28
votes
1answer
158 views

$(\mu,P,T)$ pseudo-ensemble: why is it not a proper thermodynamic ensemble?

While teaching statistical mechanics, and describing the common thermodynamic ensembles (microcanonical, canonical, grand canonical), I usually give a line on why there can be no $(\mu, P, T)$ ...
25
votes
1answer
935 views

Rubber band stretched produces heat and when released absorbs heat.. Why?

I always used to wonder why this happens.. when one stretches a rubberband to nearly it snapping point holding it close to your skin - preferably cheek(helps feel the heat), it emits heat. While ...
23
votes
8answers
8k views

Will a hole cut into a metal disk expand or shrink when the disc is heated?

Suppose you take a metal disc and cut a small, circular hole in the center. When you heat the whole thing, will the hole's diameter increase or decrease? and why?
22
votes
6answers
2k views

How do whisky stones keep your drink cold?

From a discussion in the DMZ (security stack exchange's chat room - a place where food and drink are important topics) we began to question the difference between how ice and whisky stones work to ...
21
votes
1answer
689 views

Energy in bolognese reduction - lid on or off?

Generally, to let my bolognese thicken, I leave the lid off in order to "let water vapor escape." I am however distracted from enjoying the taste because I'm having doubts that my physical reasoning ...
19
votes
3answers
126 views

Does entropy measure extractable work?

Entropy has two definitions, which come from two different branches of science: thermodynamics and information theory. Yet, they both are thought to agree. Is it true? Entropy, as seen from ...
16
votes
6answers
1k views

Why isn't temperature measured in Joules?

If we set the Boltzmann constant to $1$, then entropy would just be $\ln \Omega$, temperature would be measured in $\text{joules}$ ($\,\text{J}\,$), and average kinetic energy would be an integer ...
15
votes
2answers
304 views

Why are expressions such as $\operatorname{ln}T$ used in thermodynamics where $T$ is not dimensionless?

In all thermodynamics texts that I have seen, expressions such as $\operatorname{ln}T$ and $\operatorname{ln}S$ are used, where $T$ is temperature and $S$ is entropy, and also with other thermodynamic ...
15
votes
7answers
603 views

How is $\frac{dQ}{T}$ measure of randomness of system?

I am studying entropy and its hard for me to catch up what exactly is entropy. Many articles and books write that entropy is the measure of randomness or disorder of the system. They say when a gas ...
14
votes
2answers
823 views

Is this Landau's other critical phenomena mistake?

There was an old argument by Landau that while the liquid gas transition can have a critical point, the solid-liquid transition cannot. This argument says that the solid breaks translational symmetry, ...
13
votes
6answers
1k views

What exactly is heat?

Is it energy? Is it energy per unit volume? Is it energy per unit time i.e power? What is it?
13
votes
3answers
1k views

Home experiment to estimate Avogadro's number?

How to get an approximation of Avogadro or Boltzmann constant through experimental means accessible by an hobbyist ?
13
votes
2answers
266 views

Why aren't gas planets and stars fuzzy?

The edge of Jupiter looks very sharp. Even more bothersome, the edge of the sun looks sharp, aside from kind of a soup of particles floating above it. The sun's surface has an incredibly low ...
13
votes
2answers
3k views

Ice skating, how does it really work?

Okay, some textbooks I came across, and a homework assignment I had to do several years ago, suggested that the reason we can skate on ice is the peculiar $p(T)$-curve of the ice-water boundary. The ...
13
votes
4answers
860 views

Entropy of radiation emitted into space

In several papers I see something equivalent to the following expression for the entropy of radiation given by an astronomical object such as the Sun (assuming the object can be approximated as a ...
12
votes
6answers
864 views

Does an empty refrigerator require more power to stay cold than a full one?

Given that everything else is equal (model of fridge, temperature settings, external temperature, altitude), over a given duration of having the door closed, does it require more electricity to cool ...
12
votes
3answers
1k views

How do you prove $S=-\sum p\ln p$?

How does one prove the formula for entropy $S=-\sum p\ln p$? Obviously systems on the microscopic level are fully determined by the microscopic equations of motion. So if you want to introduce a law ...
12
votes
4answers
799 views

How slow is a reversible adiabatic expansion of an ideal gas?

A truly reversible thermodynamic process needs to be infinitesimally displaced from equilibrium at all times and therefore takes infinite time to complete. However, if I execute the process slowly, I ...
12
votes
6answers
661 views

How can it be that the beginning universe had a high temperature and a low entropy at the same time?

The Big Bang theory assumes that our universe started from a very/infinitely dense and extremely/infinitely hot state. But on the other side, it is often claimed that our universe must have been ...
11
votes
3answers
464 views

Light “diode” and 2nd law of thermodynamics

If I had a light "diode" - an object that only allowed light (at least for a range of frequencies) to travel through it in one direction, would this necessarily allow violations of the 2nd Law of ...
11
votes
3answers
863 views

Prove that negative absolute temperatures are actually hotter than positive absolute temperatures

Could someone provide me with a mathematical proof of why, a system with an absolute negative Kelvin temperature (such that of a spin system) is hotter than any system with a positive temperature (in ...
11
votes
6answers
602 views

What are the various physical mechanisms for energy transfer to the photon during blackbody emission?

By conservation of energy, the solid is left in a lower energy state following emission of a photon. Clearly absorption and emission balance at thermal equilibrium, however, thermodynamic equilibrium ...
11
votes
5answers
437 views

Why isn't temperature measured in units of energy?

Temperature is the average of the kinetic energies of all molecules of a body. Then, why do we consider it a different fundamental physical quantity altogether [K], and not an alternate form of ...
11
votes
5answers
674 views

Why does the nature always prefer low energy and maximum entropy?

Why does the nature always prefer low energy and maximum entropy? I've just learned electrostatics and I still have no idea why like charges repel each other. ...
11
votes
3answers
895 views

A water drop in vacuum

Let's imagine the following situation: At an initial moment $t=0$, a large water drop with diameter for example $D=10\ \text{cm}$ is placed in deep space (Say an astronaut is experimenting). Let's ...
11
votes
6answers
761 views

Do all massive bodies emit Hawking radiation?

It is known that any accelerated observer is subject to a heat bath due to Unruh radiation. The principle of equivalence suggests that any stationary observer on the surface of a massive body should ...
11
votes
2answers
334 views

The entropic cost of tying knots in polymers

Imagine I take a polymer like polyethylene, of length $L$ with some number of Kuhn lengths $N$, and I tie into into a trefoil knot. What is the difference in entropy between this knotted polymer and ...
11
votes
1answer
566 views

Mechanics + Thermodynamics: Bouncing Ball

In preparation for an exam, I'm revisiting old exam questions. This one seems neat, but also quite complicated: A soccer ball with Radius $R=11cm$ is inflated at a pressure of $P =9 \times 10^4 ...
10
votes
3answers
223 views

The notion of an adiabatic process in thermodynamics -vs- quantum mechanics

I'm confused about the terminology in the two contexts since I can't figure out if they have a similar motivation. Afaik, the definitions state that quantum processes should be very slow to be called ...
10
votes
4answers
5k views

Why does adding solutes to pure water lower the the specific heat?

We found that water with salt, sugar, or baking soda dissolved in it cools faster than pure water. Water has a very high specific heat; how do these solutes lower it? We heated a beaker (300ml) of ...
10
votes
4answers
318 views

Discontinuities and nondifferentiability in thermodynamics

In physics and engineering sources, calculus-based formalisms - whether differential forms on a manifold, or "differentials" of functions of several variables - are presented as a way of modeling and ...
10
votes
1answer
146 views

A formal procedure for thermodynamic relations

This is my third time taking a thermodynamics course (two in undergrad, one in grad), and I've finally become frustrated enough about something to post on here. A lot of thermodynamic questions want ...
9
votes
4answers
2k views

Difference between thermodynamics and statistical mechanics

I've just finished a class a few weeks ago which taught thermo and stat mech, and I still don't know the exact difference between the two. Can someone help clear this up for me? (Yeah it's sad, and ...
9
votes
3answers
472 views

Why does large curvature of spacetime imply high temperature?

I`ve just stumbled about a sentence which says that high curvature of spacetime implies that any matter present is at high temperature. This somehow confuses me, so my probably dumb question(s) are: ...
9
votes
6answers
4k views

Does hot air really rise?

"Heat rises" is a widely-used phrase (and widely-accepted phenomenon). Does hot air really rise? Or is it simply displaced by colder (denser) air pulled down by gravity?
9
votes
3answers
2k views

Physical meaning of Legendre transformation

I would like to know the physical meaning of the Legendre transformation, if there is any? I've used it in thermodynamics and mechanics and it seemed only a change of coordinates? Thanks.
9
votes
3answers
1k views

Is there any proof for the 2nd law of thermodynamics?

Are there any analytical proofs for the 2nd law of thermodynamics? Or is it based entirely on empirical evidence?
9
votes
2answers
263 views

Is thermal noise “quantum random”?

Is the randomness that can be extracted from thermal noise "as random" (that is, even theoretically inaccessible to measurement according to our knowledge of quantum mechanics, and not just random for ...
9
votes
1answer
392 views

Second Law of Black Hole Thermodynamics

I've been looking for a satisfying proof of this, and can't quite find it. I read the brief proof of the black hole area theorem in Wald, which is similar, but doesn't quite come down to the actual ...
9
votes
2answers
613 views

What's the difference between different speeds of sound?

In astrophysics, I often come across the speed of sound. I understand that, broadly, it represents the speed at which perturbations travel through a medium. But there's more than one speed of sound. ...
9
votes
1answer
330 views

Energy from man-made tornadoes

Peter Thiel just paid $300,000 to Canadian inventor Louis Michaud who is working to construct useful "man-made tornadoes" or "atmospheric vortex engines" which could be components of future power ...
9
votes
1answer
120 views

Is the liquid/solid line infinite?

Starting from the triple point, is the melting line between solid-phase and liquid-phase infinite? If not, why does it end? Because pressures are so high that classical inter-molecular interactions ...
9
votes
3answers
1k views

Thermodynamics of supercooled water

Now that it's been freezing outside for the last few days, I experimented a bit with supercooling. I've left a bottle of clean water outside for a few hours, and behold, when I shook the bottle, the ...
9
votes
1answer
284 views

Is almost all entropy in our universe entanglement entropy?

Our observable universe, or a subregion of our universe many times larger than the observable universe, originated from inflating from a very tiny inflationary patch. Being so small, the initial ...
8
votes
5answers
2k views

If I take a bottle of air into space, and open it, where does it go?

It seems to me that space doesn't have any/much air, and if my bottle is full of air, when I open it, where does the air go?
8
votes
4answers
4k views

How efficient is an electric heater?

How efficient is an electric heater? My guess: greater than 95%. Possibly even 99%. I say this because most energy is converted into heat; some is converted into light and kinetic energy, and ...
8
votes
3answers
526 views

How hot is the water in the pot?

Question: How hot is the water in the pot? More precisely speaking, how can I get a temperature of the water as a function of time a priori? Background & My attempt: Recently I started spend ...
8
votes
3answers
753 views

How efficient is a desktop computer?

As I understand it (and admittedly it's a weak grasp), a computer processes information irreversibly (AND gates, for example), and therefore has some minimum entropy increase associated with its ...

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