Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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What are the contributions of the Non-equilibrium Thermodynamics?

I am very interested in Thermodynamics, but though it is easy to find good books and information about classical thermo, it seems that is not the same for non-equilibrium thermodynamics. I would like ...
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2answers
76 views

Why is everything colder nowadays?

I know that when the universe began it was incredibly hot. Ever since, it is been cooling, and nowadays the average temperature of the universe is quite close to 0 K. Is this a consequence of having ...
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2answers
83 views

Is the second law of Thermodynamics an immense tautology?

Let's imagine for a second a system that is changing constantly from one microstate to another one. It could be a given volume of a gas with its atoms moving and bouncing around, or a deck of cards ...
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22 views

Ice and liquid water interacting across a boundary

Imagine we have two thermodynamic systems, one a mass of ice and the other an equal mass of liquid water, with both at 273.16K. Each system is isolated, except that they can interact with each other ...
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22 views

The relation between energy quanta of an Einstein solid and the equipartition value of heat capacity

Consider an Einstein solid with quantized energy values $U=q\epsilon$ and $N$ oscillators. I calculated some values of an Einstein solid numerically through a function in R (at the bottom of the ...
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143 views

Is there a true parallel between Gibbs' phase rule and Euler's polyhedral formula?

Gibbs' phase rule states: $$F=C-P+2$$ where $F$ is number of degrees of freedom, $C$ is number of components, $P$ is number of phases. Euler's polyhedral formula states: $$V+F-E=2$$ where $V$ is ...
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86 views

Axioms behind entropy!

The concept of entropy is very ubiquitous, we learn about its uses starting from Information Theory (Shannon entropy) up to its basic definition in statistical mechanics in terms of number of ...
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496 views

Carnot efficiency, coefficient of performance for a refrigerator

I was reading that a new type of refrigerator might reach a coefficient of performance (COP) of 10. This seems quite the achievement and the authors state that their approach might achieve a Carnot ...
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15 views

Third principle of Nernst [duplicate]

I wonder how can I prove the fulfillment of the third principle of Nernst of a body that obeys the next expression.
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1answer
28 views

Calculating new temperature of an object when air temperature changes

I'm trying to calculate the new temperature of an object when the air temperature around it changes, given a period of time. Basically I get periodic readings from an air temperature sensor in a ...
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1answer
27 views

Scale down model of a refrigerator

I am teaching Thermodynamics. For teaching how refrigerators work I am looking for a working model of a scale down refrigerator. This should be as close to real as possible but very small in size. Can ...
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224 views

Calculating the change in entropy in a melting process

I have a homework question that I'm completely stumped on and need help solving it. I have a $50\, \mathrm{g}$ ice cube at $-15\, \mathrm{C}$ that is in a container of $200\, \mathrm{g}$ of water at ...
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2answers
153 views

Why does the coefficient of performance need to be calculated with $W + Q$?

How much work must a heat pump with a COP of 2.50 do in order to extract 1.00 MJ of thermal energy from the outdoors (the cold reservoir)? The first formula that came into my mind after reading ...
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82 views

Radiation emission and absorption

Any object can emit and absorb radiation and the power of emission can be represented by the Stefan-Boltzmann law: $$P=A\epsilon\sigma T^4$$ In many texts the net power radiated is the difference ...
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1answer
78 views

Heat balance: how to obtain T(t) with energy in the form u(T(t))

I have the heat balance equation for a cooling case in the form: $$\frac{dU(T(t))}{dt}=-J$$ with $U$: energy (J) $T$: temperature (K) $t$: time (s) $J$: heat flux leaving the system (W) I have ...
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4answers
115 views

How to measure the energy consumption class of a home appliance? [on hold]

Some of you may be familiar with the EU energy consumption classes for domestic appliances (or equivalents in other areas). Let's say we have a domestic appliance which was made before the energy ...
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2answers
27 views

Latent heat of vaporization at non-boiling temperature

The latent heat of vaporization of water is what we normally use to calculate the heat transfer that occurs at 373 K when liquid water transits to vapor phase. But there are curves for latent heat of ...
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10 views

What are the thermal properties of a “perfectly rigid” container?

can a "perfectly rigid" container be a diathermal boundary? I checked the wikipedia article for heat and read: Kinetic theory explains transfers of energy as heat as macroscopic manifestations of ...
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34 views

Thermodynamic potentials: Demonstration [on hold]

I must prove whether the statement on bold is true or wrong. Under it there is what I tried, but it does not convince me. I use one maxwell relationship on the latest line. And I take advantage of ...
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2answers
79 views

Is Rosehip Syrup boiling in a bottle?

My wife made Rose-hip syrup and the final part was boiling it in a saucepan. While still hot she placed it in a glass bottle. To keep it sterile she plugged it with a wine-saver top and sucked out ...
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1answer
51 views

If you dig a deep tunnel, will the rock sublimate?

If a tunnel is dug deep inside the crust (but before reaching places where the rock is liquid), how will the enormous downwards pressure manifest itself? Will the difference in pressure ...
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28 views

How to solve this steady flow problem? [on hold]

Consider a steady Flow of air through a insulated porous plug. Air enters the plug at 100 kPa and 150m/s and leaves the plug at 50 kPa. Assuming air to be ideal gas and neglect potential energy ...
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4answers
449 views

Is the second law of thermodynamics a fundamental law, or does it emerge from other laws?

My question is basically this. Is the second law of thermodynamics a fundamental, basic law of physics, or does it emerge from more fundamental laws? Let's say I was to write a massive computer ...
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1answer
92 views

Gravity and the Second Law of Thermodynamics [duplicate]

I was wondering about the hypothetical - and apparently improbable - heat death of the Universe when I stumbled upon this seeming contradiction. A certain volume of space with a uniform distribution ...
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1answer
34 views

Calculate heat transfer out of a basement

I am thinking it should be possible to calculate heat loss out of basement based on the temperature of the walls, but am not sure how to do it (what the equations are). For example, lets say the ...
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6answers
198 views

Extracting heat energy without a heat engine

Is it possible to extract the molecular kinetic energy from a system directly (without the use of a heat engine / temperature gradient) and convert that to another form of energy, such as electricity, ...
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32 views

A problem of thermodynamics [on hold]

A lake is covered by a block of ice 10 cm thick. The water temperature is 0ºC and -5ºC for the air above. Calculate the ice growth rate of the block dx/dt knowing that the latent heat of fusion is ...
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33 views

Quadratic versus other types of degrees of freedom

In my text book I have the following question and after thinking about this one for hours, I can't figure out what they're getting at: In Section 2.5* I quoted a theorem on the multiplicity of any ...
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1k views

A water drop in vacuum

Let's imagine the following situation: At an initial moment $t=0$, a large water drop with diameter for example $D=10\ \text{cm}$ is placed in deep space (Say an astronaut is experimenting). Let's ...
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3answers
98 views

How many volcanic eruptions would be necessary per year to neutralize global warming?

Volcanic eruptions sometimes cool the earth. How many eruptions of what magnitude, locality and type would be required per year to neutralize Global Warming?
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2answers
114 views

Who invented the perfume bottle thought experiment?

A common thought experiment used to explain the second law of thermodynamics, the "arrow of time", etc. is perfume escaping from an opened perfume bottle; the perfume is likely to diffuse into the ...
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1answer
17 views

Variable area manometer duct

How does one measure the pressure at the end of the manometer tube when the manometer tube itself is having a variable area?
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1answer
46 views

On Thermodynamics of Spontaneity of the Reduction-Oxidation Chemical Reactions

According to the first and second law for a closed system containing different chemicals we have \begin{align} &\delta Q - \delta W = dU = T dS - p dV +\sum_i \mu_i d N_i\\ ...
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1answer
32 views

Partial Pressure - Which solution is right?

Question: Carbon dioxide (1.100 g) was introduced into a 1.00 L flask which contained some pure oxygen gas. The flask was warmed to 373 K and the pressure was then found to be 608 mmHg. If CO2 and O2 ...
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22 views

How powerful would a series of rail guns or bombs need to be to destabilize a hurricane?

In an effort to destabilize hurricanes by burning the necessary cold zones it has been proposed that planes drop various carbon trash on them. That seems like a minor amount of heat change over a ...
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2answers
60 views

The thermodynamics of heating water in a rigid container

When the pressure on the liquid surface is less than the vapor pressure of the liquid at a given temperature, the liquid will start to evaporate. This is common sense. The problem is more difficult ...
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3answers
92 views

Is thermodynamic free energy and potential energy the same thing?

The equation for free energy $F$ and potential energy $E_{pot}$ are: $$ F=U-TS \\ E_{pot} = E_{tot} -E_{kin} $$ But the temperature $T$ is proportional to the average kinetic energy of a system. So ...
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1answer
43 views

Irreversible work

I'm having some trouble trying to find the irreversible work done by a perfect gas when expanding. I know that the reversible work is greater than the irreversible one, but how can I find the ...
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2answers
40 views

Problem regarding heat engines [closed]

We have two different set ups: A 200K brick in a 300K environment A 300K brick in a 200K environment From which one of these can you extract more work? Assume equal mass and heat capacity. Using ...
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4answers
119 views

why are the square of the components of velocity equal?

In Principles of Physics by Resnick,Halliday,Walker, when evaluating the $v_{rms}$ ,they first found $p = \frac{nM(v_x)^2}{V}$ & then substiuted $(v_{avg})^2 = \frac{1}{3} .v^2$ where $v^2 = ...
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2answers
105 views

Coarse graining on measurement vs phase space (second law)

I've followed Leonard Susskinds series on "the theoretical minimum". In the entropy/reversibility episode in statistical mechanics, he explains (at least one way of) how the apparent paradox of ...
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1answer
1k views

Finding electric power generated using heat transfer

I'm working through an example I have been given to study. Suppose I have a 2m X 4m photovoltaic panel on my roof that is irradiated with a solar flux of $G_s = 700W/m^2$. Given: $\alpha_s = 0.83$ ...
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5answers
449 views

Entropy increase vs Conservation of information (QM)

Unitarity of quantum mechanics prohibits information destruction. On the other hand, the second law of thermodynamics claims entropy to be increasing. If entropy is to be thought of as a measure of ...
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1answer
38 views

Liquid Column “Recoils” in a Sealed Cylinder When Hit by a Piston — Is it Possible?

Consider a cylinder filled partially with a liquid (e.g. water). The cylinder is sealed, and is at held at room temperature (e.g 298K). At equilibrium (or when no external disturbance is imparted to ...
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74 views

Thermodynamics for Dummies: Entropy and temperature

I do not study physics and I have never had a course in thermodynamics. I have no idea what it is about, but I am currently taking a course where we had something about entropy. Would be great if ...
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56 views

Enthalpic Excess - Regular Solution Upon Mixing

My professor, in his handout, says the following about this diagram : For $\beta>+2$ there are two minima and phase separation occurs driven by unfavourable enthalpic interactions. I ...
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91 views

How does enthalpy help us to find the state of equilibrium?

For an adiabatic system with constant external (generalized) forces, in a state out of equilibrium we have: $$\delta H\leq 0 $$ If I understand correctly, derivation of this inequality does not rely ...
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26 views

Good explanation of phase transitions, second law of thermodynamics [duplicate]

I am looking for a good explanation (website, book, video,...) of phase transitions. I am interested in atmospheric applications (so basically condensation, etc. of water in air). I would like an in ...
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3answers
24 views

Is it possible for an electrical device to generate more heat than another using less power or the same?

People are claiming that a Plasma TV uses more power which explains why it uses more heat. We refer to power as wattage in this regard. Countering this, is it possible that a device can draw the same ...
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74 views

Is Fourier's law of conduction a consequence of the second principle?

In classical thermodynamics courses, entropy is often motivated by the need to justify that heat flows from high temperatures zones to lower temperatures zones: this is seen as a consequence of ...