Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Difference between solid and gases thermal expansion

The coefficient of linear expansion is $$\Delta L = L \,\alpha \Delta T,$$ where $\Delta t$ can be the difference of any two temperatures. However, in volume expansion of gases, $$\Delta V = V ...
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11 views

Is it impossible to find the exact analytic form of the molar volume of liquid and gas in phase transition from the van der Waal equations?

I want to find the molar volume $v_g , v_l$ of gas and liquid respectively in the coexistence curve of phase diagram with given temperature when ideal van der Waal gas $$ P = ...
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2answers
156 views

Rayleigh-Taylor Instability dependence on acceleration direction

I'm trying to bolster my understanding of the Rayleigh-Taylor instability, and I've gotten stuck on the point of which fluid (more or less dense) is being accelerated into the other. Cases of uniform ...
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1answer
39 views

Why does the temperature of a gas inside a moving container not increase with velocity?

A rectangular (simplified) container with rigid surfaces, has a certain mass of ideal gas within it, and it accelerates in free space, undergoing rectilinear motion. There are no dissipative ...
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3answers
169 views

Interpretation of systems in different state of matters BUT almost identical configuration

For a start, let me clarify that by "almost identical configuration" I mean same volume, temperature and number of molecules (but different pressure). One could for instance take two identical systems ...
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82 views

Which function denotes the energy of thermal motion within a system?

In thermodynamics, the heat $Q$ is defined as a type of energy in transfer, and is not a state function, which function denotes the energy of thermal motion within a system? 1) $TS$, (there is a ...
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45 views

Definition of 1 calorie

Why has the definition of 1 calorie been taken to be the energy required to heat 1 gram of water from 14.5 to 15.5 degree centigrade at standard pressure? Is there any specific reason for taking the ...
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2answers
29 views

Which materials absorb heat?

Which are the materials that absorb heat? and can i somehow convert that absorbed heat into a different form of energy? I am looking into trying to absorb the wasted heat dissipated by laptops,severs ...
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1answer
31 views

Seeking Reference on Transport of Momentum by Diffusion of Mass

I'm looking at continuum mechanics from the perspective of De Groot and Mazur's "Non-Equilibrium Thermodynamics" - the first reference that I've come across that seems to do a good job of bringing ...
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81 views

On Thermodynamics of Spontaneity of the Reduction-Oxidation Chemical Reactions

According to the first and second law for a closed system containing different chemicals we have \begin{align} &\delta Q - \delta W = dU = T dS - p dV +\sum_i \mu_i d N_i\\ ...
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11 views

does the internal energy and enthalpy of the GAS changes in a free expansion process?

when a balloon kept in an evacuated room is punctured and the ideal gas in the balloon goes on to fill the entire room,does the gas perform any work in this expansion, and is there in any change in ...
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795 views

Pressure vs Volume Calculation for air

I have 1 litre of air in a sealed container at atmosphere pressure (approx 15 psi absolute). I want to reduce pressure in the container by 1 psi ( 14 psi absolute or -1 psig). If I understand ...
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48 views

Electromagnetic cooling

Heat means stored kinetic energy in matter. Microwave owens and induction heaters works on increasing kinetic energy on matter. Is it possible to make inverse of this heaters like cooler. Can we ...
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35 views

Can gas return back into a sparkling beverage on cooldown?

We all know that if a sparkling beverage (let's say, CocaCola) spends some time outside of the fridge and gets warm, the gas comes out of the liquid, rises the inner pressure and makes the bottle ...
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172 views

Boltzmann Distribution of Electrons in Confining Potential

I have a particle simulation wherein many non-interacting electrons are trapped in a electric potential well. I would expect, and therefore I initialize according to this, that the electrons would ...
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1answer
89 views

Spontaneity / Free Energy of Non-Isothermal Process

I'm trying to determine a lower bound for the work input necessary to make an entropy-reducing process "spontaneous" in the sense that the 2nd law is not violated. For a constant temperature and ...
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13k views

Why is air a poor conductor of heat?

Today, I was reading an article How Thermoses Work It goes on to explain all three processes of heat transfer: Conduction Radiation Convection In Convection, It states, If it weren't for ...
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8 views

Increased pressure of Liquid Pitch and Limestone (Bitumen/Asphalt) @ approximately 300 degrees Fahrenheit

If liquid pitch and limestone (20/80 mostly limestone) is pumped (appx. 5 gpm) out of a nozzle that restricts the flow compared to the flow that would be achieved straight out of the pump ( no ...
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1answer
153 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
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2k views

Entropy of radiation emitted into space

In several papers I see something equivalent to the following expression for the entropy of radiation given by an astronomical object such as the Sun (assuming the object can be approximated as a ...
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28 views

What do physicists mean with “classical critical behaviour”?

What do physicists mean with "classical critical behaviour"? As far as I am concerned it should be "power law behaviour" of some quantity close to the critical point but I ask here to be sure.
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12 views

Specific heat capacity for constant volume and constant pressure

I have seen in some exercises that the specific heat capacity for constant volume, $c_{vo}$ and the specific heat capacity for constant pressure, $c_{po}$ , where the $o$ indicates that we are ...
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2answers
45 views

Different materials have different temperatures?

Why do two materials, under the same weather, have different temperatures? I have a small clue about it. For example, iron and wood supposed under the sun's radiation, and if we touch both of them, ...
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2answers
84 views

Why is the outside run of high presure line on a ductless mini-split airconditioner insulated?

On every ductless mini-split air conditioner I've ever seen, both the high and low pressure lines are insulated between the compressor and the building. It seems like the liquid refrigerant coming ...
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48 views

Changing the melting point of ice

Myself and a friend have been stuck on this problem for a while now. We know that we should end up with an answer of $-0.007K$ however, cannot get to this solution. Help with the method we should use ...
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2answers
79 views

What is the heat sink in an internal combustion engine?

I believe that the heat source is the spark plug because it heats up the fuel-air mixture and that the working substance is the fuel-gas mixture. Then, I know that the explosion created by the fuel ...
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48 views

derivation qm canonical ensemble

In classical mechanics the canonical ensemble can be derived from the microcanonical ensemble of two systems in weak interaction. Is a similar thing possible in quantum mechanics? Is there any good ...
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6answers
745 views

Why does the bathroom become hot after a bath?

I have noticed many times that whenever I enter into the bathroom just after someone else bathed the temperature inside it would be high. Is it that the body heat comes out when we pour a lot of ...
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5answers
175 views

Entropy Change in an irreversible process

I have just started learning thermodynamics and the concept of entropy confuses me. Suppose I have a gas in a cylindrical container fitted with a piston. I take it through an adiabatic irreversible ...
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33 views

Specific heat at constant volume

Me and my friend came across this derivation is some lecture notes of our thermal physics module. We have been trying to calculate the partial differential of the internal energy but cannot get the ...
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25 views

Work done by a gas in an expansion [duplicate]

1) Consider a gas expanding quasistatically and reversibly from $V_1$ to $V_2$ at constant temperature. I want to calculate the work done. So by convention work done by a system is a negative quantity ...
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9 views

What is the heated added and changes in internal energy? thermodynamics

A piston + cylinder initially contains 2 x 10-3 m3 of helium gas at the pressure of 1.01 x 105 Pa and with a temperature of 60'C. The gas is heated allowed to expand at a constant pressure until its ...
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14 views

Heat energy question [closed]

An aluminium block of mass 1 kg is heated by an electric heater for 3 minutes and a temperature rise of 15 °C is recorded. If the electric heater is connected to a voltmeter which gives a reading of ...
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1answer
942 views

Physics-based derivation of the formula for entropy

I am looking for a derivation of the formula $$S~=~-\Sigma_ip_i \log (p_i).$$ for entropy, from first principles. I only wish to assume the laws of physics, and without involving concepts in ...
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22 views

Classifying solutions of equation of state as functions of temperature [on hold]

I've got an exam in 2 days and the past papers don't have solutions. I'm given this equation of state: $$ p + a\frac{N}{V} = \frac{Nk_BT}{V-bN}$$ and asked to classify the solutions as functions of ...
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35 views

Find the velocity of the escape of the bullet

A gun has a muzzle 0.8 meters long and with a diameter of 0.006 m. A bullet with mass 0.002 kg is initially 0.01 m away from the end of the muzzle. As a result of a gunshot, the pressure of the gas ...
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2answers
47 views

what is the temperature (and pressure) of the oxygen inside an oxygen bottle?

In the hospital or in a lab, one can see the huge oxygen bottles. A question is, what is the temperature of the oxygen inside the bottle? And what is the pressure inside? We know the critical ...
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17 views

Find the molar specific heat for each gas [closed]

A mixture of two ideal gases, the first one atomic and the second two atomic are put in normal conditions in a calorimeter with volume 1 liter hermetically closed. After it is given 10J thermal energy ...
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24 views

Find the time needed to warm the water to a temperature [closed]

An electrical resistence has a power of 1 kW. It is put inside a container that has 10 liters water. The water is in temperature 20C with pressure 1 atm. Find the time to warm the water to the ...
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1answer
333 views

Compute convective heat transfer coefficient for a condensing steam

I have a question about convective heat transfer coefficients. I am trying to figure out how much steam I can condense in this specific heat exchanger. Steam at 9 MPa is condensed in a 1 shell pass, ...
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1answer
28 views

Show that change in internal energy equals zero for an adiabatic process with incompressible fluid

I have a problem when solving an exercise in thermodynamics. I am supposed to show that when we have an open system, where the process is adiabatic with an incompressible fluid, it follows that the ...
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1answer
166 views

Liquid column “recoils” in a sealed cylinder when hit by a piston — is it possible?

Consider a cylinder filled partially with a liquid (e.g. water). The cylinder is sealed, and is at held at room temperature (e.g 298K). At equilibrium (or when no external disturbance is imparted to ...
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1answer
143 views

How does enthalpy help us to find the state of equilibrium?

For an adiabatic system with constant external (generalized) forces, in a state out of equilibrium we have: $$\delta H\leq 0 $$ If I understand correctly, derivation of this inequality does not rely ...
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1answer
41 views

Struggling with whether its $\pm p dV $

I am struggling to understand when calculating the work done by a gas whether it is postive or negative p. It my notes and in many other notes sometimes it is $-pdV$ and sometimes it is $pdV$. I ...
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13 views

Chemical potentials of SM particles at high temperatures

Recently I've heard the statement that chemical potentials of SM particles on $T > 1 \text{ GeV}$ are very small, so that Gibbs potential reduces to free energy. How to prove this statement? Does ...
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3answers
12k views

Why do lightbulbs continue to glow after the light is turned off?

I've noticed that whenever I turn the lamp off in my room at night, the lightbulb seems to continue to glow for a minute or so after that. It's not bright though; the only way I even notice it is if ...
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2answers
52 views

clausious inquality

Take a reservoir which gains a heat Q irreversibly at temp T from a surrounding at temp T0 then the entropy change of reservoir is given by Q/t and that of the surrounding is -Q/T0...How is this ...
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80 views

Does time stand still at a phase transition?

For second order phase transition thermodynamic properties can be described in very general terms by their critical exponents. So at every transition the correlation length $\xi$ should diverge as ...
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1answer
24 views

entropy change during irreversible heat loss [duplicate]

When a thermodynamic system gains heat if the heat gain is irreversible then there is a entropy generation along with the entropy transfer..so is there a similar entropy generation associated with ...
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18 views

Superficial velocity as a function of position along flow path

I am wanting to estimate the superficial velocity of a fluid as a function of position. The system I'm trying to evaluate is as shown below: A cylinder of porous media with the source acting on ...