Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Conditions for heat exchange and evaporation

I wonder if there is any law for heat exchange. I have learnt that heat exchange between systems occurs when the temperature of the systems differ , but in case of evaporation, the process creates a ...
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2answers
40 views

Is there a way to make atom move faster without heating them?

The more heat you add the faster the atom will move. This is something that is common knowledge. My question is it possible to make the atoms in let's say a gas move faster without adding heat of a ...
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1answer
286 views

Do magnetic fields cause ionisation of gases?

I am doing my final year engineering project on Magnetic Field Assisted Combustion and was curious to see what people thought about it. Companies sell rare earth magnetic arrangements to be attached ...
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1answer
34 views

Can/will a proton escape the nucleus when a force is applied?

Protons are contained within the nucleus of an atom. Protons carry a positive charge. With an electric field, we can exert a force on the proton. Is it possible for the proton to escape the nucleus? ...
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1answer
28 views

Do air particles always rush to fill a container?

I'm sitting here in the metro station, drinking a bottle of water, and watching how the flow of water out of my mouth changes as air rushes into the bottle. My questions is: in space, obviously the ...
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0answers
15 views

Fluctuation theorem - Tasaki Crooks

The Tasaki Crooks relation connects forward and backward evolution of a system which is initially in equlibrium: $$ \frac{P_F(W)}{P_B(-W)}=\mathrm{e}^{\beta(W-\Delta F)} $$ If the system would ...
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4answers
190 views
+100

Thermodynamic equilibrium - will the piston move?

Friend asked me this question and I didn't manage to solve it with basic thermodynamic reasoning. I believe this problem is easly solvable via numeric methods by choosing specific systems, though I ...
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1answer
116 views

On Thermodynamics of Spontaneity of the Reduction-Oxidation Chemical Reactions

According to the first and second law for a closed system containing different chemicals we have \begin{align} &\delta Q - \delta W = dU = T dS - p dV +\sum_i \mu_i d N_i\\ ...
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1answer
25 views

As hot air rises is the cold air that rushes in pushed in or sucked in?

I seem to remember from high school, the state of equilibrium. Volumes of more molecules wanting to get to a volume of less molecules and causing a state of equilibrium. From this I believe cold air ...
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0answers
9 views

Heating of mixture of gases with one gas barely above its boiling point

What happens when mixture of two gases is heated in a closed container? If one gas expands faster than the other and increases pressure of the container enough so that the boiling point of the other ...
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1answer
17 views

Volume of Air pumped in Isothermal system [on hold]

A manual bicycle tire pump has a cylinder with volume V. When the piston is extended, the valve to the tire closes, and air at atmospheric pressure enters into the cylinder through another valve in ...
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1answer
316 views

Gas compressed and cooled

If a certain amount of a gas is compressed into a cylinder by the action of a piston that reduces its volume (lets say at a low speed), the kynetic energy of the gas molecules increases, what is ...
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3answers
25 views

Heat transfer equally distributed?

When heat is introduced to a copper bar's end surfaces(right or left surface) of a certain volume $cm^3$, is the heat uniformly distributed? In my calculations of heat transfer, I'm using $$Q = mC_P ...
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1answer
142 views

Energy conservation of permanent magnets engine

How to explain the fact that magnet can attract an object (apply a work W) without losing a (significant) part of its internal energy? How to apply the energy conservation principle? Please think to ...
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2answers
35 views

Carnot engine basics?

A line in my textbook says.. ' if we employ any other process that is not adiabatic, say an isochoric process, to take the system from one temperature to another, we shall need a series of ...
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1answer
26 views

Effectiveness of phase-change materials vs water for heat storage?

I'm trying to understand the benefit of specialized phase-change materials vs. water for absorbing heat in a home during the day. It's my understanding that selecting phase-change materials whose ...
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2answers
155 views

Thermodynamic transformation

Why is it that any reversible thermodynamic transformation is quasi-static? Also, why is the converse not necessarily true?
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0answers
25 views

Experiment to determine the specific heats of a gas using a resistance heater [on hold]

Can anyone explain briefly how this experiment will be conducted and what measurements i need to take and record?? i need a brief idea to start doing it. Can anyone here pls help me??
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1answer
197 views

Helmholtz Free Energy vs Gibbs Free Energy in Landau Theory

When I was studying thermodynamics potentials for the first time, I learned that keeping the pressure and the temperature constant, the Gibbs Free Energy is a minimum, also, if we maintain the ...
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1answer
3k views

Whenever we fill a bottle with cold water and close it, why is it that after a few seconds we notice cold water droplets outside the bottle?

Whenever we fill a bottle with cold water and place back the cap tightly closing it, why is it that after a few seconds we notice cold water droplets outside the bottle as if the water is coming out ...
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3answers
421 views

Distinguishable, Indistinguishable Paramagnetic Ideal Gas

In the canonical ensemble, the partition function for an ideal gas is given by: $$\frac{Z}{N!}$$ The factor $N!$ accounts for the indistinguishability of the particles of the ideal gas. What ...
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0answers
25 views

How do I compute mass flow rate for a compressible fluid?

Consider the vacuum chamber in the figure. If a hole with cross section area $A_{cs}$ is created, how can I approximate the maximum mass flow rate, $\dot{m}$, for a compressible fluid (e.g. air)?
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5answers
7k views

Why is Helium so hard to liquify?

By the end of the 19th century all gasses had been liquefied apart from helium (He). What is it about helium that makes it so hard to liquefy compared to the other gases? And why does it need to be ...
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0answers
24 views

Ratio of Stagnation to Normal Flow Properties in Incompressible Flows

I know in compressible flows the ratio of stagnation to normal flow variables is a function of the Mach number and usually the specific heat ratio. Does this ratio mean anything for incompressible ...
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1answer
23 views

Flame composition types

Can anyone define the atomic structure of a carbon fuelled flame. I have studied variations of flame patterns but this type seems to stand out.
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2answers
168 views

How do we explain the existence of liquids, from a mathematical or computational perspective? [on hold]

This post asks why matter exists in three phases. Most of its answers explain the existence of liquids with some variant of the following: liquids happen when thermodynamic conditions, temperature ...
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3answers
245 views

Entropy change in an irreversible process between 2 equilibrium state

Calculating entropy change in an irreversible process between 2 states requires computing the change in entropy for any reversible process between the 2 same states, but why? If someone could provide ...
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4answers
709 views

Why are exothermic reactions easier than endothermic?

If we talk about electric heating then we have simple elements in which we apply electrical energy which gets converted into the kinetic energy of the electrons which heats it up. But while cooling, ...
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1answer
195 views

Calculate the entropy per atom in Bohmian Mechanics

Bohmian mechanics description of a large number of interacting atoms would require a large phase space due to the large number of classical degrees of freedom. The entropy per atom is given as the ...
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3answers
731 views

Solidification by the application of heat

When you add heat to a liquid (or a fluid), can it be solidified? If not, why in the world does an egg's stuffs become solid (or at least no more a liquid) when you 'boil' it in water?
3
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1answer
23 views

Coupling constant for an object in a photon gas

I want to model a photon gas as a bath of harmonic oscillators, and examine the effects of this bath on a system which is also a harmonic oscillator. The trouble I'm having is in relating the ...
17
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6answers
467 views

Do gases have phonons?

A phonon is a quantized unit of sound; they are encountered when quantizing lattice vibrations in solids. Now, even an ideal gas supports sound waves, but in such a case, interactions between atoms ...
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1answer
538 views

Calculation of water bulk modulus using equation of state

I simply want to calculate the bulk modulus of water at 50C and increasing pressures. I think I am correctly calculating the new specific volume from the original conditions at (25C and 1atm) to 50C ...
55
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7answers
7k views

How did my candle wax crawl up the sides of the jar?

I have an Ikea candle which has sat on my bookshelf in the sun for >5 years. Aside from an hour or two shortly after I bought the candle, I have not burned the candle regularly (in fact, the wick is ...
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1answer
1k views

Otto cycle efficiency described in pressure ratio (instead of compression ratio)

The Otto cycle's thermodynamic efficiency is often described using the compression ratio: $$\eta_{th} = 1 - \left( \frac{1}{CR} \right ) ^ {k-1},$$ (where CR is the compression ratio, and k the ...
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3answers
142 views

Is liquid helium expensive because of its rarity or because of its low liquidification temperature?

I once argued with my roommate about this problem. Of course it is rare. But presumably the low liquidification temperature makes the cost high too. So which is the primary reason?
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1answer
65 views

Integrated Boltzmann equation for dark matter

In Dodelson's book, the equation for a scattering process $ a + b \Leftrightarrow c + d $ is given as \begin{align} a^{-3} \frac{\mathrm d (n_a a^3)}{\mathrm d t}&=-n^{\text{eq}}_a ...
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3answers
626 views

Cooling down to absolute zero by radiation

Consider a system consisting of a gas, it is put in a container which is permits transmission of all kinds of electromagnetic waves. If this system is isolated and put in a perfect vacuum, and left ...
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0answers
22 views

Heat loss by radiation reference

In our lab practice, we measured the rate of heat loss of a copper plate in atmospheric pressure and the rate of heat loss of the same plate in high vacuum ($\sim 10^5 torr$). So all I could find for ...
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1answer
56 views

How does covering a hot bowl of soup prevent heat losses?

Recently I took out some soup to eat and got a call from a friend. I covered it with a plate and when i came back later, it was still hot. While i was eating, i wondered how does covering this hot ...
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0answers
30 views

probability of striking the circular ring by gas molecules

In kinetic theory we use probabilistic case to derive pressure, no. Of molecules having speed c to c+dc or in such cases.and to derive such equations we introduce a term called "SOLID ANGLE" I come ...
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2answers
224 views

In a Monte Carlo NVT simulation How do I determine equilibration

I'm running an NVT (constant number of particles, volume and temperature) Monte Carlo simulation (Metropolis algorithm) of particles in two dimensions interacting via Lennard-Jonse potential ($U = ...
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4answers
3k views

If we feel it's hotter when humidity increases, then why do we feel it's colder when inside water?

When the humidity in the air is high, we sweat more and feel it's hotter than when the humidity is lower. So why don't we feel it's hotter when we go inside water, where the water content is much ...
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1answer
210 views

What causes a heat generating source to stabilize at a certain temperature? (Answered by myself, I think)

For example, we out a heat sink on a microprocessor to keep it cooler. I understand that if we run 100 watts of electricity through the microprocessor, it will generate 100 watts of heat, or 100 ...
2
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1answer
261 views

Boltzmann Distribution of Electrons in Confining Potential

I have a particle simulation wherein many non-interacting electrons are trapped in a electric potential well. I would expect, and therefore I initialize according to this, that the electrons would ...
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3answers
528 views

How does the dissolution of salt affect the solution density?

Suppose you have a container of water as a solvent and you a certain amount of salt as a solute sitting at the bottom of the container that has yet to start dissolving. Supposing temperature and ...
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1answer
52 views

How cold does this ice have to be to freeze this water bottle solid?

We are at sea level in a room that is 21 celsius. We have 1 liter of sterile water with a temperature of 21 celsius in a normal plastic bottle. We have a 20 liter bucket of ice cubes, consisting of ...
4
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0answers
30 views

How to calculate the energy transfer between working coil and working piece and dissipated energy of working piece in induction heating?

For who don't know how does induction heating work, a short description can be found here. However, my question is about physics. Assume I have a coil inductor calculated carefully 50 uH as below: ...
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2answers
62 views

How much faster are airmolecules going when the temperature raise from 15 to 25 degrees C?

As far as I know the temperature of the air depends on how fast the airmolecules are moving. But what is the increase of speed (in km/h) of those air molecules?
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2answers
145 views

Do gravitational waves have entropy?

We know, according the current understanding of black holes and General Relativity, as well as quantum fields in General Relativity, that black holes have an entropy proportional to the area of the ...