Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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367 views

How is the logarithmic correction to the entropy of a non extremal black hole derived?

I`ve just read, that for non extremal black holes, there exists a logarithmic (and other) correction(s) to the well known term proportional to the area of the horizon such that $S = \frac{A}{4G} + K ...
5
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1answer
166 views

Liquid column “recoils” in a sealed cylinder when hit by a piston — is it possible?

Consider a cylinder filled partially with a liquid (e.g. water). The cylinder is sealed, and is at held at room temperature (e.g 298K). At equilibrium (or when no external disturbance is imparted to ...
4
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1answer
75 views

Find Solution to the Heat Equation with Bessel Functions and Initial Values

I'm trying to find the time dependent solution to the heat equation in a very long cylinder (the problem only depends on radius, r, and time, t) with the initial value $T(r,0)=T_1$ and the Dirichlet ...
4
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1answer
335 views

Hysteresis and dissipation

Hysteretic phenomena are often linked to dissipation. When there is an hysteresis loop, the dissipated energy can usually be computed as the area of the cycle. For example, in ferromagnetic ...
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1answer
105 views

Why doesn't a Brownian ratchet provide free energy?

A Brownian ratchet is described here at Wikipedia. The "why it fails" section reads: Feynman demonstrated that if the entire device is at the same temperature, the ratchet will not rotate ...
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1answer
159 views

Amount of energy to separate Gases - relationship to concentration

I want to understand the efficiencies of separating mixed gases, and for that I want to understand the thermodynamic limit case. Looking at the wikipedia page for entropy of mixing, I find the ...
3
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1answer
357 views

Does a negative line tension in a 3-fluid immiscible interface make sense?

This question is inspired by this question/answer pair: Is this formula for the energy of a configuration of 3 fluids physically reasonable? Consider three immiscible fluids forming contact surfaces, ...
3
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1answer
453 views

Coffee cooling in a cup

Will coffee in two differant size styrofoam cups in the same room conditions cool at the same rate? One cup is 8 oz. and the other would be 12 oz.
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1answer
104 views

Newton's law of cooling for the heat equation boundary condition

Newton's law of cooling says the temperature of an object satisfies $$ \frac{dT}{dt} = -k(T(t) - T_0),\tag{1} $$ where $T_0$ is the surrounding temperature. See these HTML notes for example. Now if ...
2
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1answer
34 views

How does the second law of thermodynamics affect the efficiency heat-to-work conversion, at the molecular level?

I understand the second law of thermodynamics in terms of the improbability of the high--and-low-velocity particles of a gas to separate themselves so that at one moment they are at different sides of ...
2
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1answer
51 views

Do magnetic fields cause ionisation of gases?

I am doing my final year engineering project on Magnetic Field Assisted Combustion and was curious to see what people thought about it. Companies sell rare earth magnetic arrangements to be attached ...
2
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1answer
62 views

Why does ice melts faster near the surface of water?

I had a few frozen bottles and while they were melting I saw this: in all of the bootles, the ice seems to get thiner near the surface. I have searched a bit and I've found this video that shows ...
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1answer
164 views

Calculating new temperature of an object when air temperature changes

I'm trying to calculate the new temperature of an object when the air temperature around it changes, given a period of time. Basically I get periodic readings from an air temperature sensor in a ...
2
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1answer
119 views

Which air will give more effective cooling ? Dry or Moist?

Yesterday, I had an innovative idea. I live in India, and in summer season, the temperature can reach up to 45 degree Celsius. We use Split 1.5 Ton AC in our small office. The idea is to put an ...
2
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1answer
153 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
2
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1answer
604 views

Difficulties with understanding total entropy change and unavailabillty

Of course, I know the fact that the entropy of an isolated system never decreases. Neverthless what makes me confused about the entropy(or change of entropy) of an isolated system is the explanation ...
2
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1answer
943 views

Physics-based derivation of the formula for entropy

I am looking for a derivation of the formula $$S~=~-\Sigma_ip_i \log (p_i).$$ for entropy, from first principles. I only wish to assume the laws of physics, and without involving concepts in ...
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1answer
2k views

Finding electric power generated using heat transfer

I'm working through an example I have been given to study. Suppose I have a 2m X 4m photovoltaic panel on my roof that is irradiated with a solar flux of $G_s = 700W/m^2$. Given: $\alpha_s = 0.83$ ...
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1answer
11 views

does the internal energy and enthalpy of the GAS changes in a free expansion process?

when a balloon kept in an evacuated room is punctured and the ideal gas in the balloon goes on to fill the entire room,does the gas perform any work in this expansion, and is there in any change in ...
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1answer
31 views

Seeking Reference on Transport of Momentum by Diffusion of Mass

I'm looking at continuum mechanics from the perspective of De Groot and Mazur's "Non-Equilibrium Thermodynamics" - the first reference that I've come across that seems to do a good job of bringing ...
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1answer
48 views

Electromagnetic cooling

Heat means stored kinetic energy in matter. Microwave owens and induction heaters works on increasing kinetic energy on matter. Is it possible to make inverse of this heaters like cooler. Can we ...
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1answer
25 views

Triangular Cyclic Process

i am currently studying for my physics exam and i am trying to wrap my head around cyclic processes. There is the cyclic process - ![1]: (http://imgur.com/7i0JF1S) "cyclic process" We know its an ...
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1answer
16 views

How to convert the molar attenuation coefficient, ie. molar absorptivity, to heat capacity?

In spectroscopy techniques, such as infrared spectroscopy, light of a certain wavelength is absorbed. I see parallels to the concept of heat capacity, i.e. the heat necessary to change the temperature ...
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1answer
53 views

Double Pipe Heat Exchanger

I have a metal plate and I need to transfer heat out of the metal plate to the atmosphere. Hence, I can use a double pipe heat exchanger which contains 2 pipes. But what if I just use one pipe and let ...
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71 views

Experimental heat equation for a bottle of water

I'm not sure if this question belongs here, because I'm asking a question about experimental data rather than theoretic formula. Anyway, I'm trying to figure out the time-temperature relation of the ...
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137 views

diesel steam engine

Let's imagine a diesel engine's cylinder head would be heated by external means, to some hundred degree celsius, and the fuel would be replaced by water. We've made modifications so that water ...
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160 views

Food kept in a container in my pressure cooker cooks slower

The pressure cooker is heated at the base to cook the food. The pressure cooker releases steam when the force exerted by pressure exceeds the counterweight, at which point the weight rises up allowing ...
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62 views

Which pressure to use in the $T~ds$ equation?

Let's say I have an adiabatic, rigid, open container that has an amount of air at some pressure, $P_\text{cv}$, and some temperature, $T_\text{cv}$. I have heated pressurized air coming into the ...
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90 views

Best material for heat transfer between ice and water

What is the best container material for heat transfer between ice and water? this is a difficult question to ask without displaying a picture of what I'm meaning.
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31 views

Is there a thermodynamic law or theorem that expresses how systems “break” or “change” when enough energy is added?

I have a simple question about thermodynamic laws, and I am hoping you can help me. Let's say that I have a sphere container with some pressurized gas in it. I can slowly increase the pressure over ...
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127 views

Rotary Steam Engine

Leon Crux invented the concept of interlocking archimedes spirals that eventually led to the scroll compressor but intended it to be used as a rotary steam engine. However technological limitations of ...
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0answers
65 views

What is the relationship between strain and electric current?

Strain or stress can be caused by different sources. I categorized theses sources as mechanical, thermal and electrical loads and formulated the total stress as follows: $$ \epsilon_{total} = ...
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0answers
32 views

Decompression cooler

How would I figure the needed pressure differential to freeze water inside a cooler using ambient air? I am assuming that the combined gas law would apply here and that the formula P1•V1/T1=P2•V2/T2 ...
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126 views

Please correct my understanding of Clausius-Clapeyron and latent heat

As I work a problem set, I'm being asked to calculate the latent heat associated with a particular phase transition of $NH_3$ (solid -> liquid, liquid -> gas, solid -> gas). I'm being told to perform ...
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36 views

How to compute the change in entropy of s system when the temperature is decreasing?

How to compute the change in entropy of s system when the temperature is decreasing? Such a question may be too general,then we may ask a special case:How to compute the change in entropy of Annealing ...
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0answers
265 views

Constant Pressure lines in evaporation diagram

Assume that there is the following $T-H$ phase diagram with the constant pressure lines. Which is greater preasure? The preasure drops as we move to lower temperatures (i.e. from top to bottom)? ...
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366 views

How does the volume change affect an adiabatic process?

A gas consisting of rigid diatomic molecules was initially under standard conditions. Then the gas was compressed adiabatically, 5 times the original volume. Find the mean KE of rotating molecules ...
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47 views

How connected thermodynamical stability and dynamical stability for black holes?

Criteria for thermodynamical stability is the convex of entropy. But for black hole entropy is non-additive.
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61 views

Lambda transition data points of $\require{mhchem}\ce{^4He}$

I'm looking to get some data on the lambda transition of $\require{mhchem}\ce{^4He}$. I need the data points of the specific heat vs. temperature graph, if that makes sense.
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49 views

Heat of adsorption from fugacity data

I have a set of data relating the fugacity ($\approx$ pressure) to the loading for a given set of temperatures. There are three temperature sets each having five fugacity vs. loading points. The ...
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64 views

Increase in number of micro states explanation or restatement of second law?

Is the boltzmann's expression of entropy as log of micro states leading to the formulation that system is more likely to be in a macrostate with more no. Of micro states really is an explanation or ...
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88 views

Landauer's principle vs Rayleigh–Jeans law

Can we argue based on Landauer's principle that if one bit information is changed inside a blackbody, the total radiated energy should be at least or in order of $kTln2$? If it is so, can we also ...
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0answers
643 views

Entalpy and entropy role in freezing-point depression phenomena

There's this "atomic" explanation of the freezing-point phenomena on Wikipedia that leaves me really intrigued. Consider the problem in which the solvent freezes to a very nearly pure crystal, ...
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0answers
99 views

Using thermodynamics and Kinematics together to solve a parachuter problem?

I need to find a parachutist's displacement after a given height (nearly 37000m) and at a given latitude. I have his mass, area, parachute area, drop height, parachute deployment height, data about ...
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231 views

Constant volume specific heat

A monatomic ideal gas is confined to move in two dimensions. What is the constant volume specific heat for this gas? Consider a system of N independent harmonic oscillators moving in two dimensions. ...
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561 views

Carnot Engine for Finite Reservoirs

Two solid, finite thermal reservoirs have temperatures of $T_1$ and $T_2$ respectively and an engine operates between the two. Assume $T_1 > T_2$ and that each reservoir has constant heat capacity ...
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155 views

direct conversion of heat to electric potential / current - are there theories that contradict the 'Kelvin Statement'?

In particular, William Thomson (Kelvin) appeared to be wrong about key things in physics (initially X-rays, aether, even aviation feasibility). ...
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162 views

2 streams going into an engine and 2 come out. Find the enthalpy?

Problem: Steam supply to an engine is made of two streams that mix before entering the engine. Stream 1 flows at a $.01\frac{kg}{s}$ with an enthalpy of $2952\frac{kJ}{kg}$ and a velocity of ...
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24 views

Magnetic moment of a paramagnetic crystal

I've been having some trouble with a paramagnetism problem from my Statistical Mechanics class textbook (F. Mandl, Statistical Physics, 2nd edition, p. 25). The problem is as follows Since the ...
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9 views

transient condition from bodies subjected to condective boundary conditions

I would like to request you that please solve my queries about two questions. What type of conduction, Transient or steady state, should i consider during heating of water in a closed container ...