Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

learn more… | top users | synonyms (1)

1
vote
1answer
86 views

Confusion in the pressure-volume work in an irreversible process

Let there be a certain amount of gaseous substance kept in a cylinder fitted with a weightless & frictionless piston. The initial volume and pressure of the gas are $V_1$ & $P_1$ respectively. ...
0
votes
3answers
44 views

Why radiant heat only travels as infra-red waves and not as other types of em waves like UV rays

Heat is a form of energy and em waves carry energy as momentum of photons. So, I think, radiant heat can travel at any frequency. Please correct me.
-3
votes
2answers
111 views

Contradiction on Entropy of the “universe” decreasing

I have hit what seems to be a contradiction concerning entropy. In my class, we measured the entropy change of photosynthesis which is obviously a non-spontaneous process. We used the formula, ...
2
votes
0answers
51 views

Evaluate functional integral in partition function of thermal $\phi^4$ theory (Kapusta/Gale p.34-35)

my question is about some steps in the book "Finite Temperature Field Theory" by Kapusta and Gale. To explain the setting, I how to evaluate the functional integrals in the expression $$ \ln ...
2
votes
2answers
269 views

Glass tends to be cold?

In winter, our glass window serves as a separator of coldness outside and warmth inside our room. We know that the window feels cold when we touch it. Since the air temperature is different in ...
1
vote
0answers
135 views

Isentropic and Isothermal Compressibility

Why isentropic compressibility is greater than isothermal compressibility ? While deriving $C_p$ and $C_v$ relation, I got $\frac{Cp}{Cv}$ as $\frac{ke}{Kt}$. Which tells us that $Ke > Kt$. But ...
3
votes
1answer
76 views

Simple estimation of the critical temperature of water

I'm trying to develop fermi estimation skills and I came up with a question for which I don't even know where to start from. Here goes: Is it possible to estimate the critical temperature (say in ...
4
votes
0answers
65 views

Is the stability matrix of a linearised RG flow always diagonalisable?

This is a follow up on "Why are the eigenvalues of a linearized RG transformation real?". My question is simple: Is there some physical (or mathematical) reason for the stability matrix of ...
0
votes
0answers
19 views

Do holes in objects affect their heat expansion [duplicate]

If you heat (assume evenly) a 5 mm sheet of metal containing a cut away hole 20 cm diameter, so it expands, what would happen to diameter of hole? Would it increase, decrease, stay same?
1
vote
1answer
37 views

Classical limit of non-interacting, relativistic quantum gas (Kapusta/Gale p.8)

I want to understand two equations in "Finite temperature field theory" by Kapusta and Gale on page 8. The partition function is $$ \ln Z = V\int \frac{d^3 p}{(2\pi)^3}\;\ln\left(1\pm ...
0
votes
1answer
46 views

Isentropic process and reversibility [duplicate]

I know that every adiabatic reversible process is an isentropic process. Can a process be isentropic but still not reversible adiabatic? Please provide me some examples.
0
votes
1answer
26 views

(Chemistry) Dimensionless heat transfer coefficient

I'm trying to reproduce in Matlab the model of a continuous stirred tank reactor (CSTR) that I've gotten for a project. The model is written in the state space and uses some dimensionless values, ...
2
votes
2answers
140 views

Heat generated by collision

Suppose there are two objects: A = m1 and B = m2 . A is travelling at a constant velocity v toward B and collides inelastically: is there a way in which I could determine the energy which is ...
4
votes
3answers
194 views

How do gas molecules constantly bounce without losing energy?

From a related question (How does pressurized gas constantly push?), i asked myself this: How do gas molecules constantly bounce off each other without losing energy? If you drop a ball, it bounces a ...
0
votes
1answer
35 views

Explanation for Homogeneous Nucleation Temperature?

What is homogeneous nucleation temperature (for water this is listed as -42C); is it simply the lowest experimental temperature you can go before supercooled liquid turns into solid, or is it that ...
1
vote
1answer
67 views

Phase diagram of water v/s other substances

Why for water increase in pressure decreases solidification temperature? The fusion curve of water is not same as that of other substances and for other substances specific volume increases during ...
1
vote
0answers
51 views

fugacity of gases and gaseous mixtures

Is fugacity defined only for gases and gaseous solution.? In many books it is given that fugacity is "effective pressure", what does it mean? If it is applicable to liquids and liquid solutions then ...
12
votes
2answers
237 views

Why is cooling much harder than heating?

I'm trying to invent a distillation apparatus that runs solely on electricity. Suddenly, I realized that cooling things is really hard, while heating them up is so easy. Actually, it seems that there ...
0
votes
2answers
38 views

Thermodynamic equilibrium- mixing of gases

What is the final temperature and pressure after removing diaphragm of a cylinder which divides the cylinder into two equal components each of volume $0.1\,m^3$ and each component contains air at ...
0
votes
1answer
63 views

Unmixing of gases: What is the relevant temperature for my Entropy?

This answer to a question about unmixing gases states: However, let us now assume we have to hand a source of mechanical work, and a large heat reservoir at temperature $T$. I'll assume that ...
2
votes
4answers
180 views

Why does a bubble take a spherical shape?

I suspect this has something to do with thermodynamics and the isoperimetric inequality and I'm interested in a mathematical derivation of this result.
1
vote
1answer
27 views

How to calculate heat generated from cosmic dust in space? [duplicate]

Say I have a spaceship, and I'm flying it through space at a constant high velocity V. The spaceship is pretty large (big surface area). In space however, there is cosmic dust scattered throughout ...
0
votes
1answer
35 views

Why does the equation for effectiveness of heat exchangers have $C_{\text{min}}$ in the denominator?

For an ideal heat exchanger of infinite length, $$ Q_{max}=m_{h}C_{h}\left[T_{h,i}-T_{o}\right]=m_{c}C_{c}\left[T_{o}-T_{c,i}\right] $$ \begin{eqnarray*} m_{h}C_{h}T_{h,i}+m_{c}C_{c}T_{c,i} & ...
0
votes
1answer
31 views

A confusion on Radiations emitted from a body [duplicate]

Suppose an atom is accelerated...Now the protons in its nucleus and the electrons in the orbits are also accelerated...So will they emit the electromagnetic radiations? Basically here the electrons ...
2
votes
3answers
85 views

Is the amount of radiation you receive in space constant regardless of velocity?

I'm only in high school, so this will probably have fatal flaws. So basically in space, there is bound to be stray radiation, whether from the stars, or cosmic background, floating around right. And ...
3
votes
1answer
98 views

Can you explain why crystals form without thermodynamics?

I know that the basic reason that solid crystals form is because it's the lowest energy configuration (i.e. this). I am looking for an intuitive explanation for this process, one that does not involve ...
1
vote
1answer
22 views

How do I set up the tridiagonal matrix for a heat diffusion with layers of different thermal diffusivity?

I have Scala code that recreates the Crank-Nicolson solutions for the diffusion equations, and matches 'Excel for Scientists and Engineers' (Joe Billo, Wiley). However, I would like to be able to ...
1
vote
1answer
38 views

Does no variables change in an adiabatic + isothermal system?

Adiabatic + isothermal = no heat and temperature change. Does that mean the system will remain as it is? If it is adiabatic + isovolumetric or adiabatic + isobaric , is it as well no change in any ...
0
votes
1answer
151 views

What is the difference between reversible and irreversible adiabatic expansion?

What is the difference between reversible and irreversible adiabatic expansion? Is it true that the work done by the gas is the same but the pressure applied externally differ between two process? ...
0
votes
1answer
31 views

Is it only possible when 600J of heat is exhausted and 400J of heat is converted into work? [closed]

Is it only possible when 600J of heat is exhausted and 400J of heat is converted into work? Is the 600J heat will enter the cold reservoir and available to do work again? q1/T hot + q3 / T cold = 0 ...
2
votes
2answers
69 views

Why won't the efficiency of a heat pump increase when $T_\mathrm{cold}$ decreases?

Why won't the efficiency of a heat pump increase when $T_\mathrm{cold}$ decreases? In the carnot cycle, efficiency increases when $T_\mathrm{cold}$ gets colder and $T_\mathrm{hot}$ gets hotter. Are ...
1
vote
1answer
133 views

Comparison between isobaric, isothermal and adiabatic expansion

Please check if my understandings of these terms are right because they are a bit confusing to me. For all three types of expansions, a change in volume means work is done by the system to the ...
0
votes
2answers
57 views

For change in entropy dS = dq/T, is T the temperature of system or surrounding or both?

For change in entropy dS = dqrev/T, is T the temperature of system or surrounding or both? I am confused about Thot, Tcold, Tsys and Tsurr. If qrev, are we talking about the reversible cycle such as ...
6
votes
3answers
269 views

Does entropy have a physical meaning?

Entropy is incredibly useful as a mathematical tool. But what does it actually mean? I understand that the Boltzmann entropy is defined by: $$S=k\ln{\Omega}$$ With $\Omega$ being the multiplicity ...
28
votes
4answers
3k views

Why do computers generate heat?

Computers generate heat when they work. Is it a result of information processing or friction (resistance)? Are these just different ways to describe the same thing? Or does some definite part of the ...
0
votes
0answers
51 views

Temperature dependence for specific thermal diffusivity in the diffusion formula

I recently found this answer about the diffusion equation (nice one actually), but have one doubt about the temperature dependence of this formula. If the "packet" of energy (terminology suggested ...
2
votes
3answers
105 views

Is it possible for heat to flow from body having less heat energy to a body having more heat energy?

Is it possible for heat to flow from a body having less heat energy to a body having more heat energy?
0
votes
2answers
125 views

Disequilibrium during infinitesimal steps of a thermodynamic reversible process & cause of maximum work to be achieved during reversible process?

In almost every sites and even in my book,it is written that "Reversible process is the process which is carried out infinitesimally slowly so that in each step thermodynamic equilibrium is maintained ...
4
votes
4answers
79 views

Will 5 pizzas in the same Hot Bag stay warmer than 5 pizzas in 5 separate Hot Bags?

For example, say I am delivering 5 pepperoni pizzas to 5 different addresses. In one scenario, I Keep all 5 in the same insulated Hot Bag, I carry that bag to the door, and I quickly remove one of the ...
1
vote
2answers
51 views

Does the relation between entropy and temperature depend on the ensemble?

If we change the temperature of a given system, there will be a relation between its entropy and temperature S(T). Is S(T) the same in a canonical ensemble and a grand canonical ensemble? If not, is ...
4
votes
2answers
86 views

Alternative liquid for Galileo thermometer

So a friend of mine broke my Galileo thermometer recently. The glass tube and the liquid inside were lost, but the bulbs survived. I've cleaned out an old tall glass candle, and tried filling it with ...
4
votes
2answers
397 views

Difference between irreversible and entropy?

Cedric Villani recently wrote an article on Landau damping, where at least one topic discussed confused me. Besides discussing the issue of how a process can be microscopically reversible and ...
1
vote
3answers
66 views

When the low temperture reservoir with negative temperture (Kelvin), such as Ising model, is the efficiency of ideal heat engine larger than 1?

The ideal Carnot engine works between two heat reservoir with two temperatures $t_h$ and $t_l$. Its efficiency is then $1-\frac{t_l}{t_h}$ . If the low temperture reservoir is the Ising model with ...
0
votes
1answer
20 views

Is it possible to cool magnetic dipoles with a magnetic static field?

Suppose you have a bath of magnetic dipoles, with a common mean rotational kinetic energy. Now you apply a very strong magnetic field so that the dipoles align with the field, thus "losing" their ...
0
votes
1answer
23 views

Final temperature of an air parcel

How would one find the final temperature of an air parcel ascending adiabatically in the atmosphere? Like which formula would you use? I used the equation of state for dry air to find the initial ...
3
votes
1answer
42 views

Dry adiabatic lifting

If an unsaturated air parcel ascends adiabatically in the atmosphere with an initial temperature, would the final temperature of the air parcel, when it reaches it's destination, be the same at the ...
1
vote
2answers
143 views

Thermodynamic reversible process

My book says "A process is said to be reversible if it is carried out infinitesimally slowly so that in each step thermodynamic equilibrium of the system remains unchanged & any infinitesimal ...
1
vote
1answer
87 views

A puzzle of thermalization in simulating the 3D XY-model

I am learning the classical Monte Carlo simulation. When I simulate the 3D XY-model $$ \beta H = -\beta J \sum_{<i,j>} cos(\theta_i-\theta_j) $$ where $\beta$ is the inverse of the temperature ...
0
votes
0answers
15 views

Creating correlated Szilard engines

A demon has a large number of boxes with a single particle in. He / she adiabatically introduces a wall in the box, dividing it in two with a particle in one of the two halves (L, R). The demon does ...
0
votes
0answers
38 views

How much energy does a powerlifter need to perform a session of squats?

So I started the math myself and I'm hoping someone can look this over and improve on my idea. Let's say that a powerlifter performs the following sets of squats: % 1RM = lifted weight in percent ...