Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Dependence of latent heat on pressure

It is known that the latent heat of vaporization increases as external pressure decreases. What is the cause of this phenomenon?
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Is possible to synthesize diamond at relatively lower pressures (6 to 7 GPa vs 12 GPa)?

Pure binderless nanopolycrystalline diamond can be produced from graphite when the graphite is treated with more than 12 GPa pressure and at least 2100°C temperature . If we treated graphite or ...
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61 views

Few doubts about saturated vapour pressure and unsaturated vapour pressure

I have some sort of confusions towards saturated vapour pressure and unsaturated vapour pressure.. So let me give you those. What is exactly saturated vapour pressure and unsaturated vapour ...
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29 views

Can I interpret Avogadro's principle of gases from the state equation (ideal gas law)?

Considering the molar form of the ideal gas law I can solve for the ratio of some gas volume, $V$ divided by the number of gas particles, $n$ in mols $$\frac{V}{n}=\frac{RT}{P}$$ And $R$ is the ...
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Sign convention thermodynamics

Say a system is inside a volume $V$ with surface normal vector $n$ pointing out from the volume. Then there are force vector fields (nonconservative and conservative) depending on parameters external ...
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58 views

How much a juice maker increases the temperature of the product?

Recently I asked on skeptics if cold pressed juice is higher in nutrients than one from centrifugal juicer and one of the claims is that the centrifugal juicer heats the juice enough to destroy ...
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50 views

Gough-Joule effect in rubber band

When a stretched rubber band is heated, surprisingly, its tension will increase. What is the physics behind this?! Another thing. The Entropic spring model says, for a good specimen, that the ...
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Measuring variation of saturated vapour pressure with temperature

Is it possible to measure variation of saturated vapour pressure of water with time.I just hesitate about it.My suggested procedure which is incomplete is given below Procedure that I would like to ...
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43 views

steady state and thermodynamic equilibrium

What is the difference between a system being in a steady state and thermodynamic equilibrium ? Can a system be in steady state but not in thermodynamic equilibrium and vice-versa?
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Efficiency of an Internal Combustion Engine

This question is about How correct are those comments on efficiecy of internal combustion(IC) engines which calcuate it using 2nd law of thermodynamics.The maximum efficiency of a heat engine can be ...
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327 views

Will Neil Armstrong's moon boot marks really last for thousands of years?

This question concerns the residual heat (if any) contained within the Earth's moon. At the time of the Apollo moon landings, it was widely reported that the boot marks left by the astronauts would ...
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122 views

Is a larger, heated space easier or harder to ventilate if the heat source and ventilation are the same?

Imagine a well insulated room with a heat source inside. The room has two vents, which each have a fan. Cool air is drawn into the room through one vent, and warm air is pushed out the other vent. ...
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Maxwell relations | U goes down pressure?

Differentiating Helmholtz function $ A = U - TS $ with respect to $V$ we get: $$ (\frac{\partial A}{\partial V})_{\scriptscriptstyle T} = (\frac{\partial U}{\partial V})_{\scriptscriptstyle T} ...
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When is strain rate constant?

I have started a tricky problem involving strain rates. To simplify it I was wondering if I can assume the strain rate is constant (and therefore that the shear stress is constant with distance above ...
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Is a body of gas cooler in its upper portion as a result of gravity? [closed]

I read an article a couple of hours ago named Hydrostatic Lapse which makes the case for a phenomenon that I thought was well and truly confirmed; that gravity is responsible for the cooling of gas ...
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Reaction enthalpy-work relationship in a closed piston-cylinder assembly undergoing a chemical reaction

In an closed and insulated piston-cylinder assembly under constant pressure. From first law I should expect $-p(V_f-V_i) = U_f – U_i$ and thus $H_f = H_i$ and $h_f = h_i$. If an exothermic reaction ...
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34 views

Change in internal energy

One definition in my textbook states that total derivative of internal energy $dU$ has the form: $$dU = C_vdT +(\frac{\partial U}{\partial V})_{\scriptscriptstyle T}dV $$ Which I interpret this way: ...
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56 views

Heat loss during evaporation of a liquid boiling due to Bernoulli effect

this is my first post here. I watched this video https://www.youtube.com/watch?v=h5wQoA15OnQ and at 51 seconds it describes Bernoulli's effect of a drop in pressure resulting from an increased ...
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33 views

How accurate is the Callendar-Van Dusen equation?

... over 0 degC to 100 degC? The equation itself can be found here I can do a very accurate one point calibration of a 1/10 DIN PT100 sensor at 0 degC. If I use the equation to correct for non-linear ...
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Biological heat dissipation methods

If the human body is facing temperatures above it's own temperature in a humid environment eg. a rainy jungle above 37 degree celsius, are there any mechanisms that still allows heat dissipation? I ...
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61 views

How much sunlight would 'fit' through a fibre optic cable?

Say a parabolic mirror were used to focus the full sunlight spectrum into a single strand of optical fibre. Assuming ideal conditions (perfect reflecting surface, focal point smaller than diameter of ...
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24 views

Determining the final state of the gas in the tank

Suppose there is air of mass m1 in an insulated tank at temperature T1 and pressure P1. 0.25m1 of air is released through a valve attached to the tank. Find the final temperature, T2 and pressure ...
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Must irreversible heat transfer be quasistatic?

Suppose there is an isolated system composed of two subsystems $A$ and $B$ in thermal contact with each other, but mechanically and diffusively insulated from each other. The system starts off with a ...
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Does mixing violate conservation of energy?

If two fluids in an isolated system mix, the entropy of the system increases. The volume and the number of particles in the system, however, are constant. Thus $$dU=TdS+PdV-\mu dN=TdS>0$$ which ...
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Tap water in the cold glass

It is fairly long time I was in school and I was particularly bad at thermodynamics. This is an question I was trying to comprehend. I have 500ml of tap water @ 20°C. I pour it into heavy glass ...
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98 views

Calculation of entropy change in irreversible cycles, meaning of $\delta Q/T$ in irreversible processes

Lets take the two cycles in the pictures working with an ideal gas. We perform one, and than perform the other. The cycle is made reversible by making the gas exchange heat with a heat bath having ...
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unchanged temperature of balloon inside freezer

I'd tried to put a balloon in the freezer and after enough time (several hours), I took it out and noticed that as I touch it that it's temperature did not drop down . I took an empty balloon ( not ...
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Illustration of heat processes

In isothermal process the work produced in a cyclic transformation is the sum of the small quantities of work $ \delta W$ produced at each stage of the cycle. This description of work I picture, for ...
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96 views

why systems like these don't work [closed]

Suppose there is a thermal reservoir at temp T1 which is more than temperature T2 of a piston cylinder system. So it can transfer heat to system. Then the system gaining heat do work of friction on a ...
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How does a gas behave if i let it out of a pressurised canister?

So I am working on a problem where I need to know how a gas behaves if it is let out of a canister. My first approach yielded some result, but i can't seem to get all the way, although it seems to me ...
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46 views

Difference between a reversible change and a reversible process?

Question In thermodynamics what is the difference between a reversible change and a reversible process? Additional information I am new to the topic of thermodynamics and getting confused about ...
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debye Specific Heat lattice

my Question is related to a two dimensional quadratic lattice. In our exercise we should find the Debye-Frequency wich is define as integral equal to 3N.In this case i get confused because it is a ...
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Heat flow through a pipe

I have a pipe, in which a cooling medium flows through it. I would like to know the temperature of the cooling medium at different lengths of the pipe. Is there an equation to relate the length and ...
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Does the skin effect, eddy current / hysteresis losses contribute to Johnson noise in an inductor?

Based on my very basic understanding of the Johnson noise, it's not just a DC phenomena, but should change with frequency in a system, where there is a frequency dependent, real component to the ...
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Is there any easy process that absorbs heat? [closed]

In our day-to-day life, many processes procure/release heat like: burning of fuel, friction, heat losses while converting one form of energy to another, natural processes even in our body tends to ...
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66 views

What is reversible and irreversible process? Can process below even be irreversible?

I heard the definitions, but I have much trouble understanding them. My teacher told me that in an example with two chambers and gas particles (look below) entropy increases, but I cannot understand ...
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34 views

Momentum which is transfered to the wall of container by a molecule

now I study thremodynamics course, and I cant understand why for ideal gas in equilibrium state when a molecule collides with the wall of container it transfers to it the momentum which is equals to ...
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Where do combustibles(gas etc.) fit into the first law?

The first law can be written as $dU=dW + dQ$. As I understand it $W$, work, is mechanical energy from winding up springs, things spinning, flying etc. It's kinetic and potential. As I understand it ...
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CMB and Gibbs free energy

I was doing my homework and I have a doubt. I proved that if I have the radiation energy density $$u = \frac{U}{V} $$ and $$P = \frac{1}{3}u $$ Then the Gibbs free energy is 0. But, how can I to ...
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94 views

How fast does heat travel via conduction?

I have read this question which seems to ask an identical question, but I'm not sure - it had far too many words I don't understand, let alone the equations. Perhaps someone can answer with a ...
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146 views

Why is it difficult to mix helium and nitrogen gases?

I recently learned an interesting fact: That it's difficult to mix helium and nitrogen gases in a compressed gas cylinder. Gas suppliers that need to mix the two gases have to rotate the cylinders for ...
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46 views

What does temperature coefficient of resistance depend on?

I tried looking up on Google if there was an expression for the temperature coefficient of resistance(TCR) of a material in terms of other fundamental factors, but couldn't find any. Specifically I am ...
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37 views

Monatomic gas work

Recently I was trying to solve the following problem: monatomic gas expanded from 0.2 to 0.5 m^3 and pressure increased from 404 to 808 kPa. Find work done by gas, heat gained and change in internal ...
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34 views

Negative absolute pressure with positive absolute temperature

Could I ask if the derivative defining pressure $dU \over dV$ or ${∂S \over ∂V}|_{E,N} $can be negative in processes occuring in system not cosmological but statistical(gases or solids or liquids-I ...
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Is there any experimental setup to test if we are Boltzmann brains? [closed]

I am not sure if this subject belongs to mainstream physics. my question is motivated by the fact that I am not sure we could ever test if we are Boltzmann brains. The same happens with string theory, ...
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Expansion of solids on heating

I read that when we heat a solid, it expands! Based on circumstances it can expand in area, length and volume! My question is , that do they expand to a certain extent or keep on expanding, if we ...
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1answer
114 views

The whole black vs. white T-shirt issue [duplicate]

I was outside with a friend the other day and we ended up talking about clothing choices in the heat, and he repeated the usual statement that one should wear white instead of black in order to stay ...
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229 views

Can temperature be a complex number?

Is it possible for a temperature to be a complex number? I want to say "no" but I can't be so sure. If it is possible I would like to know of an example. I found an interesting article which treats ...
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Newton's Law of Cooling on a calorimeter with two systems

Having the previous calorimeter with adiabatic walls, we've proven, based on Newton's law of cooling, that the equations are... $m_{b} \times C _{pb} \frac{\mathrm{d T_{b}} }{\mathrm{d} t} = ...
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Superconductors in a magnetic field — mixed phase

In my Stat Mech class we're learning about the phase transition between superconducting and non-superconducting metals in the presence of a magnetic field (Chapter 7, Kittel). I understand that the ...