Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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The relation between energy quanta of an Einstein solid and the equipartition value of heat capacity

Consider an Einstein solid with quantized energy values $U=q\epsilon$ and $N$ oscillators. I calculated some values of an Einstein solid numerically through a function in R (at the bottom of the ...
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53 views

A gas close to zero Kelvin

Consider an adiabatic expansion of an ideal gas that work is done against friction or a piston. Since no heat exchange can occur the gas keep on losing energy and its temperature decreases and the gas ...
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119 views

Is there a relation between (non-) existence of magnetic monopoles and thermodynamics?

This question follows on previous work on connections between (other) areas of physics and thermodynamics as in here, here and even here. P. Dirac (an electrical engineer initially) was one of the ...
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7k views

What is cp/cv ratio?

Recently in our chemistry class we read that the $C_p/C_v$ ratio of the inert gases is 1.66 thus they show inert nature. I asked my teacher what was $C_p/C_v$ ratio but he didn't answer me. So I want ...
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77 views

commutator to entropy in an uncertainty relationship?

Question: Does there exist a commutator to entropy in an uncertainty relationship? Similar Energy and time for instance.
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87 views

Can one get clear ice crystals from a dirty suspension?

Euteictic freeze crystallization is a method where an electrolytic solution is cooled and separated into a stream of (relativly) clean, pure ice and a salty brine. I know anectdotally of wine ...
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3answers
568 views

Why the temperature is getting lower when the universe is expanding

As we know, if an ideal gas expands in vacuum, as its energy is unchanged, the temperature remains the same. An ideal gas's energy does not depend on volume. In general, the energy is $kT$ times the ...
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276 views

The definition of entropy

As history of thermodynamics say, it was a mystery that what is the required condition for a given energy conversion to take place? Like there are two possible events each conserving energy but only ...
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3k views

Which is more efficient, heating water in microwave or electric stove?

So our propane tank in the kitchen ran out again today. Which is more energy efficient, boiling water in a microwave on an electric stove? All things being equal i.e. starting temperature and mass ...
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454 views

Steady State Temperature of an Object Orbiting the Earth

This may be irrelevant or stupid to ask but I couldn't come up with a good answer. At least, we could not agree on with my friend the other day. I would like an estimate of the temperature of a human ...
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2answers
10k views

Why does a gas get hot when suddenly compressed? What is happening at the molecular level?

My guess is that the molecules of gas all have the same speed as before, but now there are much more collisions per unit area onto the thermometer, thus making the thermometer read a higher ...
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3answers
777 views

Why is a hot air balloon “stiff”?

1) Why is a hot air balloon stiff? 2) Is the pressure inside the balloon higher than the pressure outside (atmospheric pressure)? 3) If the pressure inside is higher than the outside, how is it ...
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59 views

Density as a derivative of the Helmholtz energy

The equation of state for nitrogen has been formulated using the Helmholtz energy as the fundamental property with independent variables of density and temperature. The equation of state in ...
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120 views

Thermodynamic reversible process

My book says "A process is said to be reversible if it is carried out infinitesimally slowly so that in each step thermodynamic equilibrium of the system remains unchanged & any infinitesimal ...
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2answers
42 views

Followup to: The relation between energy quanta of an Einstein solid and the equipartition value of heat capacity

As a followup question to this question: The relation between energy quanta of an Einstein solid and the equipartition value of heat capacity and this answer ...
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176 views

Total multiplicity and entropy of Einstein solids

This is really a question to get a little more insight about a homework exercise. 1. In my text book, the sum of multiplicities for all possible macrostates is given to be: $$\sum ...
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2answers
238 views

Why is density an intensive property?

I am still trying to understand what are intensive and extensive properties. Possibly someone can give a pointer to a decent text (preferably on the web), as I am not too happy (to say the least) with ...
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84 views

Does the energy required to increase a volume of water's temperature increase as that temperature increases?

Obviously in a simple, classroom style experiment the energy required to increase water temperature is a constant and thus wouldn't change, but what if we made the experiment just slightly more real ...
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112 views

Can you extract energy from “hot” things without a temperature differential?

I've been reading about extracting energy from heat, particularly Sterling engines. There's always a temperature gradient. Heat flows from the hot side to the cold side through the working fluid. As ...
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59 views

EM Radiation and Heat

If there is EM radiation, will there always be a heat exchange between the wave and its surroundings? If you have an extremely energy-efficient light bulb that converts ALL the energy it receives into ...
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384 views

How is NASA's mod II Stirling engine so powerful yet so small?

Is it because of the temperature difference? I just don't understand how it can propel a car. Here's the link to the engine: ...
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2answers
169 views

Separation of variables in various PDEs, physical meaning

The method of separation of variables produces an undetermined separation constant and a family of solutions indexed by the values of this constant. For instance, in the case of an infinitely long ...
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3answers
83 views

Behavior of gasses, ideal and otherwise

I'm trying to help a child research a science project on refrigeration. Refreshing my incredibly rusty thermodynamics skills.... The ideal gas law: $PV=nRT$. Let's take air at STP: $P = 101\,kPa$ $V ...
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55 views

commutators in an uncertainty relationship derived from a partition function?

The maximum information principle for the discrete case gives rise to a partition function (>>> see details here) $$Z(\lambda_1,\ldots, \lambda_m) = \sum_{i=1}^n \exp\left[\lambda_1 f_1(x_i) + \cdots ...
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48 views

Negative temperature [duplicate]

How can we prove that if a negative-temperature system is in contact with a positive-temperature system, then the heat flow from the first to the second (and finally, the temperature of the second ...
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1answer
342 views

Can we make a Maxwell's Demon using Quantum Computers?

Although I'm reasonably sure that quantum computing advances will not lead to the ability to construct a machine that globally violates the 2nd law of thermodynamics, it feels like a difficult ...
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159 views

Determine the flow and amplitude equation for thermal energy (with Del operator)

It is a question vector calculus and Maxwell's laws. I put it this way. Let's say, we are working in a $3$-Dimensional space ( e.g $x\cdot y\cdot z = 4\cdot3\cdot2$, a certain room/class of that size ...
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358 views

Calculating temperature of water in the freezer

Assuming water volume ($V$), initial water temperature ($T_0$) and environment temperature ($T_e$) are known, what is the easiest way to calculate temperature of water in given time ($T$)? For the ...
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4answers
948 views

Maximum efficiency for a counter-current heat exchanger (double flux controlled motorized ventilation)

I am not sure if I can explain the question correctly because I don't know the name of this mechanism in English. This is my explanation attempt: In a house, a tube is expelling the air from the ...
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2answers
217 views

If I put 3 bottles of water next to each other in the fridge, which one is cold first?

I was wondering: If I put three bottles of water next to each other in the fridge, which one is cold first? Does it matter? Is it the one in the middle because it gets refrigerated by the other two? ...
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2answers
1k views

Extracting heat energy from a material

Does it violate any physical laws to take a portion of the energy out of a system and use it? Specifically I'm referring to heat. (Kinetic energy). For example, if you have a material which has a lot ...
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22 views

Boltzmann Distribution [duplicate]

I am trying to solve a problem about boltzmann distribution. If(A)=0.74 Uf(V)=0.037 Ia(A)=0.130 I have to find ...
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42 views

Temperature dependence for specific thermal diffusivity in the diffusion formula

I recently found this answer about the diffusion equation (nice one actually), but have one doubt about the temperature dependence of this formula. If the "packet" of energy (terminology suggested ...
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2answers
138 views

Heat loss using alternating current

I am looking for somebody who can explain this to me. As I have read in physics books, the Joule-Lenz Law (Joule effect of heating) is represented by the formula: $$ W = I^2Rt $$ which can be ...
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69 views

Why cannot wood be fully burnt?

Burning wood emits smoke and black. Provided more oxygen or whatever required, can wood be practically burnt fully like petroleum gasses that emits a blue flame and little smoke and little black.
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167 views

Energy Analysis of Niagara Falls in Linus Pauling's “General Chemistry”

I just started reading Linus Pauling's "General Chemistry" and the first example confuses me. He writes: Example 1-1. Niagara Falls (Horseshoe) is 160 feet high. How much warmer is the water at ...
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58 views

Adiabatic Expansion with expanding control volume

I have a tube with a length $L$ and diameter $d$ that is open on 1 side. At a certain point (say $x$) from the closed end of the tube, I have a gas with a high pressure. At this point, $x$, there is ...
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508 views

Difference between pressure and stress tensor

What is the difference between hydrostatic pressure and stress tensor?
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208 views

What would give us more heat ? infrared or microwaves?

As we know that our body is made up mostly of water and the frequency of vibration of water molecules matches that of microwaves which is the working principle of microwave ovens. When we come in ...
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49 views

How does pressurized gas constantly push?

If a gas, such as hydrogen, is pressurized into an air tight container, a force in terms of pascals (or whatever unit you want to use) is exerted, correct? That is what pushes against every surface ...
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125 views

What are the experimental observations behind the first principle of thermodynamics?

As far as I understand it, the first principle of thermodynamics is a mere definition of the quantity “Heat”: $$\text d Q: = \text d L + \text d U.$$ This is somewhat the point of view taken in ...
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2k views

Definition of “intensive” and “extensive” properties

Today I was asked what does it mean for a physical property of a system to be intensive. My first answer, loosely speaking, was: "It is a property that is local." I was specifically thinking ...
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211 views

Does brown but transparent swimming pool water heat significantly faster than western style highly chlorinated pools?

Eastern European swimming pools are often brown tinted water. i was told it was the color of the chemical to keep the pools clean, but who knows. These pools did not smell unsanitary and may have even ...
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234 views

Math for Thermodynamics Basics

I am studying Statistical Mechanics and Thermodynamics from a book that i am not sure who has written it, because of its cover is not present. There is a section that i can not understand: ...
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5answers
2k views

What is the most energy efficient way to boil an egg?

Starting with a pot of cold tap water, I want to cook a hard-boiled egg using the minimum amount of energy. Is it more energy efficient to bring a pot to boil first and then put the egg in it, or to ...