Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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SInce heat is a vibration in solids, isn't it just small scale sound? [duplicate]

On an atomic scale I think of electrons hitting positive ions in an electric lattice. Most energy there is heat energy. If I think of ball bearings flying through a large lattice, I think sound is ...
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77 views

On Thermodynamics of Spontaneity of the Reduction-Oxidation Chemical Reactions

According to the first and second law for a closed system containing different chemicals we have \begin{align} &\delta Q - \delta W = dU = T dS - p dV +\sum_i \mu_i d N_i\\ ...
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70 views

Modeling an Adiabatic Expansion (EES)

How would one model an isentropic (reversible) adiabatic expansion using thermodynamic software in order to determine isentropic work? What I am looking for is an actual pressure-volume curve for the ...
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54 views

About state function [duplicate]

As I undersand in thermodynamics, a gas with an equation of state $f(V,T,p)=0$ will need only 2 variables (e.g $V$ and $p$) to determine its state. Regarding this question: I still don't ...
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228 views

Difference between Residual Function and Excess Property

Sengers describes the deviation function as the difference of the actual mixture property and as determined from a model. If this model happens to be the ideal gas model, then it is also called ...
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20 views

Distribution of temperature in a plume of a jet

The exaust gases of a plume of a missile have a distribution in temperature and in density vs. distance from the nozzle. Using a CFD software it is quite simple to get such distribution. Is there some ...
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84 views

Units kT = 1… why?

Why is it convenient to choose units kT=1? It came up in this paper: http://jfi.uchicago.edu/~leop/SciencePapers/scaling%20and%20universality%20in%20statistical%20physics.pdf in page 4, equation ...
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160 views

is boiling of water an isobaric process?

Is the conversion of water into steam at 100°C an isobaric process? It is an isothermal process, but does pressure rain constant during this process?Please explain as well..
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21 views

I need to calculate the temperature of some flat copper wire as it loses contact with a chilled capstan roller

I need some help in designing a system for cooling wire as it comes off a resistance annealer. I need to calculate the temperature of that flat copper wire as it comes off a chilled roller (call it a ...
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164 views

How to prove R value for insulation?

I ran some tests on different types of insulation. I heated water, and placed it into an insulated box. The temperature was recorded every minute, for the water, as well as the air. The insulation ...
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86 views

Thermal Conduction through sphere

In general, a sphere with conductivity $\kappa$, heat capacity per unit volume $C$ and radius $R$ obeys the differential equation at time t: $$C\frac{\partial T}{\partial t} = \kappa \frac{\partial^2 ...
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132 views

How to calculate net power output of heated, expanding air?

I'm interested in designing and building a Stirling engine which uses air that has been heated, which expands and then acts upon a piston producing power. There is a fixed amount of air inside the ...
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46 views

Hamiltonian (temperature?) and frame of reference

So we can define a particle by defining its kinetic and potential energy, knowing that we can get a wavefunction describing a particle. But the kinetic energy involves motion, and motion can be ...
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32 views

If maximal work is extracted, in what manner does the heat flow between bodies?

There are two bodies starting with different temperatures and specific heat capacities (for simplicity assume that the bodies are solid to the volumes are constant). Let the rate of heat flow from ...
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63 views

Exception to weight of hot vs cold water?

I have seen the various posts regarding the comparison of weight of heated and cold water.But is there any contradiction?I live in really hot conditions and as such tap water literally 'boils' ...
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43 views

Which metal will be on the surface after solidification?

I know that there are some metals that just "like" to be on a surface, so if I make an alloy of such metal and some other metal, the first one will be on the surface after solidification of initially ...
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19 views

Water Displacement in the Oceans As a result of Global Warming [duplicate]

Not sure if this is the right place to ask this but here goes. If the north pole ice sheets melt, everyone agrees this would be a bad thing, however one of the reasons they state for this being a bad ...
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55 views

How to calculate the amount of energy in joules/s that gas oven uses?

I know there may be missing information, but my question is really simple and yet I haven't found an answer to it. To make things easy, let's assume we have a $40×40×40$ cm oven that we want to keep ...
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45 views

How come evaporation is possible? [duplicate]

If I have wet clothes and put them on the ground and let the Sun shine on them, they dry as water evaporates. But water should evaporate at 100 degrees Celsius so how come they go dry if it's just ...
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21 views

Understanding how clouds form: warm air near the earth's surface?

I'm trying to understand how clouds are formed. I've read that it begins with air near the earth's surface heating up. But I'm hearing two different reasons for how this happens: Air pressure near ...
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16 views

Does transverse flow always assist in mixed convection?

I am dealing with both natural convection and transverse forced convection over a flat plate. There are 4 different situations: Upward-facing cold plate Downward facing cold plate Upward facing hot ...
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113 views

Using Jacobians to prove an identity

I have to prove the identity $$ \left(\frac{\partial U}{\partial V}\right)_T=T\left(\frac{\partial p}{\partial T}\right)_V-p $$ I know how to do this using Maxwell's relations, but the assignment ...
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56 views

Landau free energy

I am reading the statistical mechanics by Pathria in Chap 12. I have a question about the Landau free energy. What is the physical reasoning for that the free energy could be a functional of the order ...
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80 views

Cooling power for cloud chamber

I'd like to build a small Peltier cell cooled cloud chamber. The cold surface would be a copper sheet with a surface of 200x200 millimeters. Is there a way to even guess the cooling power needed to ...
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18 views

Is there a way to tell the rate of temperature change due to provided energy?

Let's say we have an isolated system containing two bodies with different temperatures. The bodies are touching each other. Is there a way to tell how long will it take them to reach thermodynamic ...
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59 views

Proving $RTln(a_i)$ equal to non PV work done by system,where $a_i$ is activity

First of all many here will might say that it is Chemistry question.If you think so then read this article and then answer question. Question is --- We know chemical potential is defined as $\mu_i ...
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120 views

Heat flow in a hollow cylinder

Consider a hollow cylinder of different outer radius and inner radius and two different temperatures are maintained at the outer and inner surfaces such that inner temperature is higher. Because of ...
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267 views

If fans increase the heat of the air and this DIY AC decreases it, why don't they neutralize eachother?

Please try to answer in layman terms, i am only starting to study thermodynamics (And physics) In my book one of the curiosity parts gives that fans don't actually cool the room but by hitting the ...
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32 views

Natural refrigeration

I have an electricity-free pot-in-pot refrigerator that uses evaporative cooling to keep the inside cool. However, I live in a very humid place, so the rate of evaporation will be low and hence this ...
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33 views

Question regarding temperature as a property of a system

This is probably silly question but I got stuck while reading “Lectures on Theoretical Physics-Thermodynamics and Statistical Mechanics” by Sommerfeld. In the first chapter it says : Temperature ...
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126 views

Thermodynamics First Law Question - Expansions

Two thermally iso- lated cylinders, A and B, of equal volume, both equipped with pistons, are connected by a valve. Initially A has its piston fully withdrawn and contains a monatomic gas at ...
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23 views

What is Fermi energy and Fermi level? [duplicate]

What is meant by Fermi level and Fermi energy? And what is the difference between the two?
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84 views

Adiabatic Expansion with expanding control volume

I have a tube with a length $L$ and diameter $d$ that is open on 1 side. At a certain point (say $x$) from the closed end of the tube, I have a gas with a high pressure. At this point, $x$, there is ...
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38 views

Explain Heat Transfer

I would like to know what are these formulas used for. There is no intro about it in my book at all, and I am reading Heat Transfer book. If needed Q. can be edited.
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190 views

Determine pipe outlet temperature without length?

Let's say I am flowing a fluid through a pipe that has a constant surface temperature. Is it possible to determine the heat flux on the inner surface without knowing the pipe's length when the only ...
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44 views

Applied / environmental question: direction of exhaust fumes

I'm not sure the Physics StackExchange is the perfect place for this environmental/applied physics question, but as I found no forum more fitting I ask my question here. Otherwise please move my ...
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48 views

How hot is it on the slopes of an erupting volcano?

I was watching The Return of the King and just after Frodo and Sam destroy the One Ring, they run out of the mountain and hide on top of a rock as the volcano erupts and lava flows past them. Is this ...
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29 views

where i can find thermodynamics properties of octane

where can I find thermodynamics properties for octane at $T_s$? I need this properties or where can i find all ? $$liquid-density=\rho_l=?$$ $$vapor-density=\rho_v=?$$ ...
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106 views

Questions about the second law of thermodynamics

I can not understand the second law of thermodynamics and have trouble explaining the following questions: 1) In the tropics the water near the ocean surface is warmer than the deep water. Does the ...
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1answer
84 views

Modelling multiple heat sources?

I am working on a project to model heat transfer in a data center. I have basic models for a one dimensional heat transfer using conduction and convection. Such as, taking a server and modelling the ...
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45 views

Standard Heat of Combustion

When considering tabulated standard values of heat of combustion (∆H° combustion) or any other similar value, the results are reported for species in their standard states (1 bar pressure, 25°C, etc). ...
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100 views

Why Thermodynamic cycles and no single process

Why Thermodynamic cycles are used to obtain work for example carnot engine rather than single isothermal process which is part of cycle and can be used to obtain more work.And why isothermal process ...
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294 views

Caculating thermal stresses in a composite rod

The Question Between two rigid walls separated by a distance $l_1+l_2$, two rods of equal cross-section area $A$, and length, coefficient of linear expansion and Young's modulus $l_1, ...
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25 views

Finding out the temperature difference

If we add 10 spherical bubbles then there will be some change in their area. Is there any way to find out change in temperature of the liquid from the change of its area?
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96 views

Relation between a Quasistatic and a reversible process

Why is it that if a process is reversible, it is quasi-static? Does it mean that then the process is also non-dissipative if it is quasistatic?
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51 views

When heat is rejected by a system what will be $q$ according to sign convention?

When a system rejects heat it can be assumed that work is done by the system. So as per law the sign convention must be negative. But my physics textbook says the reverse. So is the question.
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22 views

Work of an adiabatic/ compresion: sign?

As far as I am concerned the adiabatic work it is given by: $$ W_{adi}=\frac{P_{f}V_{f}-P_{i}V_{i}}{\gamma -1}$$ While I have seen in other examples that it is used with $1-\gamma$ in the ...
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56 views

What creates black streams in fountain-type fireworks?

For the New Year celebration of 2014, my nephews set off a series of fountain-type fireworks (as shown below). When one looks carefully into the shower of light, one notices that a fair number of ...
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59 views

How does pressurized gas constantly push?

If a gas, such as hydrogen, is pressurized into an air tight container, a force in terms of pascals (or whatever unit you want to use) is exerted, correct? That is what pushes against every surface ...
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88 views

NPT simulations: what is the inertia of volume fluctuations (using periodic boundary conditions)?

NPT molecular dynamics (MD) are most often implemented by adding some kind of piston that regulates the pressure. The inertia of this piston determines the dynamics of volume fluctuations in the ...