Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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183 views

Latent heat of solidification

What is the heat release mechanism involved in solidification from liquid phase? Is the energy transferred to nucleation centres?
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73 views

Freezing or melting Brine

In the freezing of brine, is it possible to do it at a rater or in such a way that the water only freezes or the ice is somehow isolated? Or conversely is this possible in the melting of brine-ice?
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136 views

'Mechanical equilibrium does not necessarily mean that the pressure is same at all points of the system' - why?

If there are variations in pressure or elastic stress within the system,parts of the system may move, or expand or contract. Eventually these motions,expansions or contractions will cease, and when ...
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48 views

Explanation for Homogeneous Nucleation Temperature?

What is homogeneous nucleation temperature (for water this is listed as -42C); is it simply the lowest experimental temperature you can go before supercooled liquid turns into solid, or is it that ...
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20 views

Is it possible to cool magnetic dipoles with a magnetic static field?

Suppose you have a bath of magnetic dipoles, with a common mean rotational kinetic energy. Now you apply a very strong magnetic field so that the dipoles align with the field, thus "losing" their ...
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47 views

compressibility of cold atoms in optical lattices

The compressibility of cold bosons in an optical lattice is defined as $\kappa = \frac{\partial \langle n\rangle}{\partial \mu}$, where $\langle n\rangle$ is the density and $\mu$ is the chemical ...
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98 views

Estimating the effect of radiant barrier on the radiant and conductive heat transfer through a metal roof

The basic question is -- Will a radiant reflective coating be more effective applied to the upper surface or the lower surface of a metal? Case 1: Imagine a metal roof subject to solar heating. The ...
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48 views

How can entropic effects be prevalent at low temperatures?

I read in a book that at low temperature the hydrophobic effect (for example) is entropic but at high temperatures it is enthalpic. I thought that entropy should decrease at very low temperatures. ...
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244 views

Helmholtz free energy from a relation for entropy

The Legendre transformation defines the helmholtz free energy (at least according to my lectures) as: $F(T,V,N)=E-TS$ It also says to start with $E(S,V,N)$ and $T=\frac{\partial{E}}{\partial{S}}$ ...
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158 views

Monte carlo simulation for continuous spin model (e.g. XY or Heisenberg model)

Unlike the Ising model, the XY model and the Heisenberg model have a continuous spectrum. So one need discretize them for a numerical simulation. But how to make sure the discretization procedure ...
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357 views

Temperature change: boiling pasta in a lot of water or a little

SeriousEats gives a not-very-scientific representation of what looks like a thermodynamics calculation: Want to hear something even more interesting? Folks will occasionally say that "using a ...
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142 views

Showing the thermal expansion coefficient is the sum of the linear expansion coefficients

Given that the thermal expansion coefficient is defined as: $$ \beta=\frac{\frac{\Delta V}{V}}{\Delta T} $$ and the linear thermal expansion coefficient is defined as: $$ \alpha = \frac{\frac{\Delta ...
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77 views

If you dig a deep tunnel, will the rock sublimate?

If a tunnel is dug deep inside the crust (but before reaching places where the rock is liquid), how will the enormous downwards pressure manifest itself? Will the difference in pressure ...
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130 views

How many volcanic eruptions would be necessary per year to neutralize global warming?

Volcanic eruptions sometimes cool the earth. How many eruptions of what magnitude, locality and type would be required per year to neutralize Global Warming?
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65 views

Dark Matter as possible an explanation for Coronal Heating

It's my understanding that the mechanism behind Coronal Heating - why the Corona is so much hotter (> 1,000,000 K) than the surface of the Sun (6,000 K), and the mechanism by which the energy gets ...
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101 views

How to define the thermodynamic temperature

I've been reading derivations of the thermodynamic temperature scale. I'm assuming these are using Kelvin's method. I follow the math and the conclusion of the argument, but I don't understand how it ...
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97 views

Which function denotes the energy of thermal motion within a system?

In thermodynamics, the heat $Q$ is defined as a type of energy in transfer, and is not a state function, which function denotes the energy of thermal motion within a system? 1) $TS$, (there is a ...
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88 views

At what gap width between two plates does convection not occur?

Does the Grashof number lead to the answer? The Wikipedia article (https://en.wikipedia.org/wiki/Grashof_number) yields an equation for vertical plates $$Gr_L = \frac{g\beta(T_s-T_\infty ...
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564 views

Thermal Velocity

What is thermal velocity? What is it's physical significance? Wikipedia says: The thermal velocity or thermal speed is a typical velocity of the thermal motion of particles which make up a gas, ...
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66 views

Macro-Level Explanation of Fluid Heat Transfer

Here's something I've been struggling with for a while. Say you have a hot fluid and cold surface (or the reverse, so long as there is a temperature difference) where the fluid flows over the ...
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365 views

Energy comparison, evaporate water vs compress air, same mass

I would like to compare the energy requirements of the 2 following tasks: Total energy to evaporate 1 litre of water at normal atmospheric pressure at normal temperature? Total energy to compress ...
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113 views

conducting heat to infinity

I am modeling a situation in which an object that is a small object that is spherical in shape is receiving heat at a constant rate and then conducting it away into a medium that can be model as ...
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47 views

How many state configurations are possible for $N$ particles in completely different states?

How many state configurations are possible for $N$ particles in completely different states? I cannot remember if the total number of state configurations for $N$ particles in completely different ...
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1k views

Does the entropy of an adiabatically isolated system stays the same after we decrease/increase the pressure?

Even if the system is isolated and there is no heat exchange with surroundings, shouldn't the decrease/increase of pressure result in increase/decrease of entropy? Does this property of an ...
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124 views

Gibbs equation and third law of thermodynamics

I have seen a discussion of what would happen for an ideal gas expands irreversibly and adiabatically until absolute zero degree K. The entropy change is like that: Δs=Cv ln(T2/T1)+R ln(V2/V1) It is ...
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175 views

Does stew lose more liquid if stirred as it cools?

Suppose I cook a stew or soup and then take it off of the stove and leave it uncovered to cool. Of course, it will cool faster if I stir it (more surface area), but it will, eventually, cool to room ...
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83 views

Electromagnetic radiation and health issue

A lots of article even wiki tells that Cell phone radiation is very dangerous for health. Some people tell that it can be reason for brain cancer. A article Mobile phone subsides man’s sperms! ...
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27 views

Perfect Ideal Gas Modelization of Air

I'm solving a Thermodynamic problem. I have Air at temperature of 293.15 K, and pressure of 20 MPa. I would understand if is possible to consider this an Ideal Gas or not (and if is possible which are ...
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54 views

Thermodynamic potentials and approach to equilibrium

I have seen some material which tries to show that when approaching equilibrium upon different constraints, the changes in some thermodynamic potential is always positive or negative (for example, ...
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50 views

Does a surface in front of a radiator (not in contact) have a significant effect on the room's temperature or heating rate?

Does a surface in front of a radiator (not in contact) have a significant effect on the room's temperature or heating rate? Some time ago I had a discussion about it, and despite none of us knowing ...
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36 views

Can the thermal energy in an object be aligned, creating a thermal jerk?

Thermal energy is related to the speed at which atoms vibrate, therefor thermal energy is a form of motion. In a stationary object, all of these vibrating atoms 'impact' each other in such a way that ...
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91 views

Steady state average of physical quantities

Consider the following Hamiltonian: $$ H = \sum_n \left[\dfrac{p_n^2}{2m_n} + U(x_l) + V(x_{l+1} - x_l) \right], $$ that corresponds to a 1-D system of particles with nearest-neighbor interactions ...
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94 views

Chemical potential in terms of temperature and pressure

For part (a), I know how to take the partial derivatives of S to get chemical potential, pressure. But there seems that I still need one equation to correctly express chemical potential in terms of ...
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126 views

Would adding water after heating decrease the overall heat, when compared to adding the water before heating for the same period of time?

I was rather cold last night, and warmed up a cup of water to drink in the microwave. I put it in for 60 seconds, but it came out boiling hot, so I put a bit of cold water in with the hot water, and ...
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85 views

Thermal Physics, Specific Question [closed]

Question: The melting point of copper is 1080 degrees Celsius and its heat of fusion is 200 kJ/kg. If a copper coin at this temperature is completely melted by the absorption of 2000 J of heat, what ...
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294 views

How hot does the upstairs need to be before it will heat the basement through convection?

During the winter we keep the basement door closed so that the cold air from upstairs won't flow into the basement. Then we heat the basement and the upstairs gets heated partially by conduction ...
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2answers
279 views

Information or Matter or Energy

Which one is the most fundamental of the universe? What it is made of? Physicists are searching for unique and fundamental form. The question is , information is more fundamental than energy ? ...
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461 views

What does 1/k represent regarding Newtons Law of Cooling?

What does 1/k represent regarding Newtons Law of Cooling? I know k represents the cooling constant. I think the inverse of k is the time taken for the liquid to cool from its maximum temperture to ...
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2answers
507 views

Isobaric expansion work, W = p(V2-V1) [closed]

Isobaric process, so $W = p\Delta V$ according to my book. We have 10 kg of saturated steam at $x = 0.9$, P = 200 kPa. We add work at a rate of $700 W$ and we're interested in the time it takes. We ...
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74 views

Thermodynamic entropy vs. quantum mechanical entropy

Is there a fundamental difference in the definition of entropy when considering the classical thermodynamic picture vs. the quantum mechanical picture, or are they both fundamentally equivalent?
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121 views

Thermal resistance of thermal interface materials?

Thermal conductivity are often used for surfaces between the computer chip and the heat sink to increase heat transfer and they want high thermal conductivity to decrease the thermal resistance. By ...
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505 views

Latent heat of vaporization

The molecular weight of water is 18.015 gram. The number of moles of water in one liter (1000 gram) will be: $3.34\times 10^{25}$ molecules (in 1kg). We know that latent heat of vaporization of water ...
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66 views

In what forms do fire energy transfer in common situations

Yesterday I was standing by the campfire. I used to think that campfire heat carried to me only by air. It was heating my face too much, so I blocked it with my hand just like blocking the sun. Then ...
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2answers
55 views

Is there an analogue to the role of vapor in liquids and gases, but for solids and liquids?

It seems common for an ordered phase to have some amount of disorder present. For example, the average moment of a ferromagnet is less than maximum except at T=0 due to the presence of fluctuations. ...
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296 views

Time to heat/cool a room

So, I have a basic, very basic, understanding of thermodynamics. I don't take it until next semester. I'm attempting to write a program which plots a temperature over time graph of a room being ...
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2answers
136 views

Which thermoelectric effect is better?

I am doing an experiment which requires the thermoelectric effect. I know about the Seebeck and the Peltier effects. Well, from what I have found till now on these topics is that they both can produce ...
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198 views

Carnot Engine Work from Heat Exchanger between Two Gas Streams

To be clear, this is not a homework question, but it is something I am studying for an exam. The question is about a hilsch tube which separates a stream of high pressure air to a high temperature ...
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86 views

Ideal gas system with diathermic piston externally manipulated

I wanted to ask about the following problem: An ideal monatomic gas is separated into two volumes $V_{1}$ and $V_{2}$ through a diathermic piston, such that each volume containing $N$ atoms and the ...
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52 views

Thermodynamics of zinc chloride to zinc

I am trying to deposit zinc metal from zinc chloride using chemical vapor deposition. But it is thermodynamically feasible to obtain zinc from zinc chloride?
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27 views

Delayed Phase Transition at Condensation of a Gas?

It is known that super heated liquids do exist, eg. when purified water is carefully heated above its boiling point. However I've never heard of subcooled gas having a temperature below its saturation ...