Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

learn more… | top users | synonyms (3)

0
votes
0answers
10 views

Adding thin films to a Peltier Device

I am using a peltier device maintaining a constant gradient by applying a voltage/current. My current setup is: Cold Side Peltier Device Hot Side CPU fan Was just wondering forgetting time ...
0
votes
0answers
19 views

Making Pudding; A complicated non-equilibrium statistical process?

There are a lot of non-equilibrium processes examples given in physics literature. But some processes that are present in everyday life are not treated. As an example, the formation of pudding can be ...
0
votes
0answers
22 views

Heat engine with three thermal baths

I was wondering if we can surpass the efficiency of the Carnot engine with three thermal baths, so my question is: Is the most efficient heat engine among three temperature reservoirs a cycle ...
0
votes
0answers
21 views

What happens when heating water in a pressure vessel?

Suppose that I take a pressure vessel that can hold up to 2000PSI force. Now I fill it with water (not completely, but around ~90%) and now I start to heat it with direct flame, LPG gas cylinder. What ...
0
votes
0answers
25 views

Theoretical efficiency Diesel vs Otto

The efficiency for the otto cycle is defined as: equation 1: $$ n_{otto} = 1 - \frac{T_4-T_1}{T_3-T_2} $$ which can be expressed in terms of the compression ratio: equation 2:$$ n_{otto} = 1 - ...
0
votes
0answers
18 views

How to prove mathematically that the work done during irreversible process is least due to viscosity stress?

This is a known fact that the work done by the system is maximum during reversible processes & least during irreversible processes owing to the viscosity stresses. But can we prove it ...
0
votes
0answers
24 views

Heat Retention of Wine

This may seem odd and lengthy but I am going to attempt to consolidate my thoughts as much as possible. I'm sorry in advance for the length of my post and if this is confusing. I am currently ...
0
votes
0answers
30 views

Does the density of water ice (any form of water ice) near 0K exceed the density of water at 277.15K?

In a question brought up by my chemistry class, the most we have determined is that the stability of most forms of ice decreases as the temperature decreases. What does this loss of stability do to ...
0
votes
0answers
27 views

How to calculate electrical and thermal conductivity, enthalpy and density of plasma column in air for a series electric arc?

I am modeling an electric arc according to "Lowke's Simple theory of free burning arc". Its a very interesting theoretical arc model and I want to implement it in Matlab/Simulink. But here, the arc ...
0
votes
0answers
12 views

How to find specific volume of air beyond normal Psychrometric table

During a calculation of direct-heat dryer, I have ended up with following situation. Inlet temperature of solid TS1 = 35.5 oC Inlet temperature of air TG2 = 615.0 ...
0
votes
0answers
46 views

Was the impossibility of the second degree perpetuum mobile in the General Relativity ever proven?

Somewhere I've heard, that gravity often likes to work against the entropy. For example, the surprisingly low temperature of the black holes. Or see the gravitational separation of different elements ...
0
votes
0answers
27 views

Can I measure the volume of a locked room by pumping gas through keyhole and measuring its entropy?

Suppose that I have a locked room and a keyhole in the door and I want to measure the room's volume. Suppose also that I have some "magical" "artificial" inert gas A that doesn't interact with ...
0
votes
0answers
59 views

Why does specific heat increase with temperature?

Except for monoatomic molecules, specific heat increases with increase in temperature. Why?
0
votes
0answers
15 views

Is Isochoric compression or expansion possible?

Stirling cycle is made of two isothermal and two isochoric processes. Heat is added isothermally, expansion and compression takes place isochorically, as given by the book. How can a gas be ...
0
votes
0answers
59 views

Equipartition theorem and virial theorem differences?

The classical virial theorem and the classical equipartition theorem are clearly related. A version of the virial theorem is, \begin{equation} \bigg\langle \sum ^{3N}_{i=1} x_i\frac{\partial ...
0
votes
0answers
30 views

Sign convention thermodynamics

Say a system is inside a volume $V$ with surface normal vector $n$ pointing out from the volume. Then there are force vector fields (nonconservative and conservative) depending on parameters external ...
0
votes
0answers
30 views

Efficiency of an Internal Combustion Engine

This question is about How correct are those comments on efficiecy of internal combustion(IC) engines which calcuate it using 2nd law of thermodynamics.The maximum efficiency of a heat engine can be ...
0
votes
0answers
19 views

Maxwell relations | U goes down pressure?

Differentiating Helmholtz function $ A = U - TS $ with respect to $V$ we get: $$ (\frac{\partial A}{\partial V})_{\scriptscriptstyle T} = (\frac{\partial U}{\partial V})_{\scriptscriptstyle T} ...
0
votes
0answers
16 views

When is strain rate constant?

I have started a tricky problem involving strain rates. To simplify it I was wondering if I can assume the strain rate is constant (and therefore that the shear stress is constant with distance above ...
0
votes
0answers
14 views

Reaction enthalpy-work relationship in a closed piston-cylinder assembly undergoing a chemical reaction

In an closed and insulated piston-cylinder assembly under constant pressure. From first law I should expect $-p(V_f-V_i) = U_f – U_i$ and thus $H_f = H_i$ and $h_f = h_i$. If an exothermic reaction ...
0
votes
0answers
30 views

Change in internal energy

One definition in my textbook states that total derivative of internal energy $dU$ has the form: $$dU = C_vdT +(\frac{\partial U}{\partial V})_{\scriptscriptstyle T}dV $$ Which I interpret this way: ...
0
votes
0answers
27 views

How accurate is the Callendar-Van Dusen equation?

... over 0 degC to 100 degC? The equation itself can be found here I can do a very accurate one point calibration of a 1/10 DIN PT100 sensor at 0 degC. If I use the equation to correct for non-linear ...
0
votes
0answers
57 views

How much sunlight would 'fit' through a fibre optic cable?

Say a parabolic mirror were used to focus the full sunlight spectrum into a single strand of optical fibre. Assuming ideal conditions (perfect reflecting surface, focal point smaller than diameter of ...
0
votes
0answers
22 views

Must irreversible heat transfer be quasistatic?

Suppose there is an isolated system composed of two subsystems $A$ and $B$ in thermal contact with each other, but mechanically and diffusively insulated from each other. The system starts off with a ...
0
votes
0answers
41 views

Does mixing violate conservation of energy?

If two fluids in an isolated system mix, the entropy of the system increases. The volume and the number of particles in the system, however, are constant. Thus $$dU=TdS+PdV-\mu dN=TdS>0$$ which ...
0
votes
0answers
33 views

How does a gas behave if i let it out of a pressurised canister?

So I am working on a problem where I need to know how a gas behaves if it is let out of a canister. My first approach yielded some result, but i can't seem to get all the way, although it seems to me ...
0
votes
0answers
21 views

debye Specific Heat lattice

my Question is related to a two dimensional quadratic lattice. In our exercise we should find the Debye-Frequency wich is define as integral equal to 3N.In this case i get confused because it is a ...
0
votes
0answers
31 views

Heat flow through a pipe

I have a pipe, in which a cooling medium flows through it. I would like to know the temperature of the cooling medium at different lengths of the pipe. Is there an equation to relate the length and ...
0
votes
0answers
32 views

Where do combustibles(gas etc.) fit into the first law?

The first law can be written as $dU=dW + dQ$. As I understand it $W$, work, is mechanical energy from winding up springs, things spinning, flying etc. It's kinetic and potential. As I understand it ...
0
votes
0answers
29 views

CMB and Gibbs free energy

I was doing my homework and I have a doubt. I proved that if I have the radiation energy density $$u = \frac{U}{V} $$ and $$P = \frac{1}{3}u $$ Then the Gibbs free energy is 0. But, how can I to ...
0
votes
0answers
33 views

What does temperature coefficient of resistance depend on?

I tried looking up on Google if there was an expression for the temperature coefficient of resistance(TCR) of a material in terms of other fundamental factors, but couldn't find any. Specifically I am ...
0
votes
0answers
22 views

Expansion of solids on heating

I read that when we heat a solid, it expands! Based on circumstances it can expand in area, length and volume! My question is , that do they expand to a certain extent or keep on expanding, if we ...
0
votes
0answers
22 views

Superconductors in a magnetic field — mixed phase

In my Stat Mech class we're learning about the phase transition between superconducting and non-superconducting metals in the presence of a magnetic field (Chapter 7, Kittel). I understand that the ...
0
votes
0answers
35 views

Does a fixed amount of gas have slighty more mass when at a higher temperature?

According to relativity, energy and mass are equivalent. Does this mean that the energy added to a fixed amount of gas when it is heated adds slightly to the mass of the gas? The difference would be ...
0
votes
0answers
37 views

Determine the amount of energy used for baking a cake

Let's suppose we have a room of temperature $T_0$ with an oven of volume $V$, both filled with air of density $\rho$ and specific heat $c$. We need to bake a cake in the temperature $T_1$. Thus we ...
0
votes
0answers
36 views

Filling an empty box with ambient air

A rigid box has a volume of $V_1$ and is thermally isolated so that it exchanges no heat with its environment. Initially the box is empty, and the air around it has a pressure of $P_0$ and a ...
0
votes
0answers
57 views

If time somehow went backwards would this violate one of the laws of thermodynamics?

If time somehow went backwards and all the physical events that had occurred in a sequence , would some of the events occurring 'backwards' or in the reverse order violate the principle of entropy or ...
0
votes
0answers
32 views

What do physicists mean with “classical critical behaviour”?

What do physicists mean with "classical critical behaviour"? As far as I am concerned it should be "power law behaviour" of some quantity close to the critical point but I ask here to be sure.
0
votes
0answers
45 views

Specific heat capacity for constant volume and constant pressure

I have seen in some exercises that the specific heat capacity for constant volume, $c_{vo}$ and the specific heat capacity for constant pressure, $c_{po}$ , where the $o$ indicates that we are ...
0
votes
0answers
12 views

What is the heated added and changes in internal energy? thermodynamics

A piston + cylinder initially contains 2 x 10-3 m3 of helium gas at the pressure of 1.01 x 105 Pa and with a temperature of 60'C. The gas is heated allowed to expand at a constant pressure until its ...
0
votes
0answers
13 views

Chemical potentials of SM particles at high temperatures

Recently I've heard the statement that chemical potentials of SM particles on $T > 1 \text{ GeV}$ are very small, so that Gibbs potential reduces to free energy. How to prove this statement? Does ...
0
votes
0answers
27 views

Internal energy of a molecule and bonding strength

I had a lecture on thermodynamics. I was told that the bond strength, $\epsilon$, is related to the latent heat of sublimation, $L_s$. $L_s\approx L_f+L_v$ if the melting and boiling points are close, ...
0
votes
0answers
40 views

Entropy of a system of gravitationally interacting particles

Lets suppose there is a container in space where there are some particles moving very fast. But due to gravitational attractions between the particles they would just come to a corner of the box. ...
0
votes
0answers
18 views

Why is the boundary layer thinner on the outside of an outer wall versus the wall inside the house

The convection on the outer suface of the outer wall of a house is larger, because outside a house it's more windy compared to inside. More wind means more turbulence which leads to more transfer of ...
0
votes
0answers
79 views

Why is there steam in a hot shower even though the water is not boiling?

When I take a hot shower, there is normally a fair amount of steam. However, I don't think the water coming out of the shower-head is actually boiling (unless I am mistaken). Why is there water ...
0
votes
0answers
42 views

Why do some materials have a negative coefficient of thermal expansion in all directions?

Those materials are especially ceramic-glasses. I've found some studies about how does it happens in one dimension (for example a nanocrystalline has a silica helix that works like twisting spring, ...
0
votes
0answers
37 views

Thermodynamics of a rubber band

I have a streched rubber band and I know that tension f is proportional to the temperature T when the length is constant. How can I proove that internal energy is only a function of temperature? I ...
0
votes
0answers
31 views

How complex is an energy balance for this problem?

Let's say I have an enclosed room in the shape of a box with forced airflow on the outer walls at an ambient temperature. Each end of the room (forward and rear) has a vent that ducts in warm air to ...
0
votes
0answers
48 views

Canonical or microcanonical ensemble?

What of this ensembles is more honest with natural thermal equilibrium? In microcanonical ensemble the sample is isolated, and we don't now the precise value of energy. By this considerations we have ...
0
votes
0answers
44 views

Physical interpretation of legendre transformations in thermodynamics

I have found this question(Physical meaning of Legendre transformation) and I have some questions regarding the transformations in thermodynamics, In thermodynamics we have: $$H= U+PV $$ $$F=U-TS ...