Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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276 views

How is the logarithmic correction to the entropy of a non extremal black hole derived?

I`ve just read, that for non extremal black holes, there exists a logarithmic (and other) correction(s) to the well known term proportional to the area of the horizon such that $S = \frac{A}{4G} + K ...
7
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1answer
126 views

Is there a true parallel between Gibbs' phase rule and Euler's polyhedral formula?

Gibbs' phase rule states: $$F=C-P+2$$ where $F$ is number of degrees of freedom, $C$ is number of components, $P$ is number of phases. Euler's polyhedral formula states: $$V+F-E=2$$ where $V$ is ...
5
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1answer
624 views

Adiabatic expansion in van der Waals gas

Given a Van der Waals gas with state equation: $$\left( P+\frac{N^2 a}{V^2}\right)\left( V-Nb \right)=NkT,$$ show that the equation of an adiabatic process is: $$\left( ...
4
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1answer
58 views

Self Stirring Boiling Liquid

A couple of weeks ago, a friend and I were brewing a new batch of beer. We boil our wort in a turkey fryer. Pretty standard setup for beginners. Anyway, our wort was getting pretty close to boiling ...
4
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1answer
101 views

Considerations and questions for a DIY heat pipe; how to choose a working fluid?

I plan to build a DIY heat pipe! For more info on what a heat pipe is, see Wikipedia. I would like to use it to cool a desktop graphics card I have. I am having trouble deciding how to choose the ...
3
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1answer
64 views

Radiation emission and absorption

Any object can emit and absorb radiation and the power of emission can be represented by the Stefan-Boltzmann law: $$P=A\epsilon\sigma T^4$$ In many texts the net power radiated is the difference ...
3
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1answer
47 views

Problems with units of entropy in statistical thermodynamics

The statistical thermodynamics definition of entropy: $S = kN \ln (W)$ troubles me a lot with the problem of dimenstions. where $S$ is entropy; $k$, the Boltzmann constant; $N$ the number of particles ...
3
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1answer
85 views

Explicit form of the entropy production in hydrodynamics

I'm trying to understand how hydrodynamics arise from a precise, mathematical formulation of thermodynamics, learning mostly from Landau's "Hydrodynamics". So Landau starts from formulating the ...
3
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1answer
120 views

Hysteresis and dissipation

Hysteretic phenomena are often linked to dissipation. When there is an hysteresis loop, the dissipated energy can usually be computed as the area of the cycle. For example, in ferromagnetic ...
3
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1answer
743 views

Simple thermodynamics basics - can internal energy be calculated?

Well this got me stumbled, because I've been wondering what the "question" is. One of the example examns got the following question (strangely there are no supplied solution books): A $0.2 {\rm ...
3
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1answer
113 views

Amount of energy to separate Gases - relationship to concentration

I want to understand the efficiencies of separating mixed gases, and for that I want to understand the thermodynamic limit case. Looking at the wikipedia page for entropy of mixing, I find the ...
3
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1answer
298 views

Does a negative line tension in a 3-fluid immiscible interface make sense?

This question is inspired by this question/answer pair: Is this formula for the energy of a configuration of 3 fluids physically reasonable? Consider three immiscible fluids forming contact surfaces, ...
3
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1answer
393 views

Coffee cooling in a cup

Will coffee in two differant size styrofoam cups in the same room conditions cool at the same rate? One cup is 8 oz. and the other would be 12 oz.
2
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1answer
19 views

Thermal expansion coefficient times temperature: under which condition is it unity?

In Landau's Fluid Mechanics p. 8 (2nd edition) he writes for the thermal expansion coefficient $\beta = (1/V) (\partial V/\partial T)_P$: For a column of gas in equilibrium which can be taken as a ...
2
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1answer
74 views

Which air will give more effective cooling ? Dry or Moist?

Yesterday, I had an innovative idea. I live in India, and in summer season, the temperature can reach up to 45 degree Celsius. We use Split 1.5 Ton AC in our small office. The idea is to put an ...
2
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1answer
62 views

How to use specific heats and temperature change in a system to calculate mass?

In a system where multiple liquids and solids are mixed together with different specific heats at different initial temperatures, reaching an equilibrium temperature, how do all of these things relate ...
2
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1answer
100 views

Thermodynamics, chaperones : How to model polymer fragmentation

Living polymers are well described by equilibrium statistical physics. Now I would like to consider a case were living polymers undergo fragmentation due to chaperones. I can think of a kinetic ...
2
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1answer
85 views

Lennard-Jones induced pseudo-molecules

It can be shown that the Lennard-Jones potential - which describes the interaction between particles in non-ideal gases - gives rise to pseudo-molecules: after a triple "collision" of three ...
2
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1answer
76 views

Rayleigh-Taylor Instability dependence on acceleration direction

I'm trying to bolster my understanding of the Rayleigh-Taylor instability, and I've gotten stuck on the point of which fluid (more or less dense) is being accelerated into the other. Cases of uniform ...
2
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1answer
330 views

What defines the adiabatic flame temperature?

What defines the adiabatic flame temperature? In a case I have to solve, I need to describe the combustion of natural gas (Groningen natural gas, to be specific). However, I am having some problems ...
2
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1answer
1k views

Finding electric power generated using heat transfer

I'm working through an example I have been given to study. Suppose I have a 2m X 4m photovoltaic panel on my roof that is irradiated with a solar flux of $G_s = 700W/m^2$. Given: $\alpha_s = 0.83$ ...
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1answer
26 views

what property of steam makes it the preferable motive fluid in jet ejectors? why not air or nitrogen?

I want to know what properties of steam make it the fluid of choice in steam turbines jet ejectors. I want to understand the mechanism of energy conversion in these equipment and hence understand ...
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329 views

Making an equal amount of positive and negative energy?

I was wondering if it would be possible to create an amount of positive energy out of a vacuum, in addition to an equal amount of negative energy, thus not violating the first law of thermodynamics, ...
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83 views

Best material for heat transfer between ice and water

What is the best container material for heat transfer between ice and water? this is a difficult question to ask without displaying a picture of what I'm meaning.
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15 views

Calimetric Perfect Ideal Gas

What is the energy equation when you have a ridgid adiabatic open system where you have a mass flow rate in and a mass static inside the system?
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31 views

Is there a thermodynamic law or theorem that expresses how systems “break” or “change” when enough energy is added?

I have a simple question about thermodynamic laws, and I am hoping you can help me. Let's say that I have a sphere container with some pressurized gas in it. I can slowly increase the pressure over ...
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269 views

What is an accurate equation for joule heating?

I know two different equations that provides the joule heating effect. The first one only depends on the potential ($\varphi$) and the electrical conductivity ($\gamma$) and can de modeled based on ...
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96 views

Rotary Steam Engine

Leon Crux invented the concept of interlocking archimedes spirals that eventually led to the scroll compressor but intended it to be used as a rotary steam engine. However technological limitations of ...
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0answers
48 views

What is the relationship between strain and electric current?

Strain or stress can be caused by different sources. I categorized theses sources as mechanical, thermal and electrical loads and formulated the total stress as follows: $$ \epsilon_{total} = ...
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0answers
30 views

Decompression cooler

How would I figure the needed pressure differential to freeze water inside a cooler using ambient air? I am assuming that the combined gas law would apply here and that the formula P1•V1/T1=P2•V2/T2 ...
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100 views

Please correct my understanding of Clausius-Clapeyron and latent heat

As I work a problem set, I'm being asked to calculate the latent heat associated with a particular phase transition of $NH_3$ (solid -> liquid, liquid -> gas, solid -> gas). I'm being told to perform ...
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34 views

How to compute the change in entropy of s system when the temperature is decreasing?

How to compute the change in entropy of s system when the temperature is decreasing? Such a question may be too general,then we may ask a special case:How to compute the change in entropy of Annealing ...
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181 views

Constant Pressure lines in evaporation diagram

Assume that there is the following $T-H$ phase diagram with the constant pressure lines. Which is greater preasure? The preasure drops as we move to lower temperatures (i.e. from top to bottom)? ...
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245 views

Triple point temperature and freezing point

Why does the triple point temperature have very similar values to the freezing point, in most substances?
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231 views

How does the volume change affect an adiabatic process?

A gas consisting of rigid diatomic molecules was initially under standard conditions. Then the gas was compressed adiabatically, 5 times the original volume. Find the mean KE of rotating molecules ...
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40 views

How connected thermodynamical stability and dynamical stability for black holes?

Criteria for thermodynamical stability is the convex of entropy. But for black hole entropy is non-additive.
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55 views

Lambda transition data points of $\require{mhchem}\ce{^4He}$

I'm looking to get some data on the lambda transition of $\require{mhchem}\ce{^4He}$. I need the data points of the specific heat vs. temperature graph, if that makes sense.
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46 views

Heat of adsorption from fugacity data

I have a set of data relating the fugacity ($\approx$ pressure) to the loading for a given set of temperatures. There are three temperature sets each having five fugacity vs. loading points. The ...
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60 views

Increase in number of micro states explanation or restatement of second law?

Is the boltzmann's expression of entropy as log of micro states leading to the formulation that system is more likely to be in a macrostate with more no. Of micro states really is an explanation or ...
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80 views

Landauer's principle vs Rayleigh–Jeans law

Can we argue based on Landauer's principle that if one bit information is changed inside a blackbody, the total radiated energy should be at least or in order of $kTln2$? If it is so, can we also ...
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411 views

Entalpy and entropy role in freezing-point depression phenomena

There's this "atomic" explanation of the freezing-point phenomena on Wikipedia that leaves me really intrigued. Consider the problem in which the solvent freezes to a very nearly pure crystal, ...
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93 views

Using thermodynamics and Kinematics together to solve a parachuter problem?

I need to find a parachutist's displacement after a given height (nearly 37000m) and at a given latitude. I have his mass, area, parachute area, drop height, parachute deployment height, data about ...
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194 views

Constant volume specific heat

A monatomic ideal gas is confined to move in two dimensions. What is the constant volume specific heat for this gas? Consider a system of N independent harmonic oscillators moving in two dimensions. ...
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368 views

Carnot Engine for Finite Reservoirs

Two solid, finite thermal reservoirs have temperatures of $T_1$ and $T_2$ respectively and an engine operates between the two. Assume $T_1 > T_2$ and that each reservoir has constant heat capacity ...
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476 views

Carnot efficiency, coefficient of performance for a refrigerator

I was reading that a new type of refrigerator might reach a coefficient of performance (COP) of 10. This seems quite the achievement and the authors state that their approach might achieve a Carnot ...
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141 views

direct conversion of heat to electric potential / current - are there theories that contradict the 'Kelvin Statement'?

In particular, William Thomson (Kelvin) appeared to be wrong about key things in physics (initially X-rays, aether, even aviation feasibility). ...
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2k views

How to determine size of a Heat Exchanger?

I am designing a Tube heat-exchanger, similar to this: My process requires water (at room temperature, 18C ~ 22C) that is being pumped out of a small tank (300 Liters) to be heated in a ...
0
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0answers
156 views

what is the physics just at bubble formation.

ie do a couple of molecules with more energy bang out a volume in the liquid where molecular attraction is overcome and the energetic molecules can move at random? where can I find out more about ...
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0answers
134 views

2 streams going into an engine and 2 come out. Find the enthalpy?

Problem: Steam supply to an engine is made of two streams that mix before entering the engine. Stream 1 flows at a $.01\frac{kg}{s}$ with an enthalpy of $2952\frac{kJ}{kg}$ and a velocity of ...
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1k views

What is the insulative value of water?

I am having a hard to finding what the R value of water is. I am trying to compare it to Styrofoam (which has an R-Value of 5). EDIT Based on the assumption that water has an insulating property, ...