Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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How much disolved oxygen is removed by boiling water?

Apologies if this is a chemistry question I've read that drinking water contains dissolved oxygen to the tune of $10\:\rm{ppm}$. I've also read that raising the temperature of water will remove some ...
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1answer
637 views

Can we explain physical similarities between Black Scholes PDE and the Mass Balance PDE (e.g. Advection-Diffusion equation)?

Both the Black-Scholes PDE{*} and the Mass/Material Balance PDE have a similar mathematical form of the PDE which is evident from the fact that on change of variables from Black-Scholes PDE we derive ...
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417 views

What's the validity of the thermodynamic definition of entropy?

Thermodynamic Entropy Variation is defined as $$\Delta S = \int_i^f \frac{dQ}{T},$$ where $i$ and $f$ are the initial and final states of the process. My question is: does this equation apply to ...
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3answers
1k views

Using 'Euler's Homogeneous Function Theorem' to Justify Thermodynamic Derivations

I've been working through the derivation of quantities like Gibb's free energy and internal energy, and I realised that I couldn't easily justify one of the final steps in the derivation. For ...
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118 views

What is a qualitative explanation for order of values of standard entropies of formation for isomers of hexane?

I have literature values for the standard enthalpy and Gibbs energy changes of formation at 298 K, $\Delta H_\text{f}^o$ and $\Delta G_\text{f}^o$, for product in the ideal gas state. Since $G=H-TS$ ...
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232 views

Hygiene thermodynamics 2

Two kinda related questions here: Is evaporation rate and temperature difference related? There is an experiment of pouring cup of hot water out the window during winter. The water evaporates almost ...
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2k views

Sauna thermodynamics

Why does it get hotter (feel hotter) in a sauna when one pours water over the hot stones? Wikipedia says that the water condenses onto the skin, but the actual air humidity is so low that I doubt ...
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4k views

Will the hole on a metal disc expand or contract upon heating? [duplicate]

Possible Duplicate: Will a hole cut into a metal disk expand or shrink when the disc is heated? The metal disc of diameter D1 has a hole in it and the diameter of the hole is D2 (D2 Now, ...
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82 views

Is there an abstract notion of heat within a microscopical system?

The microstates of a system are said to be unobservable. I can introduce the entropy as a measure of the number of microstates, which lead to the same macroscopic variables. So in this detailed ...
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231 views

Centrifugal Compressor Flow Rate

For a centrifugal compressor, as found in most turbochargers on internal combustion engines, is there a noticeable change in flow rate versus a naturally aspirated flow rate? In other words, does the ...
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259 views

Black body balloon in vacuum [closed]

The problem statement, all variables and given/known data There is a perfectly spherical balloon with surface painted black. It is placed in a perfect vacuum. It is gently inflated with an ideal ...
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78 views

Good references for specific heats

Does anyone know of a good reference for specific heats? It seems that it is no longer popular to publish values. I am especially interested in the specific heats of polymers.
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724 views

Heat absorbed by a room

How can one calculate the amount of heat absorbed inside a room in a single day using the temperature readings of the day? If the temperature has to be reduced from 30C to 20C how much heat should be ...
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2answers
4k views

Microwaves vs Gas or Electric Coil heating of a water boiler in a typical household

Wouldn't it be more energy efficient and or safe to use microwaves to heat our home's water boiler instead of using dangerous gas or hot electric coils that could catch other things on fire? I'm kinda ...
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855 views

What meaning does the slope of the efficiency path on a Mollier diagram have in terms of temperature?

Let's say I have a steam turbine that I have modified to increase its isentropic efficiency. As a specific case, consider the modification outlined in the Mollier diagram below. The arrows represent ...
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263 views

2d or 1d conduction in this scenario?

There is a rectangular fin attached to a heat exchanger with a base temperature of 350K. The fin has uniform properties and experiencesa uniform heat generation. It also experiences heat transfer with ...
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3answers
1k views

What does it take to derive the ideal gas law in themodynamics?

How can the ideal gas law be derived from the following assumptions/observations/postulates, and these only ? I'm able to measure pressure $P$ and volume $V$ for gases. I notices that if ...
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3k views

Why do steam bubbles increase in size as they rise?

In the following video (a customer's review of a glass kettle), we can observe water boiling: http://youtu.be/jByY5I7Xk7w?t=2m55s As the kettle starts to boil at around 2:55, we can see large steam ...
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1k views

Questions about compressing a liquid in a piston

We were discussing super-critical fluids with a colleague and as were thinking about different thought-experiments, it occurred to me that you cannot really have only liquid in a piston in a real ...
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Why does hot oil explode when pouring water on it?

I am puzzled to know, What is the reason of hot oil make sound and explode when we pouring water on it?
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3answers
2k views

Prove that negative absolute temperatures are actually hotter than positive absolute temperatures

Could someone provide me with a mathematical proof of why, a system with an absolute negative Kelvin temperature (such that of a spin system) is hotter than any system with a positive temperature (in ...
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4answers
2k views

Why water inside a vessel placed in a body of boiling water does not boil?

Imagine a plastic sac filled with water placed in a pan of boiling water. I wonder why the water inside the sac does not boil. The temperature of the water inside the sac should be the same as that of ...
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387 views

Energy versus free-energy diagram

Energy versus free energy diagram. I haven't been able to find an adequate definition of these two terms in relation to each other. Could someone point me in the right direction, please? From Borrell ...
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214 views

Entropy change in a cycle with two isochoric and two adiabatic processes [closed]

Prove that the change of Entropy in a cycle with two isochoric and two adiabatic processes is 0. How can I prove that? Thanks!
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2answers
1k views

Are information conservation and energy conservation related?

as evident from the title, are both, conservation of energy and conservation of information two sides of the same coin?? Is there something more to the hypothesis of hawking's radiation other than ...
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3k views

How does smoke move in the air and how can I direct it so it will go to a place I want it to go?

Let's assume a close room with 1-2 people who only one of them smoking cigarette. What is the equation describe the smoking spreading? is it diffusion? what are the parameters is so? Is there a ...
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189 views

In a Sterling Engine, does heat from the hot side transfer to the cold side?

A Sterling Engine is a closed system. The "hot" side oscillates between higher temperature with higher pressure and lower temperature with lower pressure. Does Nature switch back and forth between ...
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1k views

How long will my fridge magnet stay attached to my fridge?

I have a 500 gram neodymium magnet. It is stuck to my fridge. With the constant pull of gravity trying to pull it off how long would it stay attached to fridge? For arguments sake lets say my fridge ...
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5k views
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590 views

At what point can we assume the tip of a fin is adiabatic?

Let's say there is a fin that is 1mm thick, extends 8mm from the surface, and is 10 mm wide. The fin is exposed to a moving fluid. Can we assume the adiabatic tip condition and use the characteristic, ...
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2k views

In what situations do I use the characteristic length of a fin to find the surface area?

So I'm learning about fins in heat transfer and it seems that there are two separate formulas for the surface area of a rectangular fin of length L, width w and thickness t. The fin is attached to a ...
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What meaning do changes in the absolute value of Gibbs free energy have in a simple expansion process?

Below is a simple representation of the thermodynamics of a steam turbine. Stream kinetic and potential energy changes are neglected and no other type of non-PV work is done besides shaft work. ...
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164 views

In the Niagara Falls, which factors prevent rise of T H2O falling a certain height?

I need some ideas on a problem. The first part says: Whats the posible rise in the temperature of the water falling 49.4 m in the Niagara Falls? That one was easy, with answer 0.112 Kelvin. ($\Delta ...
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4k views

Which is more efficient, heating water in microwave or electric stove?

So our propane tank in the kitchen ran out again today. Which is more energy efficient, boiling water in a microwave on an electric stove? All things being equal i.e. starting temperature and mass ...
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117 views

Equipartition theorem for flowing gas

If an ideal gas is flowing with a velocity $v$, how is the equipartition theorem applied. Normally, we can say that $\frac{1}{2}mv_{x,rms}^2=\frac{1}{2}k_BT$. We can do the same thing for $v_y$ ...
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2k views

What's the temperature distribution of a plane wall insulated on one side with no internal heat gen.?

Let's say we have a plane wall that is insulated on one side, exposed to a fluid on the other side, and has no internal heat generation. Would the shape of the temperature distribution be a constant? ...
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115 views

How can I calculate the amount of bubbles needed to lift a submerged body?

Our teacher had us come up with our own thermodynamics experiments, so I put a glass of water inside a vacuum-capsule. Inside the glass of water I have placed a non-floating object, a small plastic ...
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Confused with stress, strain and linear thermal expansion

Four rods A, B, C, D of same length and material but of different radii r, 2r , 3r and 4r respectively are held between two rigid walls. The temperature of all rods is increased by same ...
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434 views

Is the $mL_c$ value for triangular and rectangular fins the same value?

I am looking at the solutions that my professor put up and I feel that he did something wrong. Here is the question and I will give my stab at the solution so you can see why I think that it is wrong. ...
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5answers
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Second law of Thermodynamics: Why is it only “almost” always true that entropy is non-decreasing? [duplicate]

Wikipedia - Second law of thermodynamics: ...the entropy of any closed system not in thermal equilibrium almost always increases. I understand that the second law of thermodynamics is based on ...
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377 views

When do thermal and chemical equilibrium not coincide?

What is an example for a system, which is in chemical equilibrium, but not in thermodynamical equilibrium? And what about the other way around? It seems to me, that as long as Parameters like ...
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366 views

What's the efficency of a steam jet pump?

Jet pumps or venturi pumps are often stated as having a "terribly low" efficiency, steam jet pumps specifically are usually describes as "only justifiable when there's an abundant steam supply anyway" ...
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710 views

How do I find average temperature given a temperature distribution?

I was told to find the temperature distribution of a wire with a current going through it. So I found $$T(x)=T_{\infty}-\frac{\dot{q}}{km^{2}}[\frac{cosh(mx)}{cosh(mL)}-1]$$ I need to find the ...
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4answers
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What does third law of thermodynamics tell us?

I just have a question concerning the third law of thermodynamics. The third law describes that the entropy should be a well defined constant if the system reaches the ground state which depends ...
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684 views

How to calculate the Gibbs free energy out of a given Entropy?

I'm stuck in a small calculation. I try to solve a small exercise. You should calculate for a given entropy the Gibbs free energy, where the entropy is given as $S\left(U,V\right) = ...
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1answer
656 views

How should a heat current be defined for two component system with unequal numbers

I'm trying to calculate a heat current in a linear response regime of a very weakly-interacting two component low temperature Fermi gas with imbalanced population. I think there are two standard ways ...
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3answers
765 views

What is the most efficient way to use hand dryer?

What's the most efficient way to place your hands under the hand dryer? Let's assume that dryer creates simple downward flow of hot air. Here are some examples:
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461 views

How equivalent are heat energy and work energy in connection with a spinning flywheel?

Let's say we have two identical spinning flywheels, that have arbitrary geometry, and are made of copper. Now we apply some heat energy at the center point of flywheel A, causing it to slow down a ...
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94 views

Terminology question about energy

I'm looking for the appropriate term to use for what gets "used up" as potential energy is converted to heat and work. For example, some of the the energy in solar radiation is converted by ...
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Thermodynamics of supercooled water

Now that it's been freezing outside for the last few days, I experimented a bit with supercooling. I've left a bottle of clean water outside for a few hours, and behold, when I shook the bottle, the ...