Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Standard Heat of Combustion

When considering tabulated standard values of heat of combustion (∆H° combustion) or any other similar value, the results are reported for species in their standard states (1 bar pressure, 25°C, etc). ...
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5k views

Does specific heat change with pressure? If so, why?

As pressure is increased, do we require more energy to increase the temperature from given temperature for the same mass. For example, if we heat water at 1 atm to raise its temperature by 20 degree ...
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1answer
551 views

Do ideal gases at zero Kelvin have potential energy?

Do ideal gases at zero Kelvin have potential energy?
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1answer
217 views

Why Thermodynamic cycles and no single process

Why Thermodynamic cycles are used to obtain work for example carnot engine rather than single isothermal process which is part of cycle and can be used to obtain more work.And why isothermal process ...
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71 views

What is concept of temperture in ion trap?

As only several thousands of particles are holding in the ion trap, how can we understand the temperature?
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143 views

Thermodynamics - convection current

please could someone help explain the mechanism of a convection current as I keep finding conflicting explanations. Is a convection current caused by differences in density or differences in pressure? ...
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71 views

How the pressure of a system changes in terms of density?

I am modeling a closed natural circulation loop, filled with water. Some parts of the loop are heated, some are cooled and other are assumed adiabatic. As an effect of heating and cooling the density ...
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1answer
94 views

Details in the derivation of the second law starting from the phase space volume

I had a question on one of the details of the derivation of the second law of thermodynamics starting from the phase space volume. I'll type out what I understand so far: Letting the Hamiltonian ...
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4answers
10k views

Deriving combined gas law from Boyle's and Charles' laws

I know that the combined gas law, $$\frac{PV}{T}=k$$ should be derivable from Boyle's Law and Charles' Law. Since these are very basic equations, I presumed that it would be a simple matter, so I ...
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2answers
153 views

Pressure versus Volume system problem

A rigid air tight container of volume 1.5 m$^3$ is filled with a gas of density 8 kg/m$^3$. The container has a density meter that allows us to watch the changes in density in the gas in the ...
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15k views

Why does a human body only emit infra red radiation and not other types of electromagnetic radiation?

What causes humans to emit infra red radiation and why don't we also emit other types of electromagnetic radiation such as ultra violet or microwave? Sunlight contains UV and our body takes it in, but ...
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78 views

Entropy of a chain

A chain has N segments which can be oriented in either the x or y directions. For each segment oriented along y, there is an energy penalty of $\epsilon$. We also know the end segment is at $(L_x, ...
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67 views

Calculating energy U from $\partial U/\partial q$

Imagine $N$ oscillators with only two possible energies, $\epsilon_0$ and $ \epsilon_1$, with $\epsilon_1 > \epsilon_0$. Taking $\epsilon_0 = 0$ for now I showed $\Omega(q\epsilon_1) = ...
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191 views

Can entropy of a system decrease if we wait long enough?

A ball rests on a smooth surface. The ball's particles are in constant motion. So are the particles of the floor. Some of the ball's particles collide with the floor's particles and transfer kinetic ...
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38k views

Why is there water coming out of a car’s tail pipe?

I notice yesterday that my neighbor’s car had water coming out of the exhaust pipe in the morning. My first response was since the hot exhaust is hotter than the cold tail pipe, heat is transferred ...
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3answers
16k views

Maximum theoretical efficiency of internal combustion engine

This Wikipedia article states that: Most steel engines have a thermodynamic limit of 37%. Is it correct? If so then it is not clear where this number comes from. Is it derived somehow from ...
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3answers
729 views

Would sea water moderate a nuclear submarine meltdown?

My son asked me: If nuclear submarines get sunk or blown up, what is to stop them going into nuclear meltdown? I thought about it and came to the conclusion that because they're in the sea the ...
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615 views

Caculating thermal stresses in a composite rod

The Question Between two rigid walls separated by a distance $l_1+l_2$, two rods of equal cross-section area $A$, and length, coefficient of linear expansion and Young's modulus $l_1, ...
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40 views

Maximum temperature of an elliptical thermodynamic process

Given a heat engine made from the curve $$V(t)=V_0 +A \cos(\omega t); \qquad P(t)=P_0-B \sin(\omega t).$$ What are the hottest and coldest points of this cycle, and what are the temperatures at those ...
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25 views

Finding out the temperature difference

If we add 10 spherical bubbles then there will be some change in their area. Is there any way to find out change in temperature of the liquid from the change of its area?
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2k views

How is this process not quasi-static yet reversible?

Consider a (adiabatic) canister with a piston containing some gas kept in a vacuum. There are two weights on the canister which equalize the pressure of the gas on the piston. Assume the system is at ...
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2answers
5k views

Work done by isothermal expansion from two different viewpoints

Consider an adiabatic system as follows. It consists of a gas in a container and a piston. Initially, the system is at equilibrium and the gas inside it occupies a volume $V_i$ at a pressure $p_i$ ...
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4answers
6k views

Water in vacuum (or space) and temperature in space

So, water in vacuum will boil first and then freeze. I don't know how the freeze happens. As pressure lowers to zero, what happened to freezing point? (I know heat taken by vapor, and the water cool ...
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1answer
75 views

How many radiotherapy sessions would it take to boil one cup of water? [closed]

Context: Gray (Gy) is a unit dose used in radiotherapy. It is defined as the absorbed energy of 1J per kilogram of matter. There is a wide misconception that ionizing radiation acts by heating ...
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3answers
550 views

When to use the Boltzmann distribution and the chemical potential?

How do you know when to use the Boltzmann distribution for a particular problem? I have many polymers connected together in many different possibilities by connector agents. All are in a solvent. I ...
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2k views

Basic Thermodynamics: Quasistatic Adiabatic Process

I'm going through the exercises in a Thermodynamics book, just to revise and build my intuition. Right now, I'm working on: Show that for a quasistatic adiabatic process in a perfect gas, with ...
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1answer
4k views

Why do real gases deviate from ideal behavior above the Boyle temperature?

My textbook says that Boyle temperature is the temperature at which a real gas shows maximum ideal gas behavior. Below the Boyle temperature, molecules come too close and intermolecular forces skew ...
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182 views

Relation between speed of sound and compressibility

We know that $c^2=\frac{\partial p}{\partial ρ}$ The adiabatic compressibility is defined as: $\beta_S=-\frac{1}{V}\frac{\partial V}{\partial p}$ such that the subscript "S" stands for "adiabatic" ...
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173 views

Speed of Sound?

The speed of sound in a gas may be given by the following formula, $$c = (kRT)^{1/2},$$ where $k$ is specific heat ratio, $R$ is the gas constant and $T$ is the temperature. What are the limits of ...
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3answers
164 views

cooling glass of milk glass and a jar of water

When im given a steel glass of boiling milk which I cannot even touch, I used to put that glass in a jar surrounded with room-temp water and give it 10 mins. At the end, I used to find the steel glass ...
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83 views

Is heat energy from electronics wasted in the winter? [duplicate]

In the winter, are not all electronics heating the house - thus no energy is wasted? Considering the energy I'm paying for: If I leave my computer running while I'm out, how much energy is actually ...
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1answer
101 views

Spin version of Maxwell's demon: Where's the energy?

I have confused myself about the following variant of Maxwell's demon and I can't seem to find out where the energy went. Consider this: You have a chain (one dimension) of spins (up/down) with a ...
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4answers
2k views

Heat transfer by conduction is not possible for gases?

Today one of my instructor told me that gases cannot have heat transfer thru conduction because molecules are far apart and so it cannot transfer heat,infact the diffusion process of gases transfers ...
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1answer
134 views

What is the difference between thermodynamical equilibrium and statistical equilibrium?

I am trying to understand what is the different between thermodynamical equilibrium and statistical equilibrium, for example, between photons and electrons at the early universe. (I read through paper ...
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2answers
7k views

Why does the windshield of my car freeze even if the outside temperature is above freezing? [duplicate]

Under what conditions does the windshield of a car freeze even if the outside temperature is above freezing? It is not clear whether this is related to the question why bridges freeze with ...
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3k views

How does a canvas water bag cool water?

I was reading about this water bottle by Botl that behaves like a canvas water bags to keep water cool. I found out that this idea is an old idea and cars would drive with water bags in front as shown ...
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3answers
2k views

Why it is difficult to drink tea with a straw?

It is easy to drink cold drinks, soft drinks with straw but when I tried to drink tea with straw then that was very unpleasant and even for time I lost the sense from my tongue. My question is why it ...
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1answer
136 views

How does a MRI use 20.1kW yet creates over 204K BTU/h? [closed]

I've been reading through a manual about MRI operating procedures for a large healthcare provider. The manual (written by Siemens) states that the MRI machines use 9kW in stand-by mode and 20.1kW ...
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2answers
161 views

Temperature as frequency spectrum of stress-energy tensor?

I am currently learning general relativity, and in the textbooks that I am reading, temperature seems to be treated as a scalar field, extraneous to the geometry of spacetime. This is puzzling me, ...
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2answers
786 views

Considerations and questions for a DIY heat pipe; how to choose a working fluid? [closed]

I plan to build a DIY heat pipe! For more info on what a heat pipe is, see Wikipedia. I would like to use it to cool a desktop graphics card I have. I am having trouble deciding how to choose the ...
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3answers
16k views

Temperature behavior over time of black or white cars in hot, sunny regions

How does the color of a car influence its inner temperature change over time when parked outside in windless, hot and sunny regions? I know what's the common idea about that: black cars are supposed ...
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3answers
660 views

Temperature; Why A Fundamental Quantity?

Temperature is just an indication of the combined property of mass of the molecules and their random motion. We can explain no effective energy transfer between two conducting solid bodies in contact ...
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1answer
126 views

Relation between a Quasistatic and a reversible process

Why is it that if a process is reversible, it is quasi-static? Does it mean that then the process is also non-dissipative if it is quasistatic?
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203 views

Why does the blade height goes on decreasing in a multi-stage axial flow compressor? [closed]

The axial compressors used in jet engines have their blade heights in decreasing order in the direction of the flow.
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5answers
9k views

Why am I not burned by a strong wind?

So I was thinking... If heat I feel is just lots of particles going wild and transferring their energy to other bodies, why am I not burned by the wind? When I thought about it more I figured out ...
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2answers
305 views

Thermal equilibrium and kinetic energies

Is temperature solely a function of a kinetic energy? If a solid and a gas are at thermal equilibrium at a temperature of 20 degrees Celsius, the solid has much less kinetic energy than the gas. How ...
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1answer
704 views

Why does a cooling motorcycle make popping noises?

I was sitting in my parked car tonight when a Harley-Davidson motorcycle parked next to me. With my window down, I could hear that as the motorcycle was cooling down, it was giving off some type of ...
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3answers
895 views

Is thermodynamic reversibility a function of path?

Question: given a path taken by a system through state space, is it possible to make a statement such as 'that path corresponds to an irreversible process' or 'that path corresponds to a reversible ...
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3k views

Mixing of Ideal gas - Thermodynamic equilibrium

I always get confused what exactly happens when two ideal gases mix. Consider the initial situation where two gases are in a box, separated by a rigid and adiabatic wall between them. Now when the ...
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1k views

Is the second law of thermodynamics a fundamental law, or does it emerge from other laws?

My question is basically this. Is the second law of thermodynamics a fundamental, basic law of physics, or does it emerge from more fundamental laws? Let's say I was to write a massive computer ...