Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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180 views

Maximizing Multiplicity of Einstein Solid == (Temperature = $\infty$)?

If I have a system consisting of 2 Einstein solids (A and B) is it equivalent to say that maximizing the multiplicity of the ...
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49 views

Heat of adsorption from fugacity data

I have a set of data relating the fugacity ($\approx$ pressure) to the loading for a given set of temperatures. There are three temperature sets each having five fugacity vs. loading points. The ...
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0answers
64 views

Increase in number of micro states explanation or restatement of second law?

Is the boltzmann's expression of entropy as log of micro states leading to the formulation that system is more likely to be in a macrostate with more no. Of micro states really is an explanation or ...
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2answers
622 views

Spontaneous conversion of heat into work at negative temperatures

Consider a heavy macroscopic object moving in a gas. Friction causes its kinetic energy to be converted into heat. Thermodynamically, there is (effectively) no entropy associated with the kinetic ...
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4answers
154 views

Is it possible to “add cold” or to “add heat” to systems?

Amanda just poured herself a cup of hot coffee to get her day started. She took her first sip and nearly burned her tongue. Since she didn't have much time to sit and wait for it to cool down, ...
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2k views

Joule-Thomson effect of Van der Waals gas

I'm supposed to calculate the inversion pressure $p_i$ of a Van der Waals gas. The state equation of the Van der Waals gas is: $$(p + \frac{a}{V^2})(V-b) = RT.$$ To get a hold of the inversion ...
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2answers
142 views

gravity affecting a molecules speed? [closed]

Why are the poles colder than the rest ofthe planet?Is the gravity stronger making molecules spin slower?How does gravity affect heat and hydrogen bonds? And what affects gravity?A little off topic ...
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1answer
176 views

Liquid oxygen how do they use it as fuel?

Rockets are said to be using liquid oxygen as fuel. How do they use liquid oxygen since it's just oxygen, it only helps in the combustion process. How can it be a fuel on its own?
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2answers
6k views

Hot Air Balloon and Buoyancy

This is a conceptual question in a solution I am trying to understand. Problem statement: I have a balloon with a volume of V $m^3$. The outside air temp is $K$ kelvin and mass to lift is $m$ kg. I ...
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1answer
214 views

What is the term for heat generation by a flowing fluid?

I would like to know more about the heat distribution over time in a flowing liquid. To this end, I consider the Navier-Stokes equation (where the coefficients may be temperature dependent) and the ...
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1answer
2k views

How long does it take a warm object to cool in air?

This is a work-related question. A warm steel torus of a given diameter & thickness is left in a room held at a controlled temperature, how long does it take to reach equilibrium? Assume the air ...
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3answers
332 views

How can I determine the coefficient $k$ in $ \dfrac{dT}{dt} = -k(T - 100 \mathrm{^\circ C}) $?

I recently spend some time on cooking and I'm curious about the time evolution of the temperature of the water. I did some experiment and the temperature is of the form $$ T = 100 \mathrm{^\circ C} + ...
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3answers
845 views

Which form of the first law of thermodynamics should I use?

I usually wonder which thermodynamics first law is better to use ? The one given by physics : $\Delta U=Q-\Delta W$ or the one by chemistry : $\Delta U=Q+\Delta W$ In other words, should I take ...
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1answer
2k views

How does a thermal temperature gun work?

I once worked as a kitchen porter over a winter season. We had fun with thermal temperature guns (like these) which I learned can be used for measuring the temperature of something a reasonable ...
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3answers
808 views

How hot is the water in the pot?

Question: How hot is the water in the pot? More precisely speaking, how can I get a temperature of the water as a function of time a priori? Background & My attempt: Recently I started spend ...
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2answers
568 views

Why does $U = T S - P V + \sum_i \mu_i N_i$?

From the first law of thermodynamics: $$ dU = TdS - PdV + \sum_i\mu_i dN_i.$$ Quoting Wikipedia: As conjugate variables to the composition $N_{i}$ the chemical potentials are intensive ...
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0answers
59 views

Interface condition for heat exchange

I would like to compute the heat distribution of a piece of metal with some surrounding material. The heat is assumed to propagate by diffusion, so inside the metal piece and also on the outside, the ...
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2answers
3k views

Increase thermal efficiency of combustion engine by using heat of coolant/exhaust?

I can't be the only one who's ever thought of this, but obviously it hasn't caught on: In terms of energy density, fossil fuels are the best thing around short of enriched uranium (and, flammability ...
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1answer
261 views

Math for Thermodynamics Basics

I am studying Statistical Mechanics and Thermodynamics from a book that i am not sure who has written it, because of its cover is not present. There is a section that i can not understand: ...
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3answers
2k views

Why is Entropy expressed in terms of Enthalpy?

Why does ${\Delta}S_{m(fusion)} = \frac{{\Delta}H_{m(fusion)}}{T}$ ? I always thought ${\Delta}S = \frac{dQ}{T}$ In this case does it mean $dQ = {\Delta}H$ ?? Why is it so?
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3answers
575 views

Is there a mechanism for time symmetry breaking?

Excluding Thermodynamic's arrow of time, all mathematical descriptions of time are symmetric. We know the arrow of time is real and we know the equations describing physics are real so is there any ...
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1answer
792 views

What determines bubble locations in boiling water?

Something a little different to our usual fare. I was boiling a pan of water for cookery the other day, and got to wondering what caused the location of the bubble streams from the bottom of the pan. ...
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1answer
115 views

Can Joule's First Law of Thermodynamics be Applied to Atomic Charges?

James Joule established that all forms of energy were basically the same and interchangeable. My question is if thas law is relevant in particle physics. Can a positive charge and a negative charge be ...
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2answers
786 views

Dispersion relation and Heat Capacity

I have seen case studies of the 3D Debye model where the vibrational modes of a solid is taken to be harmonic with dispersion relation $\omega = c_sk$. It is said that for temperatures much less than ...
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4answers
2k views

Human as a heat engine

humans are heat engines. heat engines can't operate when the source and the sink are at the same temperatures and also if the temperature of the sink is higher than that of the source. in humans' ...
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1answer
417 views

Maxwell demon : how can the demon move the door without doing any work ?

Here is something that I never understood about Maxwell's demon paradox : in order to contradict the second law of thermodynamics, the demon must open and close the door without doing any work... But ...
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3answers
898 views

Temperature change inside pressure chamber

Let's say there is a pressure chamber with some sort of sample / specimen (e.g. protein crystal) in it. Now I apply a certain amount of gas pressure, e.g. 10 or 20 atm. Let's say I use xenon as a gas. ...
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2k views

What are the various physical mechanisms for energy transfer to the photon during blackbody emission?

By conservation of energy, the solid is left in a lower energy state following emission of a photon. Clearly absorption and emission balance at thermal equilibrium, however, thermodynamic equilibrium ...
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1answer
656 views

Net work output of an engine performing Carnot cycle?

My problem gives me a Carnot cycle heat engine with water as its working fluid, with $T_H$, $T_L$, and the fact that it starts from saturated liquid to saturated vapor in the heating process. I need ...
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1answer
82 views

In $PdV$, what is the value of $P$? $P_1$ or $P_2$?

Say I have an ideal gas that has a known $P_1$, $P_2$, $T_1$, and $T_2$ undergoing a reversible adiabatic process. I want to find the work done so I must use $PV = RT$ to get the change in $V$, so ...
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1answer
624 views

Difficulties with understanding total entropy change and unavailabillty

Of course, I know the fact that the entropy of an isolated system never decreases. Neverthless what makes me confused about the entropy(or change of entropy) of an isolated system is the explanation ...
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1answer
271 views

Information bearing degrees of freedom of a quantum simple harmonic oscillator

I am trying to make sense of arXiv:physics/0210005. I am confused with the concept of information bearing degrees of freedom of a system mentioned at the very beginning. To verify the arguments of the ...
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1k views

Why is the equation for Entropy of an ideal gas that undergoes reversible change in T at constant Pressure like this?

Why is the equation for change in Entropy for a reversible change in $T$ at constant $P$ described as $$\Delta S = n C_p \ln\frac{T_f}{T_i}$$
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1answer
112 views

Landauer's principle vs Wien's displacement law

Can we argue based on Landauer's principle that if one bit information is changed inside a blackbody, the total radiated energy should be at least or in order of kTln2? If it is so, can we also argue ...
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89 views

Landauer's principle vs Rayleigh–Jeans law

Can we argue based on Landauer's principle that if one bit information is changed inside a blackbody, the total radiated energy should be at least or in order of $kTln2$? If it is so, can we also ...
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2answers
272 views

Behaviour of individual terms in Einstein-Smoluchowski fluctuation-dissipation relation

Consider a bath of Brownian particles at temperature $T$. If we sprinkle some larger particles in this (eg: pollen grains in water or dust motes in air), they'll diffuse with diffusion constant $D$ ...
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462 views

Rotational Constant and Moment of Inertia of Fluorine gas

I have come across some homework question on thermodynamics which needs me to calculate $B$ of $F_2$ My attempt: $B= \frac{h}{8\pi^2cI}$ where $I=\mu r^2=\frac{m_1m_2}{m_1+m_2} r^2$ Atomic mass of ...
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1answer
115 views

Is there a relation between supersymmetry and entropy?

Considering that entropy denotes the level of order/disorder in a system, would it be possible for entropy and supersymmetry to exist at the same time? Or, are they entirely unrelated?
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3answers
764 views

Why isn't the Bekenstein-Hawking Entropy considered the quantum gravitational unification?

Based on the Bekenstein-Hawking Equation for Entropy, hasn't the relationship between quantum mechanics and gravity already been established.
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2answers
1k views

How long will a water drop exist until it evaporates based on ambient conditions? [closed]

How long will a water drop exist until it evaporates based on ambient conditions? I am looking for a simple equation or table that would tell me how long a water drop may exist until it evaporates ...
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1answer
757 views

Sensible heat question (solving for temperature)

If $55 034.175 \rm{kJ }$ of heat are transferred to $150 \rm{kg}$ of ice at a temperature of $-12.15 ^\circ \rm{C}$, calculate the temperature of the resulting water. Using $Q = mc(t_2-t_1)$ or ...
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1answer
600 views

Have negative pressures any physical meaning?

Some cubic thermodynamical equations of state predict negative pressures, have negative pressures any physical meaning? Could they be related to negative mass?
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1answer
321 views

Rate of Cooling

I was given the following problem: Two objects have a temperature difference of 20 degrees C at time 0. Two minutes later, they have a temperature difference of 18 degrees. How long does it take ...
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1answer
221 views

What pressure or tension occurs in a glass jar when I pour boiling water inside?

Sometimes it happens that when you pour a boiling water into a glass jar, it cracks. Since glass is very hard material and resilient to pressure, the tension must be very high. Is it possible to ...
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0answers
138 views

How to solve state parameters using these givens for an ideal gas?

In a thermodynamic turbine using air as an ideal gas, given that you have a known inlet temperature value $T_i$, a known exit pressure value $P_e$, a known inlet and exit velocity $V_i$ and $V_e$, a ...
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3answers
2k views

Determine the Dependence of S (Entropy) on V and T

Why can the equation $$dS= \frac{1}{T} dU + \frac{P}{T} dV$$ be expressed as $$dS= \left. \frac{\partial S}{\partial T} \right|_V dT + \left. \frac{\partial S}{\partial V} \right|_T dV \quad?$$
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2answers
3k views

How to describe heat transfer between two solid materials?

A general equation for dealing with heat transfer between one material and a region of insulating material. I've seen basic heat transfer equations for one material, but I'd love to see an explanation ...
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1answer
1k views

Does an object's color change its rate of cooling?

The motivation for this question comes directly from this thread. The proposition is that the color of something changes how fast it cools (note: specifically the rate of cooling, not taking into ...
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3answers
5k views

How can my water cool down more quickly?

I have a cup and I can only pour hot water inside, I wanna know whether the heat will dissipate more quickly with more water or less water? How about the occasion when my cup is well covered?
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2answers
376 views

Most efficient type of heat pump

Can I make a heat pump beat the Carnot efficiency? Why is the Carnot process the most efficient one? If I have a heatpump that is sphere shaped, and cascaded in layers like a onion can I beat Carnot ...