Covers the study of (mostly homogeneous) macroscopic systems from a heat/energy/entropy point of view. Maybe combine with [tag:statistical-mechanics].

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Are Maxwell Relations valid only out of saturation?

My thermodynamics book suggests that the Maxwell Relations must be used when dealing with a single-phase system. The equations come right after the section Mathematical Relations for the Homogeneous ...
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104 views

Woodstove coppertubing heat exchanger [closed]

I am trying to use the excess temperature of my wood stove's stack to heat a copper tube heat exchanger with water running through it. The water is piped through my concrete floor for radiant floor ...
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1answer
102 views

Spontaneity / Free Energy of Non-Isothermal Process

I'm trying to determine a lower bound for the work input necessary to make an entropy-reducing process "spontaneous" in the sense that the 2nd law is not violated. For a constant temperature and ...
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3answers
157 views

Ice and liquid water interacting across a boundary

Imagine we have two thermodynamic systems, one a mass of ice and the other an equal mass of liquid water, with both at 273.16K. Each system is isolated, except that they can interact with each other ...
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49 views

What are the thermal properties of a “perfectly rigid” container?

can a "perfectly rigid" container be a diathermal boundary? I checked the wikipedia article for heat and read: Kinetic theory explains transfers of energy as heat as macroscopic manifestations of ...
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1answer
156 views

Calculate heat transfer out of a basement [closed]

I am thinking it should be possible to calculate heat loss out of basement based on the temperature of the walls, but am not sure how to do it (what the equations are). For example, lets say the ...
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3answers
1k views

Zeroth Law of Thermodynamics, temperature, and ordering

In my thermodynamics course (and in other places on the internet) it is asserted that the Zeroth Law of Thermodynamics can be used to define the concept of temperature. One statement of the Zeroth ...
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54 views

Is there an efficiency-optimizing layout of items in a refrigerator? [closed]

Is there some optimal layout of items, or types of items (characterized by size, shape, density, solid/liquid, etc) that will allow a common household refrigerator to function with optimal energy ...
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133 views

Milk-First School

I have always been struck by the huge amount of different arguments about the issue: When you make a cup of tea, the milk should be poured first or added to the cup after the tea? Wikipedia, ...
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1answer
58 views

minimum possible absolute temperature in the universe? [duplicate]

Sorry guys i went wrong in my previous question , actually my question is what is the minimum possible absolute temperature in the universe of what ever substance...?
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46 views

White bread toasted seems hotter than brown bread?

Ok this is a bit of a random question but I 99% of the time use white bread for toast and I always toast my bread the same amount and every time I take it out it's too hot to handle and the butter ...
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1answer
336 views

Does the energy required to increase a volume of water's temperature increase as that temperature increases?

Obviously in a simple, classroom style experiment the energy required to increase water temperature is a constant and thus wouldn't change, but what if we made the experiment just slightly more real ...
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152 views

What algorithms can be used to compute the binodal in a ternary Flory-Huggins theory?

What are the most popular algorithms used to obtain a binodal curve for the ternary mixture (starting from Flory-Huggins theory)? I would like to obtain a plot similar to the one calculated here ...
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1answer
76 views

Chemical potentials for multicomponent solids

I have a problem understanding how to deal with the chemical potential when two thermodynamic systems are in contact. For simplicity, let us consider $T=0\ K$. We have a system that is composed of two ...
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67 views

Confusion on entropy in the universe [closed]

I was researching about the heat-death of the universe, and I was wondering if my understanding of it so far is factual to the theory? However, the 3rd Law of Thermodynamics prevents the universe’s ...
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154 views

Ergodic Hypothesis; canonical ensemble

I'm currently studying for an exam in thermodynamics/classic statistical mechanics and 2 things came up which are confusing me. First the ergodic hypothesis states that it is equal to take the mean ...
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34 views

Gibbs equation and reversibility [duplicate]

The equation $$TdS=dU+PdV$$ is a combination of $$dQ=dU+PdV$$ and $$TdS=dQ.$$ But in some process that is very irreversible, $TdS>dQ$, should we write $$TdS>dU+PdV$$ instead of the first ...
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52 views

Supercritical Steam Expansion [closed]

Ten kg of steam at 500 bar is expanded at constant pressure until its volume increases to seven times its initial value of 0.01 $m^3 $. (a) Calculate the initial and final temperature of the steam ...
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100 views

Specific Internal Energy Decreases with Increasing Pressure?

I was looking at "Properties of Compressed Liquid Water" (Table A-5) in Fundamentals of Engineering Thermodynamics by Moran. Table A-5 shows that the specific internal energy $u$ of compressed liquid ...
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1answer
1k views

Pressure vs Volume Calculation for air

I have 1 litre of air in a sealed container at atmosphere pressure (approx 15 psi absolute). I want to reduce pressure in the container by 1 psi ( 14 psi absolute or -1 psig). If I understand ...
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1answer
57 views

Spherical Shaped Electrical Leads for Thermal Conductivity Mitigation?

I am designing a thermionic converter and one of the biggest inefficiencies is the thermal conductivity and limited electrical conductivity of the leads. I'm trying to mitigate the loss of heat ...
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1answer
56 views

Vapor-compression refrigeration

In a vapor-compression refrigeration system I would like to understand the following : Why is there a need for the compressor ? Can't the saturated vapor from the evaporator be cooled directly in ...
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1answer
253 views

Can you extract energy from “hot” things without a temperature differential?

I've been reading about extracting energy from heat, particularly Sterling engines. There's always a temperature gradient. Heat flows from the hot side to the cold side through the working fluid. As ...
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68 views

Free energy a continuous function of temperature but may not be differentiable everywhere?

So according to my understanding, the free energy of the system should be a continuous function of temperature. This is because if the free energy is not continuous at temperature T, then at this ...
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49 views

Cost vs. purity producing liquid oxygen [closed]

We are a group of rocket amatures who build rockets using LOX and ethanol as propellent. We normally buy the LOX from supplier. But lately we have been discussing if there is an easy way to produce it ...
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91 views

Effusion of particles from one box to another - pressure calculation

Suppose we have a container divided into equal halves. Right half is fixed at temperature $T$, volume $\frac{V}{2}$. Initially it has pressure $P_0$, a hole of area $A$ is opened between them. I ...
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27 views

Thermodynamics of binary symmetric channels

I am reading this very interesting paper: http://m.iopscience.iop.org/1751-8121/41/40/402002/pdf/1751-8121_41_40_402002.pdf about thermodynamics of channels in information theory. More generally, ...
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1answer
162 views

Problem about thermodynamic relations

We know that for constant pressure thermodynamic processes, $dH=dQ_p$. My question is, does it implies that only reversible work is possible in this processes so that $dw=0$ because $dv$ is zero? In ...
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253 views

Irreversible heat engines strictly less efficient than reversible ones

I undertand how Canot's theorem implies that irreversible heat engines must be no more efficient than reversible one's, but it isless clear why they need to be less efficient, as I have seen stated in ...
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135 views

Calculating heat capacity from the equation of state

It is known that within thermodynamics alone, given the equation of the state of a system, one cannot explicitly determine the heat capacity. What is the mathematical reason for this? Intuitively, it ...
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294 views

Thermal expansion of two bolts

I have this question asking me about the thermal expansions of two bolts, a steel one, and a brass one. I have the equation: $\ (\delta L/L)/T = \alpha $ I don't understand how I can use this ...
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1answer
285 views

Chemical Potential with Pressure at Constant Temperature

The above picture shows how the Gibbs free energy of a solid, liquid and gas vary with pressure. I have found no similar graphs on the internet that match the above. Instead I often find these ...
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40 views

Energy stored in a battery?

I want to calculate the energy lost from a battery to heat, and the energy stored in a battery. Are these formula's correct? $ E_b$ = $I$$V$ x $t$ $ E_H$ = $I$$R$$^2$ x $t$ $E_b$ = energy stored in ...
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1answer
145 views

What causes a heat generating source to stabilize at a certain temperature? (Answered by myself, I think)

For example, we out a heat sink on a microprocessor to keep it cooler. I understand that if we run 100 watts of electricity through the microprocessor, it will generate 100 watts of heat, or 100 ...
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1answer
50 views

Heat generated on thin disc plate in magnetic field [closed]

There are the eddy currents in thin circular copper plate thickness h and radius a, in a harmonic magnetic field which is perpendicular to plate and the effect of auto-induction is negligible. Now we ...
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67 views

Given partial derivatives find the state function

I have to find the state function of a gas (which under very low pressures behaves as an ideal gas). So, first I tried writing it as part of an equation $ dV = \dfrac{\partial V}{\partial T}\ dT + ...
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39 views

Snowmaking in the tropics - an estimate of water evaporation

If I set up a snowmaker in the tropics and sprayed water with it how much water would I evaporate? How would I calculate?
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42 views

Do COBE, WMAP, and Plack have design flaws? [duplicate]

MRI expert Pierre-Marie Robitaille on the design flaws of COBE, WMAP, & Planck and the violation Kirchhoff's Law: Here are his talks: Pierre-Marie Robitaille: The Cosmic Microwave Background ...
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29 views

Heat energy in special theory of relativity [duplicate]

Is heat energy invariant under Lorentz transformation? If so then how?
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59 views

Chemical potential of photons [duplicate]

Why do photons have zero chemical potential and what is its the physical significance? From what I know the chemical potential could be interpreted as the energy per unit particle that is put into a ...
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1answer
33 views

fusing two air containers with fixed pressures $p_1,p_2$ and temperatures $T_1, T_2$, what end-result $T$ and $p$ will be?

Let's say that I have two boxes with both volumes equal $V$, filled with an air. Air in first box have pressure $p_1$ and temperature $T_1$, likewise air in second box have pressure $p_2$ and ...
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61 views

Radiation heat transfer

I'm looking at the radiosity equations for heat transfer http://en.wikipedia.org/wiki/Radiosity_(heat_transfer)#Radiosity_method Specifically, I'm hesitant to accept the equation: $$ \dot Q_i = ...
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76 views

Restrained expansion of a piston/cylinder

Suppose an ideal gas in a piston cylinder has some initial pressure $p_1$, volume $V_1$, and temperature $T_1$. A pin, which holds the piston in place, is suddenly removed, and the gas quickly ...
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330 views

VdW Gas Entropy/Enthalpy/Gibbs Free Energy of Mixing in 2 Chamber Experiment

What are the equations for $\Delta S_{mix}$, $\Delta G_{mix}$, and $\Delta H_{mix}$ for a real gas? Explanation: In one of the most well known experiments in thermodynamics, two chambers are ...
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2answers
93 views

EM Radiation and Heat

If there is EM radiation, will there always be a heat exchange between the wave and its surroundings? If you have an extremely energy-efficient light bulb that converts ALL the energy it receives into ...
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73 views

Derivation of cylindrical line heat source problem?

I have a line heat source embedded inside a cylinder and I am trying to find the temperature distribution T(r,t). By using the similarity variable, the solution to the differential equation is ...
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47 views

Vacancy Generation / Annihilation Time (Relaxation Time)

Vacancy Generation/Annihilation Time, Recombination Time and Relaxation Time ($\tau$) are all synonymously used in atomic physics literatures. They're defined as the time that it takes for vacancies ...
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2answers
41 views

Infinite heat from gas?

Does any type of gas keep the same temperature if is constantly exposed to same force? In other words, must we change the applied force in some moment to get heat again, or is the same constant force ...
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269 views

Partition Function of a three state particle system

I've just finished studying the partition function of a two-state particle system, where particles can have a 0 energy value or E energy value . That is: Where $t_j$ is a variable of value ...
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1answer
673 views

Otto cycle efficiency described in pressure ratio (instead of compression ratio)

The Otto cycle's thermodynamic efficiency is often described using the compression ratio: $$\eta_{th} = 1 - \left( \frac{1}{CR} \right ) ^ {k-1},$$ (where CR is the compression ratio, and k the ...